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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

In the last couple of decades, countries have enacted new laws concerning environmental pollution caused by heavy-duty commercial and passenger vehicles. This is done mainly in an effort to reduce smog and health impacts caused by the different pollutions. One of the legislated pollutions, among a wide range of regulated pollutions, is nitrogen oxides (commonly abbreviated as NOx). The SCR (Selective Catalytic Reduction) was introduced in the automotive industry to reduce NOx emissions leaving the vehicle. The basic idea is to inject a urea solution (AdBlue™) in the exhaust gas before the gas enters the catalyst. The optimal working temperature for the catalyst is somewhere in the range of 300 to 400 °C. For the reactions to occur without a catalyst, the gas temperature has to be at least 800 °C. These temperatures only occur in the engine cylinder itself, during and after the combustion.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

The use of Selective Catalytic Reduction (SCR) is becoming increasingly more popular as a way of reducing NOx emissions from heavy duty vehicles while maintaining competitive operating costs. In order to make efficient use of these systems, it's important to have a complete system approach when it comes to calibration of the engine and aftertreatment system. This paper presents a simplified model of a heavy duty SCR catalyst, primarily intended for use in combination with an engine-out emissions model to perform model based offline optimization of the complete system. The traditional way of modelling catalysts using a dense discretization of the catalyst channels and non-linear differential equation solvers to solve the heat and mass balance equations, requires too much computational power in this application. The presented model is also useful in other applications such as model based control.

In order to make efficient use of a Diesel engine equipped with an SCR system, it's important to have a complete system approach when it comes to calibration of the engine and the aftertreatment system. This paper presents a complete model of a heavy duty diesel engine equipped with a vanadia based SCR system. The diesel engine uses common rail fuel injection, a variable geometry turbocharger (VGT) and cooled EGR. The engine model consists of a quasi steady gas exchange model combined with a two-zone zero dimensional combustion model. The combustion model is a predictive heat release model. Using the calculated zone temperatures, the corresponding NOx concentration is given by the original Zeldovich mechanism. The SCR catalyst model is of the state space type. The basic model structure is a series of continuously stirred tank reactors and the catalyst walls are discretized to describe mass transport inside the porous structure.

Achieving upcoming HD emissions legislation, Euro VI/EPA 10, is a challenge for all engine manufacturers. A likely solution to meet the NOx limit is to use a combination of EGR and SCR. Combining these two technologies poses new challenges and possibilities when it comes to optimization and calibration. Using a complete system approach, i.e., considering the engine and the aftertreatment system as a single unit, is important in order to achieve good performance. Optimizing the complete system is a tedious task; first there are a large number of variables which affect both emissions and fuel consumption (injection timing, EGR rate, urea dosing, injection pressure, pilot/post injections, for example). Secondly, the chemical reactions in the SCR catalyst are substantially slower than the dynamics of the diesel engine and the rest of the system, making the optimization problem time dependent.

The tightening legislation in the on-road heavy-duty diesel area means that pollution control systems will soon be widely introduced on such engines. A number of different aftertreatment systems are currently being considered to meet the incoming legislation, including Diesel Particulate Filters (DPF), Diesel Oxidation Catalysts (DOC) and Selective Catalytic Reduction (SCR) systems. Relatively little is known about the interactions between lubricant-derived species and such aftertreatment systems. This paper describes the results of an experimental program carried out to investigate these interactions within DPF, DOC and SCR systems on a state-of-the-art 9 litre engine. The influence of lubricant composition and lube oil ash level was investigated on the different catalyst systems. In order to reduce costs and to speed up testing, test oil was dosed into the fuel. Tests without dosing lubricant into the fuel were also run.

Diesel exhaust fluid, DEF, (32.5 wt.% urea aqueous solution) is widely used as the NH3 source for selective catalytic reduction (SCR) of NOx in diesel aftertreatment systems. The transformation of sprayed liquid phase DEF droplets to gas phase NH3 is a complex physical and chemical process. Briefly, it experiences water vaporization, urea thermolysis/decomposition and hydrolysis. Depending on the DEF doser, decomposition reaction tube (DRT) design and operating conditions, incomplete decomposition of injected urea could lead to solid urea deposit formation in the diesel aftertreatment system. The formed deposits could lead to engine back pressure increase and DeNOx performance deterioration etc. The formed urea deposits could be further transformed to chemically more stable substances upon exposure to hot exhaust gas, therefore it is critical to understand this transformation process.

