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Journal Article

Laboratory Study of Soot, Propylene, and Diesel Fuel Impact on Zeolite-Based SCR Filter Catalysts

2009-04-20
2009-01-0903
Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.
Journal Article

Ash Effects on Diesel Particulate Filter Pressure Drop Sensitivity to Soot and Implications for Regeneration Frequency and DPF Control

2010-04-12
2010-01-0811
Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.
Journal Article

Characteristics and Effects of Lubricant Additive Chemistry on Ash Properties Impacting Diesel Particulate Filter Service Life

2010-04-12
2010-01-1213
Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.
Journal Article

High Strain Rate Mechanical Characterization of Carbon Fiber Reinforced Polymer Composites Using Digital Image Correlations

2017-03-28
2017-01-0230
The introduction of carbon fiber reinforced polymer (CFRP) composites to structural components in lightweight automotive structures necessitates an assessment to evaluate that their crashworthiness dynamic response provides similar or higher levels of safety compared to conventional metallic structures. In order to develop, integrate and implement predictive computational models for CFRP composites that link the materials design, molding process and final performance requirements to enable optimal design and manufacturing vehicle systems for this study, the dynamic mechanical response of unidirectional (UD) and 2x2 twill weave CRFP composites was characterized at deformation rates applicable to crashworthiness performance. Non-standardized specimen geometries were tested on a standard uniaxial frame and an intermediate-to-high speed dynamic testing frame, equipped with high speed cameras for 3D digital image correlation (DIC).
Journal Article

Impact of Rivet Head Height on the Tensile and Fatigue Properties of Lap Shear Self-Pierced Riveted CFRP to Aluminum

2017-03-28
2017-01-0477
Tensile and fatigue properties of continuous braided carbon fiber reinforced polymer (CFRP) composite to AA6111 self-piercing riveted (SPR) lap shear joints are presented. Rivets were inserted at two target head heights separated by 0.3 mm. Even within the narrow range of head heights considered, the flushness of the rivet head was found to have a dominant effect on both the monotonic and fatigue properties of the lap shear SPR joints. Joints created with a flush head resulted in a greater degree of fiber breakage in the top ply of the CFRP laminate, which resulted in lower lap shear failure load as compared to SPR joints produced with a proud rivet head. Irrespective of the lap shear failure load, rivet pullout was the most common failure mode observed for both rivet head heights. In fatigue tests, the SPR joints produced with a proud head exhibited higher fatigue life compared to SPR joints produced with a flush head.
Journal Article

Failure Mode and Fatigue Behavior of Flow Drill Screw Joints in Lap-Shear Specimens of Aluminum 6082-T6 Sheets of Different Thicknesses

2018-04-03
2018-01-1239
Failure mode and fatigue behavior of flow drill screw (FDS) joints in lap-shear specimens of aluminum 6082-T6 sheets of different thicknesses are investigated based on the experimental results and a structural stress fatigue life estimation model. Lap-shear specimens of different thicknesses with FDS joints with clearance hole were made and tested under quasi-static and cyclic loading conditions. Optical micrographs show the failure modes of the FDS joints with clearance hole in lap-shear specimens of different thicknesses under quasi-static loading conditions. Under quasi-static loading conditions, as the thickness increases, the FDS joint failed from the penetration of the screw head into the upper sheet to the failure of the screw between the two sheets. Optical micrographs also show the failure modes of the FDS joints with clearance hole in lap-shear specimens of different thicknesses under cyclic loading conditions.
Journal Article

Failure Mode and Fatigue Behavior of Flow Drill Screw Joints in Lap-Shear Specimens of Aluminum 6082-T6 Sheets Made with Different Processing Conditions

2018-04-03
2018-01-1237
Failure mode and fatigue behavior of flow drill screw (FDS) joints in lap-shear specimens of aluminum 6082-T6 sheets made with different processing conditions are investigated based on the experimental results and a structural stress fatigue life estimation model. Lap-shear specimens with FDS joints without clearance hole and lap-shear specimens with stripped FDS joints with clearance hole were made and then tested under quasi-static and cyclic loading conditions. Optical micrographs show the failure modes of the FDS joints without clearance hole (with gap) and the stripped FDS joints with clearance hole under quasi-static and cyclic loading conditions. The fatigue failure mode of the FDS joints without clearance hole (with gap) in lap-shear specimens is similar to those with clearance hole. The fatigue lives of lap-shear specimens with FDS joints without clearance hole are lower than those with clearance hole for given load ranges under cyclic loading conditions.
Journal Article

