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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

In today's highly competitive automotive markets manufacturers must provide high quality products to survive. Manufacturers can achieve higher levels of quality by changing or improving their manufacturing process and/or by product inspection where many strategies with different cost implications are often available. Cost of Quality (CoQ) reconciles the competing objectives of quality maximization and cost minimization and serves as a useful framework for comparing available manufacturing process and inspection alternatives. In this paper, an analytic CoQ framework is discussed and some key findings are demonstrated using a set of basic inspection strategy scenarios. A case of a welded automotive assembly is chosen to explore the CoQ tradeoffs in inspection strategy selection and the value of welding process improvement. In the assembly process, many individual components are welded in series and each weld is inspected for quality.

Astrium investigates Methane Pyrolysis in the perspective of long-duration exploration missions. In particular this process, which recovers Hydrogen from Methane, allows reaching the maximum closure level of the Air Revitalization System ARES. Past studies were reviewed in the light of today's technical advancement and a technology trade-off, supported by bread boarding, is performed. Current activities do concentrate on Critical technology selection and feasibility demonstration including bread boarding and testing, Methane Pyrolysis Assembly (MPA) operational interfaces with ARES Potential applications of MPA for other exploration capabilities, like in-situ resources utilization (Moon and Mars) The paper presents the achievements so far.

During the last years extensive work has been done to design and develop the Closed-Loop Air Revitalization System ARES. The potential of ARES e.g. as part of the ISS ECLSS is to significantly reduce the water upload demand and to increase the safety of the crew by reducing dependence on re-supply flights. The design is adapted to the interfaces of the new base lined Russian MLM module as possible location for a future installation of ARES. Due to the lack of orbital support equipment and interfaces to a waste water bus, to a feed water supply line and due to the availability of only one single vent line it was necessary to make the ARES process water loop as independent as possible from the host vehicle. Another optimization effort was to match the CO2 desorption profile with the available hydrogen flow to achieve a sufficient water recovery performance, while meeting all related safety requirements, minimizing complexity and improving reliability.

The life of an automotive engine is often limited by the ability of its components to resist wear. Zinc dialkyldithiophosphate (ZDDP) is an engine oil additive that reduces wear in an engine by forming solid antiwear films at points of moving contact. The effects of this additive are fairly well understood, but there is little theory behind the kinetics of antiwear film formation and removal. This lack of dynamic modeling makes it difficult to predict the effects of wear at the design stage for an engine component or a lubricant formulation. The purpose of this discussion is to develop a framework for modeling the formation and evolution of ZDDP antiwear films based on the relevant chemical pathways and physical mechanisms at work.

Astrium investigates Methane Pyrolysis in the perspective of long-duration exploration missions. In particular this process, which recovers Hydrogen from Methane, allows reaching the maximum closure level of the Air Revitalization System ARES, see figure 1. Past studies as presented in ref. /1/ had been reviewed in light of today's technical advancement and a technology trade-off, supported by bread boarding, resulting in the pre selection of the plasma technique to perform the Methane Pyrolysis. In parallel two methods for plasma provision are investigated: Direct Current Plasma, sustained by a discharge arc rotating in a nozzle to supply energy to the flowing through carrier gas. Micro Wave (MW) Plasma, sustained by a MW within a Quartz tube embedded in a MW resonator cuboid Study activities did concentrate on Development testing of pre selected plasma Pyrolysis technology.

ESA has been developing regenerative physicochemical air revitalisation technology for more than 20 years. The effort is now maturing into a flight demonstration experiment which is planned to be located in the Columbus module on ISS. The experiment shall be sized for a crew of three. It will comprise a CO2 concentration assembly, a Sabatier reactor and an electrolyser. The paper describes the adaptation of ARES to the available Columbus interfaces as well as ARES development status, performances, benefits to the ISS and operational agreements with ISS partners.

This paper illustrates a methodology in which complete material-manufacturing process cases for closure panels, reinforcements, and assembly are modeled and compared in order to identify the preferred option for a lightweight closure design. First, process-based cost models are used to predict the cost of lightweighting the closure set of a sample midsized sports utility vehicle (SUV) via material and process substitution. Weight savings are then analyzed using a powertrain simulation to understand the impact of lightweighting on fuel economy. The results are evaluated in the context of production volume and total mass change.

Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.

