Search Results

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

This paper presents the emission characteristics of a HCCI engine operation using n-heptane. The experiments were conducted in a single cylinder Co-operative Fuel Research (CFR) engine equipped with an air-assist port fuel injector. The effects of intake temperature, air/fuel ratio, compression ratio, turbo-charging, and EGR rate on exhaust emissions were explored. The analysis of the exhaust gases included oxides of nitrogen (NOx), nitrous oxide (N2O), carbon monoxide (CO), total hydrocarbon (THC), and soot. The hydrocarbon species present in exhaust gases and their concentrations at several operating conditions were also characterized. The strategies to obtain low HC, CO and NOx emissions are presented and discussed. The approaches to effectively retard HCCI combustion phase without deteriorating combustion efficiency are examined. It was found that HCCI combustion produces extremely low soot and NOx emissions.

The objective of this work is to better understand freezing fog/drizzle conditions using observations collected during the Fog Remote Sensing and Modeling project (FRAM-S) that took place at St. John's International Airport, St. John's, NL, Canada. This location was ~1 km away from the Atlantic Ocean coast. During the project, the following measurements at one minute resolution were collected: precipitation rate (PR) and amount, fog/drizzle microphysics, 3D wind speed (Uh) and turbulence (Uh'), visibility (Vis), IR and SW radiative fluxes, temperature (T) and relative humidity (RH), and aerosol observations. The reflectivity and microphysical parameters obtained from the Metek Inc. MRR (Microwave Rain Radar) were also used in the analysis. The measurements were then used to obtain freezing fog/drizzle microphysical characteristics and their relation to visibility.

A 1.9L turbocharged direct-injection engine representing a model year 1998-2003 Volkswagen vehicle, equipped with the OEM diesel oxidation catalyst (DOC) and exhaust gas recirculation (EGR), was tested on an eddy-current engine dynamometer with a critical flow venturi-constant volume sampling system (CFV-CVS). The engine was operated over three steady-state modes: 1600 rev/min at 54 Nm; 1800 rev/min at 81 Nm; and 2000 rev/min at 98 Nm. Commercially available ultra-low sulfur diesel fuel (≺15 ppm S) was splash-blended with fatty acid methyl ester biodiesels derived from three different feedstocks: canola, soy, and tallow/waste fry oil. Test blend levels included: 0%, 2%, 5%, 20%, 50%, and 100% biodiesel for each feedstock.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

This paper presents a numerical model of the rotational and lateral dynamics of the piston (secondary motion) and piston slap in mixed lubrication. Piston dynamic behavior, frictional and impact forces are predicted as functions of crank angle. The model considers piston skirt surface waviness, roughness, skirt profile, thermal and mechanical deformations. The model considers partially-flooded skirt and calculates the pressure distributions and friction in the piston skirt region for both hydrodynamic and boundary lubrication. Model predictions are compared with measurements of piston position using gap sensors in a single-cylinder engine and the comparison between theory and measurement shows remarkable agreement.

The recent tightening of emission standards for new heavy duty engines has lead to the development and implementation of alternative fuel engines, particularly for urban transit bus applications. Alternative fuels are intended to offer a potential emissions benefit with regards to the regulated emissions, and especially the particulate matter, which has received the greatest degree of regulatory action. However, the entire composition of the engine emissions should be considered when evaluating the environmental benefits of these new fuels, and also the continued performance of these engines in actual fleet service. In this study the exhaust emissions from methanol, ethanol, and diesel - powered buses were determined during transient operation of the vehicles on a heavy duty chassis dynamometer. The tests of the alcohol fuelled buses, and a control diesel bus were conducted as the buses accumulated mileage in revenue generating service.

As more stringent vehicle emission standards are introduced worldwide, there is an increased need to provide a thorough assessment of the environmental impact of alternative fuels. With the advent of CNG as a viable transportation fuel, the development of advanced computer controlled fuel delivery systems is imperative in order to ensure acceptable emission performance. At present, the majority of light and medium duty engines operating on natural gas are primarily gasoline automotive engines which have been retrofitted to allow for the use of CNG. The Mobile Sources Emissions Division of Environment Canada and the Canadian Gas Association have conducted a joint test program in order to develop a database of exhaust emissions from vehicles typically converted for operation on either gasoline or natural gas at various operating temperatures.

Cranking and startup fuel control has become increasingly important due to ever tightening emission requirements. Additionally, engine-off strategies during idle will require substantially more engine startup events with the associated need for very clean starts. Thus, knowledge of an engine's Air-Fuel Ratio (AFR) during its early cycles is necessary in order to optimize cranking and startup fueling. This paper examines and compares two methods of measuring an engine's AFR during engine startup (approximately the first second of operation); an in-cylinder technique using a Fast Flame Ionization Detector (FFID) and the conventional exhaust based Universal Exhaust Gas Oxygen (UEGO) sensor method. Engine starts using a Ford Zetec engine were performed at three different temperatures (0, 20 and 90 C) as well as different initial engine starting positions.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

Reliable means for on-board detection of particulate filter failures or malfunctions are needed to meet diagnostics (OBD) requirements. Detecting these failures, which result in tailpipe particulate matter (PM) emissions exceeding the OBD limit, over all operating conditions is challenging. Current approaches employ differential pressure sensors and downstream PM sensors, in combination with particulate filter and engine-out soot models. These conventional monitors typically operate over narrowly-defined time windows and do not provide a direct measure of the filter’s state of health. In contrast, radio frequency (RF) sensors, which transmit a wireless signal through the filter substrate provide a direct means for interrogating the condition of the filter itself.

