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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Lean-burn combustion is an effective method for increasing the thermal efficiency of gasoline engines fueled with stoichiometric fuel-air mixture, but leads to an unacceptable level of high cyclic variability before reaching ultra-low nitrogen oxide (NOx) emissions emitted from conventional gasoline engines. Multi-point micro-flame ignited (MFI) hybrid combustion was proposed to overcome this problem, and can be can be grouped into double-peak type, ramp type and trapezoid type with very low frequency of appearance. This research investigates the micro-flame ignition stages of double-peak type and ramp type MFI combustion captured by high speed photography. The results show that large flame is formed by the fast propagation of multi-point flame occurring in the central zone of the cylinder in the double-peak type. However, the multiple flame sites occur around the cylinder, and then gradually propagate and form a large flame accelerated by the independent small flame in the ramp type.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

This paper is a complementary to previous investigations by the authors (1,2,3,4) on the different effects of EGR on combustion and emissions in DI diesel engine. In addition to the several effects that cold EGR has on combustion and emissions the application of hot EGR results in increasing the inlet charge temperature, thereby, for naturally aspirated engines, lowering the inlet charge mass due to thermal throttling. An associated consequence of thermal throttling is the reduction in the amount of oxygen in the inlet charge. Uncooled EGR, therefore, affects combustion and emissions in two ways: through the reduction in the inlet charge mass and through the increase in inlet charge temperature. The effect on combustion and emissions of increasing the inlet charge temperature (without reducing the inlet charge mass) has been dealt with in ref. (1).

The effects of load, speed, exhaust gas recirculation (EGR) level and hydrogen addition level on the emissions from a diesel engine have been investigated. The experiments were performed on a 2.0 litre, 4 cylinder, direct injection engine with a high pressure common-rail injection system. Injection timing was varied between 14° BTDC and TDC and injection pressures were varied from 800 bar to 1400 bar to find a suitable base point. EGR levels were then varied from 0% to 40%. Hydrogen induction was varied between 0 and 6% vol. of the inlet charge. In the case of using hydrogen and EGR, the hydrogen replaced air. The load was varied from 0 to 5.4 bar BMEP at two engine speeds, 1500 rpm and 2500 rpm. For this investigation the carbon monoxide (CO), total unburnt hydrocarbons (THC), nitrogen oxides (NOx) and the filter smoke number (FSN) were all measured.

Controlled Auto-Ignition (CAI), also known as HCCI (Homogeneous Charge Compression Ignition), is increasingly seen as a very effective way of lowering both fuel consumption and emissions from gasoline engines. Therefore, it's seen as one of the best ways to meet future engine emissions and CO2 legislations. This combustion concept was achieved in a Ford production, port-injected, 4 cylinder gasoline engine. The only major modification to the original engine was the replacement of the original camshafts by a new set of custom made ones. The CAI operation was accomplished by means of using residual gas trapping made possible by the use of VCT (variable cam timing) on both intake and exhaust camshafts. When running on CAI, the engine was able to achieve CAI combustion with in a load range of 0.5 to 4.5 BMEP, and a speed range of 1000 to 3500 rpm. In addition, spark assisted CAI operation was employed to extend the operational range of low NOx and low pumping loss at part-load conditions.

The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.

The spark-assisted compression ignition (SACI) is widely used to expend the high load limit of homogeneous charge compression ignition (HCCI), as it can reduce the high heat release rate effectively while partially maintain the advantage of high thermal efficiency and low NOx emission. But as engine load increases, the SACI combustion traditionally using negative valve overlap strategy (NVO) faces the drawback of higher pumping loss and limited intake charge availability, which lead to a restricted load expansion and a finite improvement of fuel economy. In this paper, research is focused on the SACI combustion using positive valve overlap (PVO) strategy. The characteristics of SACI combustion employing PVO strategy with external exhaust gas recirculation (eEGR) are investigated. Two types of PVO strategies are analyzed and compared to explore their advantages and defects, and the rules of adjusting SACI combustion with positive valve overlap are concluded.

Controlled Auto-Ignition (CAI), also known as Homogeneous charge compression ignition (HCCI), has been the subject of extensive research because of their ability to providing simultaneous reduction in fuel consumption and NOx emissions in a gasoline engine. However, due to its limited operation range, combustion mode switching between CAI and spark ignition (SI) combustion is essential to cover the overall operational range of a gasoline engine for passenger car applications. Previous research has shown that the SI-CAI hybrid combustion has the potential to control the ignition timing and heat release process during both steady state and transient operations. However, it was found that the SI-CAI hybrid combustion process is often characterized with large cycle-to-cycle variations, due to the flame instability at high dilution conditions.