A new monitoring system predicts the progression of welding temperature fields during resistance spot welding. The system captures welding voltages and currents to predict contact diameters and simulate temperature fields. The system accurately predicts fusion lines and heat-affected zones. Accuracy holds even for electrode tips used for a few thousand welds of zinc coated steels.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

The piston skirt is an important contributor of friction in the piston assembly. This paper discusses friction contributions from various aspects of the piston skirt. A brief study of piston skirt patterns is presented, with little gains being made by patterning the piston skirt coating. Next the roughness of the piston skirt coating is analyzed, and results show that reducing piston skirt roughness can have positive effects on friction reduction. Finally, an introductory study into the profile of the piston skirt is presented, with the outcome being that friction reduction is possible by optimizing the skirt profile.

EADS SPACE Transportation investigates Methane Pyrolysis in the perspective of long-duration exploration missions. In particular this process, which recovers Hydrogen from Methane, allows reaching the maximum closure level of the Air Revitalization System ARES. Past studies are reviewed in the light of today's technical advancement and a technology trade-off, supported by breadboarding, is performed. Accordingly, current activities do concentrate on Critical technology selection and feasibility demonstration including breadboarding and testing, Methane Pyrolysis Assembly (MPA) operational interfaces with ARES Potential applications of MPA for other exploration capabilities, like in-situ resources utilization (Moon and Mars) The paper presents the achievements so far.

EADS SPACE Transportation GmbH designed, built and tested a condensate buffer to be located between a Condensing Heat Exchanger (CHX) and a Condensate Water Separator Assembly (CWSA), as part of the ECLSS of the European Columbus Module. Under zero-g conditions, the separation of water from an air-water mixture is always difficult, especially if a passive device is to be used such as the low power consuming Columbus CWSA. The additional buffer volume reduces condensate water peaks reaching the CWSA to a level that excludes an overloading of the CWSA and a release of free water droplets into the air return to the cabin. In the CHX/CWSA system this may only be necessary under worst case operational conditions and with a failure of the qualified hydrophilic coating of the CHX. The buffer design principle was confirmed via prior analyses and on-ground testing. The performance of such a condensate buffer under micro-g conditions was verified during parabolic flights.

The quest for higher efficiency and performance of automotive vehicles requires application of materials with high strength, stiffness and lower weight in their construction. Particulate-reinforced aluminum-matrix composites are cost-competitive materials, which can meet these requirements. MMCC, Inc. has been optimizing particulate-reinforced alloy systems and developing the Advanced Pressure Infiltration Casting (APIC™) process for the manufacture of components from these materials. This paper discusses the results of a recent study in which composites reinforced with 55 vol.% alumina were cast using two sizes of alumina particulate and eight different matrix alloys based on Al-4.5 wt.% Cu with varying amounts of silicon and magnesium. Optimum heat treatments for each alloy were determined utilizing microhardness studies. The tensile strength and fracture toughness were evaluated as a function of alloy chemistry, particulate size, and heat treatment.

Painting is the most expensive unit operation in automobile manufacturing and the source of over 90 percent of the air, water and solid waste emissions at the assembly plant. While innovative paint technologies such as waterborne or powder paints can potentially improve plant environmental performance, implementing these technologies often requires major capital investment. A process-based technical cost model was developed for examining the environmental and economic implications of automotive painting at the unit operation level. The tradeoffs between potential environmental benefits and their relative costs are evaluated for current and new technologies.

A novel system for the forming of three dimensional sheet metal parts is described that can form a variety of part shapes without the need for fixed tooling, and given only geometry (CAD) information about the desired part. The central elements of this system are a tooling concept based on a programmable discrete die surface and closed-loop shape control. The former give the process the degrees of freedom to change shape rapidly, and the latter is used to insure that the correct shape is formed with a minimum of forming trials. A 540 kN (60 ton) lab press has been constructed with a 0.3 m (12 in) square pair of discrete tools that can be rapidly re-shaped between forming trials. The shape control system uses measured part shapes to determine a shape error and to correct the tooling shape. This correction is based on a unique “Deformation Transfer Function” approach using a spatial frequency decomposition of the surface.

In this paper we investigate the optimal forming of conical cups of AL 2008-T4 through the use of real-time process control. We consider a flat, frictional binder the force of which can be determined precisely through closed-loop control. Initially the force is held constant throughout the forming of the cup, and various levels of force are tested experimentally and with numerical simulation. Excellent agreement between experiment and simulation is observed. The effects of binder force on cup shape, thickness distribution, failure mode and cup failure height are investigated, and an “optimal” constant binder force is determined. For this optimal case, the corresponding punch force is recorded as a function of punch displacement and is used in subsequent closed-loop control experiments. In addition to the constant force test, a trial variable binder force test was performed to extend the failure height beyond that obtained using the “optimal” constant force level.