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A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.

Exhaust Emission Control: DPF Systems. Presenter Shingo Iwasaki, NGK Insulators, Ltd.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.

This paper details the design and operating attributes of a triple input clutch, layshaft automatic transmission (TCT) with a torque converter in a rear wheel drive passenger vehicle. The objectives of the TCT design are to reduce fuel consumption while increasing acceleration performance through the design of the gearing arrangement, shift actuation system and selection of gear ratios and progression. A systematic comparison of an 8-speed TCT design is made against a hypothetical 8-speed planetary automatic transmission (AT) with torque converter using an energy analysis model based upon empirical data and first principles of vehicle-powertrain systems. It was found that the 8-speed TCT design has the potential to provide an approximate 3% reduction in fuel consumption, a 3% decrease in 0-100 kph time and 30% reduction in energy loss relative to a comparable 8-speed planetary AT with an idealized logarithmic ratio progression.

The field of automotive engineering has devoted much research to reduce fuel consumption to attain sustainable energy usage. Friction reductions in powertrain components can improve engine fuel economy. Quantitative accounting of friction is complex because it is affected by many physical aspects such as oil viscosity, temperature, surface roughness and component rotation speed. The purpose of this paper is two-fold: first, to develop a useful tool for evaluating the friction in engine and accessories based on test data; second, to exercise the tool to evaluate the fuel economy gain in a drive cycle for several friction reduction technologies.

As the piston pin works under significant mechanical load, it is susceptible to wear, seizure, and structural failure, especially in heavy duty internal combustion engines. It has been found that the friction loss associated with the pin is comparable to that of the piston, and can be reduced when the interface geometry is properly modified. However, the mechanism that leads to such friction reduction, as well as the approaches towards further improvement, remain unknown. This work develops a piston pin lubrication model capable of simulating the interaction between the pin, the piston, and the connecting rod. The model integrates dynamics, solid contact, oil transport, and lubrication theory, and applies an efficient numerical scheme with second order accuracy to solve the highly stiff equations. As a first approach, the current model assumes every component to be rigid.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

This investigation was aimed at measuring the relative performance of two spray-guided, single-cylinder, spark-ignited direct-injected (SIDI) engine combustion system designs. The first utilizes an outwardly-opening poppet, piezo-actuated injector, and the second a conventional, solenoid operated, inwardly-opening multi-hole injector. The single-cylinder engine tests were limited to steady state, warmed-up conditions. The comparison showed that these two spray-guided combustion systems with two very different sprays had surprisingly close results and only differed in some details. Combustion stability and smoke emissions of the systems are comparable to each other over most of the load range. Over a simulated Federal Test Procedure (FTP) cycle, the multi-hole system had 15% lower hydrocarbon and 18% lower carbon monoxide emissions.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

Mid 2006 a study group at General Motors developed the concept for the electric vehicle with extended range (EREV),. The electric propulsion system should receive the electrical energy from a rechargeable energy storage system (RESS) and/or an auxiliary power unit (APU) which could either be a hydrogen fuel cell or an internal combustion engine (ICE) driven generator. The study result was the Chevrolet VOLT concept car in the North American Auto Show in Detroit in 2007. The paper describes the requirements, concepts, development and the performance of the battery used as RESS for the ICE type VOLTEC propulsion system version of the Chevrolet Volt. The key requirement for the RESS is to provide energy to drive an electric vehicle with “no compromised performance” for 40 miles. Extended Range Mode allows for this experience to continue beyond 40 miles.

This paper describes rationale for determining the apportionment of variable or ‘shuttered’ airflow and non-variable or static airflow through openings in the front of a vehicle as needed for vehicle cooling. Variable airflow can be achieved by means of a shutter system, which throttles airflow through the front end and into the Condenser, Radiator, and Fan Module, (CRFM). Shutters originated early in the history of the auto industry and acted as a thermostat [1]. They controlled airflow as opposed to coolant flow through the radiator. Two benefits that are realized today are aerodynamic and thermal gains, achieved by restricting unneeded cooling airflow. Other benefits exist and justify the use of shutters; however, there are also difficulties in both execution and practical use. This paper will focus on optimizing system performance and execution in terms of the two benefits of reduced aerodynamic drag and reduced mechanical drag through thermal control.

Cast aluminum alloys are increasingly used in cyclically loaded automotive structural applications for light weight and fuel economy. The fatigue resistance of aluminum castings strongly depends upon the presence of casting flaws and characteristics of microstructural constituents. The existence of casting flaws significantly reduces fatigue crack initiation life. In the absence of casting flaws, however, crack initiation occurs at the fatigue-sensitive microstructural constituents. Cracking and debonding of large silicon (Si) and Fe-rich intermetallic particles and crystallographic shearing from persistent slip bands in the aluminum matrix play an important role in crack initiation. This paper presents fatigue life models for aluminum castings free of casting flaws, which complement the fatigue life models for aluminum castings containing casting flaws published in [1].

Compressed natural gas (CNG) currently is used as an alternative fuel for internal combustion engines in motor vehicles. This paper presents results of an analysis of leaks from a model isolated section of CNG fuel system. Discharge of CNG was modeled as vent flow of a real gas hydrocarbon mixture through an orifice from a reservoir with finite volume. Pressures typically used in CNG fuel systems result in choked flow for gas venting directly to atmosphere, producing an under-expanded, momentum-dominated, turbulent free jet with well defined velocity and concentration fields. This paper presents results of analyses of reservoir pressure decay, and vent flow and concentrations fields for CNG venting from a pressurized reservoir into the atmosphere. A combination of empirically-derived analytical relationships and detailed two-dimensional high resolution computational fluid dynamic modeling was used to determine the velocity and concentrations fields of the resulting CNG jet.