The emission control in heavy-duty vehicles today is based on predefined injection strategies and after-treatment systems such as SCR (selective catalytic reduction) and DPF (diesel particulate filter). State-of-the-art engine control is presently based on cycle-to-cycle resolution. The introduction of the crank angle resolved pressure measurement, from a piezo-based pressure sensor, enables the possibility to control the fuel injection based on combustion feedback while the combustion is occurring. In this paper a study is presented on the possibility to control NOx (nitrogen oxides) formation with a crank angle resolved NOx estimator as feedback. The estimator and the injection control are implemented on an FPGA (Field-Programmable Gate Array) to manage the inherent time constraints. The FPGA is integrated with the rest of the engine control system for injection control and measurement.

Emissions standards are becoming increasingly harder to reach without the use of exhaust aftertreatment systems such as Selective Catalytic Reduction and particulate filters. In order to make efficient use of these systems it is important to have accurate models of engine-out emissions. Such models are also useful for optimizing and controlling next-generation engines without aftertreatment using for example exhaust gas recirculation (EGR). Engines are getting more advanced using systems such as common rail fuel injection, variable geometry turbochargers (VGT) and EGR. With these new technologies and active control of the injection timing, more sophisticated models than simple stationary emission maps must be used to get adequate results. This paper is focused on the calculation of engine-out NOx and engine parameters such as cylinder pressure, temperature and gas flows.

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

Troubleshooting trees are traditionally used to guide technicians through the process of identifying the cause of vehicle problems and solving them. These static trees can successfully visualize complex information. However, for modular vehicles, the trees become difficult to create and maintain due to the numerous different configurations of vehicles that can be constructed. These issues can be overcome by using a model-based approach. This paper describes a prototype tool for guided troubleshooting and shows its application to a selective catalytic reduction system used in many heavy vehicles. The troubleshooting tool guides the technician through the troubleshooting process by presenting the most likely fault candidates and recommending the most useful actions to perform. The list of candidates and recommendations are updated continuously to reflect the outcomes of past actions.

The after treatment devices (ATD) used in internal combustion engine (IC-engine) exhaust systems are mainly designed with emphasis on emission control, i.e. chemical efficiency, while paying less attention to the acoustic performance. In automotive applications, the duct diameters are so small that studying the acoustic wave propagation only in the plane wave frequency range is usually sufficient. In the case of medium speed IC-engines, used for example in power plants and ships, the three dimensional acoustic phenomena must also be taken into account. The main elements of the medium speed IC-engine ATD are the selective catalytic reducer (SCR) and oxidation catalyst (OC), which are based on a large amount of coated channels, i.e. the substrates. The number and type of the substrates depends not only on the regional environment legislations but also on the engine type.

Catalytic and non-catalytic engine aftertreatment components, such as the diesel oxidation catalyst (DOC), selective catalytic reduction on filter (SCRF), the gasoline particulate filter (GPF) and the diesel particulate filter (DPF) are complex, multifunctional emissions control technologies that are robustly designed for extended use in harsh automotive exhaust environments. Over the useful component lifetime, lubricant-derived inorganic and incombustible ash accumulates in and/or on the surface of the aforementioned aftertreatment components, resulting in degraded performance and other potential problems. In order to better understand effects of ash in such components, a multiscale analytical approach is necessary, requiring a variety of experimental tools.

In heavy-duty engines, Euro VI legislation regulates the total particle number (PN) in the exhaust based on the particle measurement program (PMP) guidelines. By PMP directives, the exhaust sample is diluted and conditioned to contain non-volatile particles before measuring the PN. The fraction of non-volatile and volatile particles changes along the exhaust after-treatment system and could affect the total PN measured. Therefore, it is of interest to compare the performance of the dilution systems at different positions along the after-treatment system. For this purpose, a standard PMP compliant two-stage dilution system (DS1) with evaporation tube (ET) was compared with a close coupled two-stage ejector dilution system (DS2). In DS2, the non-volatile PN was measured with a dilution temperature of 350°C (same as the DS1 ET temperature) while the volatile PN was measured with a dilution temperature of 150°C.

Particle emissions from heavy-duty engines are regulated both by mass and number by Euro VI regulation. Understanding the evolution of particle size and number from the exhaust valve to the tail pipe is of vital importance to expand the possibilities of particle reduction. In this study, experiments were carried out on a heavy-duty Euro VI engine after-treatment system consisting of diesel oxidation catalyst, diesel particulate filter and selective catalytic reduction (SCR) unit with AdBlue injection followed by ammonia slip catalyst. The present work focusses on the SCR unit with regard to total particle number with and without nucleation particles both. Experiments were conducted by varying the AdBlue injection quantity, SCR inlet temperature [to vary the reaction temperature], exhaust mass flow rate [to vary the residence time in SCR], and fuel injection pressures [to vary inlet particle number and inlet NOx].