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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.

The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this study, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications.

The goal of this interview analysis was to explore and document the perceptions of two unique lane centering systems (S90’s Pilot Assist and CT6’s Super Cruise). Both systems offer a similar type of functionality (adaptive cruise control and lane centering), but have significantly different design philosophies and HMI (Human-Machine Interface) implementations. Twenty-four drivers drove one of the two vehicle models for a month as part of a field operational test (FOT) study. Upon vehicle return, drivers took part in a 60-minute semi-structured interview covering their perceptions of the vehicle’s various advanced driver-assistance systems (ADAS). Transcripts of the interviews were coded by two researchers, who tagged each statement with relevant system and perception code labels. For analysis, the perception codes were grouped into larger thematic bins of safety, comfort, driver attention, and system performance.

Rare earths are a group of elements whose availability has been of concern due to monopolistic supply conditions and environmentally unsustainable mining practices. To evaluate the risks of rare earths availability to automakers, a first step is to determine raw material content and value in vehicles. This task is challenging because rare earth elements are used in small quantities, in a large number of components, and by suppliers far upstream in the supply chain. For this work, data on rare earth content reported by vehicle parts suppliers was assessed to estimate the rare earth usage of a typical conventional gasoline engine midsize sedan and a full hybrid sedan. Parts were selected from a large set of reported parts to build a hypothetical typical mid-size sedan. Estimates of rare earth content for vehicles with alternative powertrain and battery technologies were made based on the available parts' data.

This paper presents a new methodology for the safety assessment of complex software intensive systems such as is envisioned for the coming major upgrade of the air traffic management system known as NextGen. This methodology is based on a new, more inclusive model of accident causation called Systems Theoretic Accident Model and Process (STAMP) [1]. STAMP includes not just the standard component failure mechanisms but also the new ways that software and humans contribute to accidents in complex systems. A new hazard analysis method, called Systems Theoretic Process Analysis (STPA), is built on this theoretical foundation. The STPA is based on systems theory rather than reliability theory; it treats safety as a control problem rather than a failure problem with interactive and possibly nested control loops that may include humans. In this methodology, safety is assured by closed loop control of safety parameters.

Air-launched Small Unmanned Aerial Systems (SUASs) provide critical information to warfighters, but are currently limited by the power and energy available from small electric propulsion systems. This paper describes proof-of-concept testing of a novel power system for SUASs. The power system comprises a compact hydrogen generator and a hydrogen PEM fuel cell. The hydrogen generator uses ammonia borane (AB) as a solid chemical hydrogen storage material and heats the AB to produce hydrogen through thermal decomposition. The innovative ignition and control process generates highly pure hydrogen on-demand from a system that is very compact, lightweight, and rugged. We built a proof-of-concept hydrogen generator and used it to supply hydrogen to a small PEM fuel cell. The proof-of-concept generator used prototypical AB, heat source, control scheme, and purification media to absorb trace amounts of ammonia, borazine, and carbon monoxide (CO).

Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.

Diesel engine exhaust aftertreatment components, especially the diesel particulate filter (DPF), are subject to various modes of degradation over their lifetimes. One particular adverse effect on the DPF is the significant rise in pressure drop due to the accumulation of engine lubricant-derived ash which coats the inlet channel walls effectively decreasing the permeability of the filter. The decreased permeability due to ash in the DPF can result in increased filter pressure drop and decreased fuel economy. A unique two-step approach, consisting of experimental measurements and direct numerical simulations using ultra-high resolution 3D imaging data, has been utilized in this study to better understand the effects of ash accumulation on engine aftertreatment component functionality.

The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.

To address the growing need for detailed chemistry in engine simulations, new software tools and validated data sets are being developed under an industry-funded consortium involving members from the automotive and fuels industry. The results described here include systematic comparison and validation of detailed chemistry models using a wide range of fundamental experimental data, and the development of software tools that support the use of detailed mechanisms in engineering simulations. Such tools include the automated reduction of reaction mechanisms for targeted simulation conditions. Selected results are presented and discussed.

The NASA-wide CEV Smart Buyer Team (SBT) was assembled in January 2006 and was tasked with the development of a NASA in-house design for the CEV Crew Module (CM), Service Module (SM), and Launch Abort System (LAS). This effort drew upon over 250 engineers from all of the 10 NASA Centers. In 6 weeks, this in-house design was developed. The Thermal Systems Team was responsible for the definition of the active and passive design architecture. The SBT effort for Thermal Systems can be best characterized as a design architecting activity. Proof-of-concepts were assessed through system-level trade studies and analyses using simplified modeling. This nimble design approach permitted definition of a point design and assessing its design robustness in a timely fashion. This paper will describe the architecting process and present trade studies and proposed thermal designs

For NASA's Constellation Program, an Intravehicular Activity (IVA) and Extravehicular Activity (EVA) Life Support Umbilical System (LSUS) will be required to provide environmental protection to the suited crew during Crew Exploration Vehicle (CEV) cabin contamination or depressurization and contingency EVAs. The LSUS will provide the crewmember with ventilation, cooling, power, communication, and data, and will also serve as a crew safety restraint during contingency EVAs. The LSUS will interface with the Vehicle Interface Assembly (VIA) in the CEV and the Suit Connector on the suit. This paper describes the effort performed to develop concept designs for IVA and EVA umbilicals, universal multiple connectors, handling aids and stowage systems, and VIAs that meet NASA's mission needs while adhering to the important guiding principles of simplicity, reliability, and operability.