The application of controlled auto-ignition (CAI) combustion in gasoline direct injection (GDI) engines is becoming of more interest due to its great potential of reducing both NOx emissions and fuel consumption. Injection timing has been known as an important parameter to control CAI combustion process. In this paper, the effect of injection timing on mixture and CAI combustion is investigated in a single-cylinder GDI engine with an air-assisted injector. The liquid and vapour phases of fuel spray were measured using planar laser induced exciplex fluorescence (PLIEF) technique. The result shows that early injection led to homogeneous mixture but late injection resulted in serious stratification at the end of compression. CAI combustion in this study was realized by using short-duration camshafts and early closure of the exhaust valves. During tests, the engine speed was varied from 1200rpm to 2400rpm and A/F ratio from stoichiometric to lean limit.

Controlled Auto Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), is one of the most promising combustion technologies to reduce the fuel consumption and NOx emissions. Currently, CAI combustion is constrained at part load operation conditions because of misfire at low load and knocking combustion at high load, and the lack of effective means to control the combustion process. Extending its operating range including high load boundary towards full load and low load boundary towards idle in order to allow the CAI engine to meet the demand of whole vehicle driving cycles, has become one of the key issues facing the industrialisation of CAI/HCCI technology. Furthermore, this combustion mode should be compatible with different fuels, and can switch back to conventional spark ignition operation when necessary. In this paper, the CAI operation is demonstrated on a 2-stroke gasoline direct injection (GDI) engine equipped with a poppet valve train.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

Having achieved CAI-combustion in a 4-cylinder four-stroke gasoline DI engine the effects of ignition timing on the CAI combustion process were investigated through the introduction of spark. By varying the start of fuel injection, the effects on Indicated Specific values for NOx, HC, CO emissions and fuel consumption were investigated for CAI combustion. The CAI combustion process was then assisted by spark and three different ignition timings were studied. The effect on engine performance and the emission specific values were investigated further. The engine speed was maintained at 1500 rpm and lambda was kept constant at 1.2. It was found that with spark-assisted CAI, IMEP and ISNOx values increased as compared with typical CAI. ISHC values were lower for spark-assisted CAI as compared to typical CAI. Heat release data was studied to better understand this phenomenon.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

The purpose of the 4-SPACE (4-Stroke Powered gasoline Auto-ignition Controlled combustion Engine) industrial research project is to research and develop an innovative controlled auto-ignition combustion process for lean burn automotive gasoline 4-stroke engines application. The engine concepts to be developed could have the potential to replace the existing stoichiometric / 3-way catalyst automotive spark ignition 4-stroke engines by offering the potential to meet the most stringent EURO 4 emissions limits in the year 2005 without requiring DeNOx catalyst technology. A reduction of fuel consumption and therefore of corresponding CO2 emissions of 15 to 20% in average urban conditions of use, is expected for the « 4-SPACE » lean burn 4-stroke engine with additional reduction of CO emissions.

Controlled Auto-Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), has the potential to improve gasoline engines’ efficiency and simultaneously achieve ultra-low NOx emissions. Two of the primary obstacles for applying CAI combustion are the control of combustion phasing and the maximum heat release rate. To solve these problems, dimethyl ether (DME) was directly injected into the cylinder to generate multi-point micro-flame through compression in order to manage the entire heat release of gasoline in the cylinder through port fuel injection, which is known as micro-flame ignited (MFI) hybrid combustion.

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

Controlled Auto-Ignition (CAI) combustion, also known as Homogeneous Charge Compression Ignition (HCCI), has the potential to simultaneously reduce the fuel consumption and nitrogen oxides emissions of gasoline engines. However, narrow operating region in loads and speeds is one of the challenges for the commercial application of CAI combustion to gasoline engines. Therefore, the extension of loads and speeds is an important prerequisite for the commercial application of CAI combustion. The effect of intake charge boosting, charge stratification and spark-assisted ignition on the operating range in CAI mode was reviewed. Stratified flame ignited (SFI) hybrid combustion is one form to achieve CAI combustion under the conditions of highly diluted mixture caused by the flame in the stratified mixture with the help of spark plug.

Controlled Auto-Ignition (CAI), also known as Homogeneous Charge Compression Ignition (HCCI), can improve the fuel economy of gasoline engines and simultaneously achieve ultra-low NOx emissions. However, the difficulty in combustion phasing control and violent combustion at high loads limit the commercial application of CAI combustion. To overcome these problems, stratified mixture, which is rich around the central spark plug and lean around the cylinder wall, is formed through port fuel injection and direct injection of gasoline. In this condition, rich mixture is consumed by flame propagation after spark ignition, while the unburned lean mixture auto-ignites due to the increased in-cylinder temperature during flame propagation, i.e., stratified flame ignited (SFI) hybrid combustion.