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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

A task group within the SAE Automotive Corrosion and Protection (ACAP) Committee continues to pursue the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. The program is a cooperative effort with OEM, supplier, and consultant participation and is supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels, but correlations between laboratory test results and in-service performance have not been established. The primary objective of this project is to identify an accelerated laboratory test method that correlates with in-service performance. In this paper the type, extent, and chemical nature of cosmetic corrosion observed in the on-vehicle exposures are compared with those from some of the commonly used laboratory tests

Over the past several years a task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has conducted extensive on-vehicle field testing and numerous accelerated lab tests with the goal of establishing a standard accelerated test method for cosmetic corrosion evaluations of finished aluminum auto body panels. This project has been a cooperative effort with OEM, supplier, and consultant participation and was also supported in part by DOE through USAMP (AMD 309). The focus of this project has been the identification of a standardized accelerated cosmetic corrosion test that exhibits the same appearance, severity, and type of corrosion products that are exhibited on identical painted aluminum panels exposed to service relevant environments. Multi-year service relevant exposures were conducted by mounting panels on-vehicles in multiple locations in the US and Canada.

Engine oils formulated using molybdenum dialkyldithiocarbamate, Mo(dtc)2, additives can provide substantial friction reduction under mixed to boundary lubrication conditions. It has been previously shown that the effectiveness of Mo(dtc)2 is significantly affected by the presence of other additives and by additive interaction and depletion processes occurring during use. In this study, ligand exchange reactions in an additive system containing Mo(dtc)2 and zinc dialkyldithiophosphate, Zn(dtp)2, have been investigated during oxidation in hexadecane and various base oils at 160°C. Samples of different composition obtained from these studies were used in investigations of the effects of original additives and ligand exchange products on friction reducing capability at 45 and 105°C.

Since 2000, an Aluminum Cosmetic Corrosion task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has existed. The task group has pursued the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. A cooperative program uniting OEM, supplier, and consultants has been created and has been supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Prior to this committee's formation, numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels. However, correlations between these laboratory test results and in-service performance have not been established. Thus, the primary objective of this task group's project was to identify an accelerated laboratory test method that correlates well with in-service performance.

An electrochemical testing protocol for assessing the intrinsic corrosion-resistance of creep-resistant magnesium alloys in aqueous environments, and effects of passivating surface films anticipated to develop in the presence of engine coolants is under development. This work reports progress in assessing the relative corrosion resistance of the base metals (AMC-SC1, MRI-202S, MRI-230D, AM50 and 99.98% Mg) in a common test environment, based on a near-neutral pH buffered saline solution, found to yield particularly stable values for the open-circuit or corrosion potential. This approach was found to provide a platform for the eventual assessment of the durability of certain passivating layers expected to develop during exposure of the magnesium alloys to aqueous coolants.

There is an increasing global realization about the need for fuel efficient vehicles. An inexpensive way to accomplish this is through mass reduction, and one of the most effective ways that this can occur is through substituting current materials with magnesium, the lightest structural metal. This document describes the results of a U.S. Automotive Materials Partnership (USAMP) sponsored study [1] that examines why magnesium use has only grown 10% per year and identifies how to promote more widespread commercial applications beyond the 5-6 kg of component currently in vehicles. The issues and concerns which have limited magnesium use are discussed via a series of research and development themes. These address concerns associated with corrosion, fastening, and minimal metalworking/non-traditional casting processing. The automotive and magnesium supplier industries have only a limited ability to develop implementation-ready magnesium components.

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

This paper presents the progress of an ongoing vehicle micro corrosion environment study. The goal of the study is to develop an improved method for estimating vehicle corrosion based on the Total Vehicle Accelerated Corrosion Test at the Arizona Proving Ground (APG). Although the APG test greatly accelerates vehicle corrosion compared to the field, the “acceleration factor” varies considerably from site-to-site around the vehicle. This method accounts for the difference in corrosivity of various local corrosion environments from site-to-site at APG and in the field. Correlations of vehicle microenvironments with the macroenvironment (weather) and the occurrence of various environmental conditions at microenvironments are essential to the study. A comparison of results from APG versus field measurements generated using a cold rolled steel based corrosion sensor is presented.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.

