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Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

The objective of this research is a detailed investigation of unburned hydrocarbon (UHC) in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the mechanisms that control the formation of UHC via experiments and simulations in a 0.48L signal-cylinder light duty engine operating at 2000 r/min and 5.5 bar IMEP with multiple injections. A multi-gas FTIR along with other gas and smoke emissions instruments are used to measure exhaust UHC species and other emissions. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, analysis of spray trajectory with a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2].

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

An infrared laser absorption technique has been developed to measure in-cylinder concentrations of CO in an optical, automotive HCCI engine. The diagnostic employs a distributed-feedback, tunable diode laser selected to emit light at the R15 line of the first overtone of CO near 2.3 μm. The collimated laser beam makes multiple passes through the cylinder to increase its path length and its sampling volume. High-frequency modulation of the laser output (wavelength modulation spectroscopy) further enhances the signal-to-noise ratio and detection limits of CO. The diagnostic has been tested in the motored and fired engine, exhibiting better than 200-ppm sensitivity for 50-cycle ensemble-average values of CO concentration with 1-ms time resolution. Fired results demonstrate the ability of the diagnostic to quantify CO production during negative valve overlap (NVO) for a range of fueling conditions.

This paper presents experimental results for two fuel-related topics in a diesel engine: (1) how fuel volatility affects the premixed burn and heat release rate, and (2) how ignition quality influences the soot formation. Fast evaporation of fuel may lead to more intense heat release if a higher percentage of the fuel is mixed with air to form a combustible mixture. However, if the evaporation of fuel is driven by mixing with high-temperature gases from the ambient, a high-volatility fuel will require less oxygen entrainment and mixing for complete vaporization and, consequently, may not have potential for significant heat release simply because it has vaporized. Fuel cetane number changes also cause uncertainty regarding soot formation because variable ignition delay will change levels of fuel-air mixing prior to combustion.

Mixture formation in an optically accessible hydrogen-fueled engine was investigated using Planar Laser-Induced Fluorescence (PLIF) of acetone as a fuel tracer. The engine was motored and fueled by direct high-pressure injection. This paper presents the evolution of the spatial distribution of the ensemble-mean equivalence ratio for six different combinations of nozzle design and injector geometry, each for three different injection timings after intake-valve closure. Asymmetric single-hole and 5-hole nozzles as well as symmetric 6-hole and 13-hole nozzles were used. For early injection, the low in-cylinder pressure and density allow the jet to preserve its momentum long enough to undergo extensive jet-wall and (for multi-hole nozzles) jet-jet interaction, but the final mixture is fairly homogeneous. Intermediately timed injection yields inhomogeneous mixtures with surprisingly similar features observed for all multi-hole injectors.

The effects of spray targeting on mixing, combustion, and pollutant formation under a low-load, late-injection, low-temperature combustion (LTC) diesel operating condition are investigated by optical engine measurements and multi-dimensional modeling. Three common spray-targeting strategies are examined: conventional piston-bowl-wall targeting (152° included angle); narrow-angle floor targeting (124° included angle); and wide-angle piston-bowl-lip targeting (160° included angle). Planar laser-induced fluorescence diagnostics in a heavy-duty direct-injection optical diesel engine provide two-dimensional images of fuel-vapor, low-temperature ignition (H2CO), high-temperature ignition (OH) and soot-formation species (PAH) to characterize the LTC combustion process.

Fuel injection during negative valve overlap (NVO) can extend low-load gasoline HCCI operation through control of main combustion phasing. Reactions and heat release accompanying NVO fuel injection give rise to changes in temperature and composition of the charge prior to main combustion. The extent of reaction of injected NVO fuel and the relative importance of resulting thermal and chemical effects on main combustion are a current research topic. In this work, bulk temperature computations are used to quantify thermal conditions prior to main ignition for cases with and without NVO fueling. To separate measured thermal effects from chemical effects of NVO fuel reactions on the main combustion, cases without NVO fuel but with similar mixture temperatures and combustion phasing are compared. Effects of varying NVO fuel amount and injection timing on heat release, combustion phasing, bulk temperature evolution, and iso-octane ignition temperatures are analyzed.

Multiple fuel-injections during a single engine cycle can reduce combustion noise and improve pollutant emissions tradeoffs. Various hypotheses have been proposed in the literature regarding the in-cylinder processes responsible for the pollutant emissions improvements. This paper provides a brief overview of these hypotheses along with an investigation exploring which of these mechanisms are important for post injections under low-temperature combustion (LTC) conditions in a heavy-duty diesel engine. In-cylinder soot and exhaust smoke are measured by 2-color soot thermometry and filter paper blackening, respectively. The evolution and interaction of soot regions from each of the injections is visualized using high-speed imaging of soot luminosity, both in the piston bowl and in the squish regions.

The influence of soy- and palm-based biofuels on the in-cylinder sources of unburned hydrocarbons (UHC) and carbon monoxide (CO) was investigated in an optically accessible research engine operating in a partially premixed, low-temperature combustion regime. The biofuels were blended with an emissions certification grade diesel fuel and the soy-based biofuel was also tested neat. Cylinder pressure and emissions of UHC, CO, soot, and NOx were obtained to characterize global fuel effects on combustion and emissions. Planar laser-induced fluorescence was used to capture the spatial distribution of fuel and partial oxidation products within the clearance and bowl volumes of the combustion chamber. In addition, late-cycle (30° and 50° aTDC) semi-quantitative CO distributions were measured above the piston within the clearance volume using a deep-UV LIF technique.