Development of new air revitalization system (ARS) technology can initially be performed in a subscale laboratory environment, but in order to advance the maturity level, the technology must be tested in an end-to-end integrated environment. The Air Revitalization Technology Evaluation Facility (ARTEF) at the NASA Johnson Space Center (JSC) serves as a ground test bed for evaluating emerging ARS technologies in an environment representative of spacecraft atmospheres. At the center of the ARTEF is a hypobaric chamber which serves as a sealed atmospheric chamber for closed loop testing. A Human Metabolic Simulator (HMS) was custom-built to simulate the consumption of oxygen, and production of carbon dioxide, moisture and heat by up to eight persons. A variety of gas analyzers and dew point sensors are used to monitor the chamber atmosphere and the process flow upstream and downstream of a test article. A robust vacuum system is needed to simulate the vacuum of space.

The new devices and missions to achieve the aims of NASA's Science Mission Directorate (SMD) are creating increasingly demanding thermal environments and applications. In particular, the low conductance of metal-to-metal interfaces used in the thermal switches lengthen the cool-down phase and resource usage for spacecraft instruments. During this work, we developed and tested a vacuum-compatible, durable, heat-conduction interface that employs carbon nanotube (CNT) arrays directly anchored on the mating metal surfaces via microwave plasma-enhanced, chemical vapor deposition (PECVD). We demonstrated that CNT-based thermal interface materials have the potential to exceed the performance of currently available options for thermal switches and other applications.

The importance of being able to determine the usage rate of life support subsystem consumables was recognized well before the first Apollo Extravehicular Activity (EVA). Since that time, metabolic activity levels have been evaluated and recorded for each EVA crew member. Throughout the history of the United States space program, EVA metabolic rates have been shown to be variable depending upon the mission scenario and the equipment used. Knowing this historic information is invaluable for current EVA planning activities, as well as for the design of future Extravehicular Mobility Unit (EMU) systems. This paper presents an overview of historic metabolic expenditures for Apollo, Skylab, and Shuttle missions, along with a discussion of the types of EVA crew member activities which lead to various metabolic rate levels, and a discussion on how this data is being used to develop advanced EMU systems.

Introduction of an array of new electrical and electronic features into future vehicles is generating vehicle electrical power requirements that exceed the capabilities of today's 14 volt electrical systems. In the near term (5 to 10 years), the existing 14V system will be marginally capable of supporting the expected additional loads with escalating costs for the associated charging system. However, significant increases in vehicle functional content are expected as future requirements to meet longer-term (beyond 10 years) needs in the areas of emission control, fuel economy, safety, and passenger comfort. A higher voltage electrical system will be required to meet these future requirements. This paper explores the functional needs that will mandate a higher voltage system and the benefits derivable from its implementation.

NASA's Constellation Program, which includes the mission objectives of establishing a permanently-manned lunar Outpost, and the exploration of Mars, poses new and unique challenges for human life support systems that will require solutions beyond the Shuttle and International Space Station state of the art systems. In particular, the requirement to support crews for extended durations at the lunar outpost with limited resource resupply capability will require closed-loop regenerative life support systems with minimal expendables. Planetary environmental conditions such as lunar dust and extreme temperatures, as well as the capability to support frequent and extended-duration Extra-vehicular Activity's (EVA's) will be particularly challenging.

A reconfigurable control system is an intelligent control system that detects faults within the system and adjusts its performance automatically to avoid mission failure, save lives, and reduce system maintenance costs. The concept was first successfully demonstrated by NASA between December 1989 and March 1990 on the F-15 flight control system (SRFCS), where software was integrated into the aircraft's digital flight control system to compensate for component loss by reconfiguring the remaining control loop. This was later adopted in the Boeing X-33. Other applications include modular robotics, reconfigurable computing structure, and reconfigurable helicopters. The motivation of this work is to test such control system designs for future long term space missions, more explicitly, the automation of life support systems.

We have completed preliminary tests that show the feasibility of an innovative concept for a spacesuit thermal control system using a lightweight, flexible heat pump/radiator. The heat pump/radiator is part of a regenerable LiCI/water absorption cooling device that absorbs an astronaut's metabolic heat and rejects it to the environment via thermal radiation at a relatively high temperature. We identified key design specifications for the system, demonstrated that it is feasible to fabricate the flexible radiator, measured the heat rejection capability of the radiator, and assessed the effects on overall mass of the PLSS. We specified system design features that will enable the flexible absorber/radiator to operate in a wide range of space exploration environments. The materials used to fabricate the flexible absorber/radiator samples were all found to be low off-gassing and many have already been qualified for use in space.