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In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

With the aim of improving the air quality in large cities, the California Air Resources Board (CARB) has stipulated that non-methane organic gas (NMOG) composed of carbon numbers from C1 to C12 must be reduced for vehicle categories designated as Transitional Low Emission Vehicles (TLEVs), Low Emission Vehicles (LEVs), Ultra low Emission Vehicles (ULEVs), and Zero Emission Vehicles (ZEVs). Although considerable research work has been done on this issue to date, the entire picture is still not clear. Studies done by the authors have been aimed at providing a better understanding of the potential for reducing automotive tailpipe emissions by using several clean fuel candidates. The major questions of concern are the extent to which emissions of certain species can actually be reduced and what fuel can provide the best performance under a reduced NMOG condition.

The California Low-Emission Vehicle (LEV) standards mandate a reduction in non-methane organic gases (NMOG). With the aim of analyzing NMOG emissions, a comparison was made of the hydrocarbon species found in the exhaust gas when different types of catalyst systems and fuel specifications were used. NMOG emissions are usually measured by removing methane from the total hydrocarbon (THC) emissions and adding aldehyde and ketone emissions. The NMOG level found in this way is thus influenced by the rate of methane in THC emissions. Another important factor in the LEV standards is specific reactivity (SR), indicating the formation potential of ozone, which is one cause of photochemical smog. Specific reactivity is expressed by the amount of ozone generated per unit weight of NMOG emissions, and is affected by the respective proportion of hydrocarbon species in the total NMOG emissions.