The potential of boosted HCCI for achieving high loads has been investigated for intake pressures (Piⁿ) from 100 kPa (naturally aspirated) to 325 kPa absolute. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) equipped with a compression-ratio 14 piston at 1200 rpm. The intake charge was fully premixed well upstream of the intake, and the fuel was a research-grade (R+M)/2 = 87-octane gasoline with a composition typical of commercial gasolines. Beginning with Piⁿ = 100 kPa, the intake pressure was systematically increased in steps of 20 - 40 kPa, and for each Piⁿ, the fueling was incrementally increased up to the knock/stability limit, beyond which slight changes in combustion conditions can lead to strong knocking or misfire. A combination of reduced intake temperature and cooled EGR was used to compensate for the pressure-induced enhancement of autoignition and to provide sufficient combustion-phasing retard to control knock.

One of the issues in stamping of advanced high strength steels (AHSS) is the stretch bending fracture on a sharp radius (commonly referred to as shear fracture). Shear fracture typically occurs at a strain level below the conventional forming limit curve (FLC). Therefore it is difficult to predict in computer simulations using the FLC as the failure criterion. A modified Mohr-Coulomb (M-C) fracture criterion has been developed to predict shear fracture. The model parameters for several AHSS have been calibrated using various tests including the butter-fly shaped shear test. In this paper, validation simulations are conducted using the modified (M-C) fracture criterion for a dual phase (DP) 780 steel to predict fracture in the stretch forming simulator (SFS) test and the bending under tension (BUT) test. Various deformation fracture modes are analyzed, and the range of usability of the criterion is identified.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Fuel injection during negative valve overlap offers a promising method of controlling HCCI combustion, but sorting out the thermal and chemical effects of NVO fueling requires knowledge of temperatures throughout the cycle. Computing bulk temperatures throughout closed portions of the cycle is relatively straightforward using an equation of state, once a temperature at one crank angle is established. Unfortunately, computing charge temperatures at intake valve closing for NVO operation is complicated by a large, unknown fraction of residual gases at unknown temperature. To address the problem, we model blowdown and recompression during exhaust valve opening and closing events, allowing us to estimate in-cylinder charge temperatures based on exhaust-port measurements. This algorithm permits subsequent calculation of crank-angle-resolved bulk temperatures and residual gas fraction over a wide range of NVO operation.

This paper examines the interaction of bulk flow and jet-induced fuel convection in an optically accessible hydrogen-fueled engine with direct injection. Planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel tracer was performed to obtain quantitative images of the hydrogen mole-fraction in the operating engine. With the engine motored, fuel was injected into inert bulk gas from a centrally located injector during the compression stroke. The injector had a single-hole nozzle with the jet angled at 50 degrees with respect to the vertical injector axis. Two parameters were varied in the experiments, injector orientation and tumble intensity, and for each of these, the injection timing was varied. Image series of the mean fuel mole-fraction between injection and near-TDC crank angles capture the mixture-formation process for each configuration and injection timing.

The rotary engine provides high power density compared to piston engine, but one of its downside is higher oil consumption. A model of the oil seals is developed to calculate internal oil consumption (oil leakage from the crankcase through the oil seals) as a function of engine geometry and operating conditions. The deformation of the oil seals trying to conform to housing distortion is calculated to balance spring force, O-ring and groove friction, and asperity contact and hydrodynamic pressure at the interface. A control volume approach is used to track the oil over a cycle on the seals, the rotor and the housing as the seals are moving following the eccentric rotation of the rotor. The dominant cause of internal oil consumption is the non-conformability of the oil seals to the housing distortion generating net outward scraping, particularly next to the intake and exhaust port where the housing distortion valleys are deep and narrow.

The rotary engine provides high power density compared to piston engine, but one of its downside is higher oil consumption. In order to better understand oil transport, a laser induced fluorescence technique is used to visualize oil motion on the side of the rotor during engine operation. Oil transport from both metered oil and internal oil is observed. Starting from inside, oil accumulates in the rotor land during inward motion of the rotor created by its eccentric motion. Oil seals are then scraping the oil outward due to seal-housing clearance asymmetry between inward and outward motion. Cut-off seal does not provide an additional barrier to internal oil consumption. Internal oil then mixes with metered oil brought to the side of the rotor by gas leakage. Oil is finally pushed outward by centrifugal force, passes the side seals, and is thrown off in the combustion chamber.

Piston rings are large contributors to friction losses in internal combustion engines. To achieve higher engine efficiency, low friction ring packs that can maintain good sealing performance must be designed. To support this effort, simulation tools have been developed to model the performance of piston rings during engine operation. However, the challenge of predicting oil consumption, blow by, and ring pack friction with sufficient accuracy remains. This is mostly due to the complexity of this system. Ring dynamics, deformation, interaction with liner and piston, gas and lubricant flow must all be studied together to make relevant predictions. In this paper, a new curved beam finite element model of piston rings is proposed. Ring structural deformation and contact with the liner are treated on two separate grids. A comparison with ring models in the literature and analytical solutions shows that it can provide accurate results efficiently.