Investigation of Failure Mode and Fatigue Behavior of Flow Drill Screw Joints in Lap-Shear Specimens of Aluminum 6082-T6 Sheets

2016-04-05
2016-01-0501
Failure mode and fatigue behavior of flow drill screw (FDS) joints in lap-shear specimens of aluminum 6082-T6 sheets with and without clearance hole are investigated based on experiments and a structural stress fatigue life estimation model. Lap-shear specimens with FDS joints were tested under cyclic loading conditions. Optical micrographs show that the failure modes of the FDS joints in specimens with and without clearance hole are quite similar under cyclic loading conditions. The fatigue lives of the FDS joints in specimens with clearance hole are longer than those of the FDS joints in specimens without clearance hole for the given load ranges under cyclic loading conditions. A structural stress fatigue life estimation model is adopted to estimate the fatigue lives of the FDS joints in lap-shear specimens under high-cycle loading conditions.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

A Comparative Study of Two ASTM Shear Test Standards for Chopped Carbon Fiber SMC

2018-04-03
2018-01-0098
Chopped carbon fiber sheet molding compound (SMC) material is a promising material for mass-production lightweight vehicle components. However, the experimental characterization of SMC material property is a challenging task and needs to be further investigated. There now exist two ASTM standards (ASTM D7078/D7078M and ASTM D5379/D5379M) for characterizing the shear properties of composite materials. However, it is still not clear which standard is more suitable for SMC material characterization. In this work, a comparative study is conducted by performing two independent Digital Image Correlation (DIC) shear tests following the two standards, respectively. The results show that ASTM D5379/D5379M is not appropriate for testing SMC materials. Moreover, the failure mode of these samples indicates that the failure is caused by the additional moment raised by the improper design of the fixture.
Journal Article

On-Board Particulate Filter Failure Prevention and Failure Diagnostics Using Radio Frequency Sensing

2017-03-28
2017-01-0950
The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this study, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications.
Journal Article

Evaluation of Non-Contiguous PM Measurements with a Resistive Particulate Matter Sensor

2017-03-28
2017-01-0952
The resistive particulate matter sensor (PMS) is rapidly becoming ubiquitous on diesel vehicles as a means to diagnose particulate filter (DPF) leaks. By design the device provides an integrated measure of the amount of PM to which it has been exposed during a defined measurement period within a drive cycle. The state of the art resistive PMS has a large deadband before any valid output related to the accumulated PM is realized. As a result, most DPF monitors that use the PMS consider its output only as an indicator that a threshold quantity of PM has amassed rather than a real-time measure of concentration. This measurement paradigm has the unfortunate side effect that as the PM OBD threshold decreases, or the PMS is used on a vehicle with a larger exhaust volume flow, a longer measurement is required to reach the same PM sensor output. Longer PMS measurement times lead to long particulate filter monitoring durations that may reduce filter monitor completion frequency.
Journal Article

Enhanced Durability of a Cu/Zeolite Based SCR Catalyst

2008-04-14
2008-01-1025
Passenger and light duty diesel vehicles will require up to 90% NOx conversion over the Federal Test Procedure (FTP) to meet future Tier 2 Bin 5 standards. This accomplishment is especially challenging for low exhaust temperature applications that mostly operate in the 200 - 350°C temperature regime. Selective catalytic reduction (SCR) catalysts formulated with Cu/zeolites have shown the potential to deliver this level of performance fresh, but their performance can easily deteriorate over time as a result of high temperature thermal deactivation. These high temperature SCR deactivation modes are unavoidable due to the requirements necessary to actively regenerate diesel particulate filters and purge SCRs from sulfur and hydrocarbon contamination. Careful vehicle temperature control of these events is necessary to prevent unintentional thermal damage but not always possible. As a result, there is a need to develop thermally robust SCR catalysts.
Journal Article

Technical Advantages of Vanadium SCR Systems for Diesel NOx Control in Emerging Markets