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

With the recent advancement in sensing and controller technologies architecture design of an autonomous driving system becomes an important issue. Researchers have been developing different sensors and data processing technologies to solve the issues associated with fast processing, diverse weather, reliability, long distance recognition performance, etc. Necessary considerations of diverse traffic situations and safety factors of autonomous driving have also increased the complexity of embedded software as well as architecture of autonomous driving. In these circumstances, there are almost countless numbers of possible architecture designs. However, these design considerations have significant impacts on cost, controllability, and system reliability. Thus, it is crucial for the designers to make a challenging and critical design decision under several uncertainties during the conceptual design phase.

Fog and drizzle observations collected during the arctic weather and SAR (Search and Rescue) operations (SAAWSO) project at sub-freezing temperatures (T) are analyzed in this study to identify icing conditions, improve ground-based in-situ and remote sensing observations, and develop icing parameterizations for numerical weather prediction (NWP) models. The SAAWSO project took place during the 2012-2013 winter conditions that occurred over St. John's, NFL, Canada. Observations were obtained by a Droplet Measuring Technologies Fog Measuring Device (FMD), a ground cloud imaging probe (GCIP), a Radiometrics Profiling Microwave Radiometer (PMWR), a Rosemount icing detector, a laser disdrometer, and surface meteorological sensors. Precipitation, wind, and radiation data were also collected. Results suggest that observations obtained from integrated in-situ and remote sensors can be used to characterize icing conditions.

The focus of this study was the characterization and comparison of power-specific exhaust emission rates from a closed-loop small spark-ignited engine fuelled with ethanol and isobutanol gasoline blends. A 4-cycle Kohler ECH-630 engine certified to the Phase 3 emissions standards was operated over the G2 test cycle, a six-mode steady-state test cycle, in its original configuration. This engine was equipped with electronic ignition, electronic fuel injection and an oxygen sensor. Certification gasoline fuel was splash-blended by percent volume with ethanol and isobutanol to result in the test blend levels of E10, E15, iB16 and iB8-E10. Reductions in emission rates of carbon monoxide (up to 12.0% with the ethanol blends and up to 11.4% with the isobutanol blends) were achieved along with a reduction in total hydrocarbons (up to 10.9% with the ethanol blends and up to 8.2% with the isobutanol blends). Nitrogen oxide emissions were decreased by up to 9.8% with the ethanol blends.

We report on a feasibility study of an optical micro-electro-mechanical systems (MEMS) flow sensor to measure flow rate using Moiré fringe displacement of a floating element. Due to constraints on weight, power, and size for space environmental systems, the development of sensor components that minimize the equivalent systems mass (ESM) while maintaining or exceeding required specifications is highly desirable. A feature of the optical detection method is a physical separation of electrical components from the flow stream. The geometric Moiré fringe shift optically amplifies small displacements by the ratio of the fringe pitch to the movable grating pitch that is detected using an external CCD imager, providing an electrically isolated, robust, direct scheme for detecting flow from shear stress induced displacement.

Internal combustion engines for plug-in hybrid heavy duty trucks, especially long haul trucks, could play an important role in facilitating use of battery power. Power from a low carbon electricity source could thereby be employed without an unattractive vehicle cost increase or range limitation. The ideal engine should be powered by a widely available affordable liquid fuel, should minimize air pollutant emissions, and should provide lower greenhouse gas emissions. Diesel engines could fall short in meeting these objectives, especially because of high emissions. In this paper we analyze the potential for a flex fuel gasoline-alcohol engine approach for a series hybrid powertrain. In this approach the engine would provide comparable (or possibly greater) efficiency than a diesel engine while also providing 90 around lower NOx emissions than present cleanest diesel engine vehicles. Ethanol or methanol would be employed to increase knock resistance.

The NOx emissions during the crank-start and cold fast-idle phases of a GDI engine are analyzed in detail. The NOx emissions of the first 3 firing cycles are studied under a wide set of parameters including the mass of fuel injected, start of injection, and ignition timing. The results show a strong dependence of the NOx emissions with injection timing; they are significantly reduced as the mixture is stratified. The impact of different valve timings on crank-start NOx emissions was analyzed. Late intake and early exhaust timings show similar potential for NOx reduction; 26-30% lower than the baseline. The combined strategy, resulting in a large symmetric negative valve overlap, shows the greatest reduction; 59% lower than the baseline. The cold fast-idle NOx emissions were studied under different equivalence ratios, injection strategies, combustion phasing, and valve timings. Slightly lean air-fuel mixtures result in a significant reduction of NOx.