Meeting upcoming stringent emission standards will require that exhaust gas catalyst systems become active very quickly, function at very high efficiencies and maintain those capabilities at high mileages. This means that contamination of the catalysts by engine oil derived poisons must be minimized. Phosphorus compounds, derived from the zinc dialkyldithio-phosphate (ZDTP) additives that provide antiwear and antioxidant activity, are a principal contaminant that can increase catalyst light off times and reduce catalyst efficiency. Therefore, reducing the concentration of, or eliminating, phosphorus in engine oils is desirable. Doing so, however, requires that oils be reformulated to ensure that wear protection will not be compromised and that oxidation stability will be maintained. To address these concerns, laboratory tests for evaluating oil oxidation and wear performance have been developed and used to evaluate developmental low phosphorus oils.

The Automotive Aluminum Alliance in conjunction with SAE ACAP founded a corrosion task group in 2000 with a goal to establish an in-laboratory cosmetic corrosion test for finished aluminum auto body panels, which provides a good correlation with in-service performance. Development of this test involves a number of key steps that include: (1) Establishing a reservoir of standard test materials to provide a well-defined and consistent frame of reference for comparing test results; (2) Defining a real-world performance for the reference materials through on-vehicle tests conducted in the U.S. and Canada; (3) Evaluating existing laboratory, proving ground, and outdoor tests; (4) Conducting statistically designed experiments to evaluate the effects of cyclic-test variables; (5) Comparing corrosion mechanisms of laboratory and on-vehicle tests; and (6) Conducting a round robin test program to determine the precision of the new test. Several of these key steps have been accomplished.

This paper presents the upgrades and improvements needed to bring an old and seldom used reverberation room test suite up to current standards. The upgrades and improvements included eliminating a below-floor pit that was open to the reverberation room, improving the acoustical diffusion within the room, enlarging the opening between the reverberation room and an adjacent anechoic chamber, renovating the anechoic receiving chamber, constructing an innovative sound transmission loss test fixture, and installing of a high power reverberation room sound system.

Proving Ground cyclic testing was used to evaluate vehicles assembled with electrogalvanized and organic composite coated electrogalvanized steel. These same materials, along with several commonly available precoated steels, were also evaluated as hem flange assemblies on towed trailers at the Proving Ground. Testing was terminated as perforation of some of the assemblies occurred. Pitting depth was used to quantitatively evaluate metal loss.

A laboratory wear test is used to evaluate the wear protection properties of new and used engine oils formulated for FFV service. Laboratory-blended mixtures of these oils with methanol and water have also been tested. The test consists of a steel ball rotating against three polished cast iron discs. Oil samples are obtained at periodic intervals from a fleet of 3.0L Taurus vehicles operating under controlled go-stop conditions. To account for the effects of fuel dilution, some oils are tested before and after a stripping procedure to eliminate gasoline, methanol and other volatile components. In addition to TAN and TBN measurements, a capillary electrophoresis technique is used to evaluate the formate content in the oils. The results suggest that wear properties of used FFV lubricants change significantly with their degree of usage.

As automobile power needs increase 42-volt electrical systems are being proposed for use in consumer vehicles. One concern when using these new systems is the corrosion resistance of these components, especially in underhood environments. Corrosion is an electrochemical phenomenon and as such can be altered (increased or decreased) by the application of an external current or voltage. Although unintentional, the use of a higher voltage electrical system has the ability to increase corrosion through its normal use. This program evaluated the impact of corrosion on electrical components powered by 14 and 42-volt DC systems. Accelerated corrosion test findings suggested that 42-volt systems may be more susceptible to corrosion, but without proper environmental shielding both supply system can have unacceptable degradation.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.