2008-04-14
2008-01-1029
Selective catalytic reduction (SCR) is a promising technology for diesel aftertreatment to meet NOx emissions targets in several countries. In established markets such as the US and Europe, zeolite SCR systems are expected to be used due to their ability to survive the exhaust gas temperatures seen in an active diesel particulate filter regeneration. In emerging markets where the fuel sulfur level may be as high as 2000 parts per million, zeolite SCR catalysts may have durability issues. In these markets, low sulfur fuel is needed overall to meet emissions standards and to avoid high sulfate emissions, but the aftertreatment system must be durable to high sulfur levels because there is a risk of exposure to high sulfur fuel. Also, emissions standards may be met without a DPF in some applications, so that the exhaust system would not see temperatures of 600°C or higher.
Journal Article

An Advanced and Comprehensive CAE Approach of Piston Dynamics Studies for Piston Optimal and Robust Design

2011-04-12
2011-01-1404
A successful piston design requires eliminate the following failure modes: structure failure, skirt scuffing and piston unusual noise. It also needs to deliver least friction to improve engine fuel economy and performance. Traditional approach of using hardware tests to validate piston design is technically difficult, costly and time consuming. This paper presents an up-front CAE tool and an analytical process that can systematically address these issues in a timely and cost-effectively way. This paper first describes this newly developed CAE process, the 3D virtual modeling and simulation tools used in Ford Motor Company, as well as the piston design factors and boundary conditions. Furthermore, following the definition of the piston design assessment criteria, several piston design studies and applications are discussed, which were used to eliminate skirt scuffing, reduce piston structure dynamic stresses, minimize skirt friction and piston slapping noise.
Journal Article

Soot and Ash Deposition Characteristics at the Catalyst-Substrate Interface and Intra-Layer Interactions in Aged Diesel Particulate Filters Illustrated using Focused Ion Beam (FIB) Milling

2012-04-16
2012-01-0836
The accumulation of soot and lubrication-derived ash particles in a diesel particulate filter (DPF) increases exhaust flow restriction and negatively impacts engine efficiency. Previous studies have described the macroscopic phenomenon and general effects of soot and ash accumulation on filter pressure drop. In order to enhance the fundamental understanding, this study utilized a novel apparatus that of a dual beam scanning electron microscope (SEM) and focused ion beam (FIB), to investigate microscopic details of soot and ash accumulation in the DPF. Specifically, FIB provides a minimally invasive technique to analyze the interactions between the soot, ash, catalyst/washcoat, and DPF substrate with a high degree of measurement resolution. The FIB utilizes a gallium liquid metal ion source which produces Ga+ ions of sufficient momentum to directionally mill away material from the soot, ash, and substrate layers on a nm-μm scale.
Journal Article

Sensitivity Analysis of Ash Packing and Distribution in Diesel Particulate Filters to Transient Changes in Exhaust Conditions

2012-04-16
2012-01-1093
Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.
Journal Article

Ash Permeability Determination in the Diesel Particulate Filter from Ultra-High Resolution 3D X-Ray Imaging and Image-Based Direct Numerical Simulations

2017-03-28
2017-01-0927
Diesel engine exhaust aftertreatment components, especially the diesel particulate filter (DPF), are subject to various modes of degradation over their lifetimes. One particular adverse effect on the DPF is the significant rise in pressure drop due to the accumulation of engine lubricant-derived ash which coats the inlet channel walls effectively decreasing the permeability of the filter. The decreased permeability due to ash in the DPF can result in increased filter pressure drop and decreased fuel economy. A unique two-step approach, consisting of experimental measurements and direct numerical simulations using ultra-high resolution 3D imaging data, has been utilized in this study to better understand the effects of ash accumulation on engine aftertreatment component functionality.
Journal Article

In-Situ Optical Analysis of Ash Formation and Transport in Diesel Particulate Filters During Active and Passive DPF Regeneration Processes

2013-04-08
2013-01-0519
The formation and transport processes governing the build-up of incombustible ash deposits in diesel particulate filters (DPF) are influenced to a large extent by the filter's operating history. More specifically, the regeneration process, whether active, passive, or some variation of the two, has long been assumed to exert significant influence on the resulting ash characteristics. Until recently, only limited circumstantial evidence was available to describe differences in ash properties and distribution impacting DPF performance for filters subjected to different regeneration strategies. This work presents, for the first time, results from a comprehensive series of evaluations with optically-accessible DPF core samples showing the processes controlling the formation, transport, and interaction of the soot and ash deposits over a range of DPF regeneration conditions.
Journal Article

Ash Accumulation and Impact on Sintered Metal Fiber Diesel Particulate Filters

2015-04-14
2015-01-1012
While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.
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