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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

Using small thin-film pressure sensors deposited onto a piston skirt surface, oil-film pressure on the piston skirt surface is measured when piston slap noise is generated without affecting the surface geometry, stiffness and mass of the piston. Under a no-load firing engine condition and at low temperature, the measured oil-film pressure corresponded well to the measured acceleration of the cylinder liner, which is indicative of piston slap noise, confirming the validity of the present method. Moreover, the oil-film pressure distribution on the skirt surface was measured for different engine speeds and piston pin offsets, which enabled more insight to be provided into piston secondary motion than that by considering the effects of cylinder liner acceleration.

The primary objective in design is to achieve the target value of the design's response function. If a design fails to achieve the target value, it most likely fails in two ways: inconsistent functional output and in design involving multiple response functions, unable to converge to the multiple target values in spite of iterative adjustment of the design parameters. The former is symptom of a design not able to perform in the presence of variability, i.e., noise. The latter is symptom of a design that fails to perform in the presence of functional coupling. Both problems are best addressed at the conceptual stage of the design at which only design solution that is inherently robust to noise and functionally uncoupled is entertained. If this is not possible, the alternative is to exploit the interaction between control variables and variables that are sources of noise and functional coupling to render the design insensitive to them.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

The results of this study make clear the characteristics of electrode performance deterioration in terms of cell voltage reduction in polymer electrolyte fuel cells (PEFCs) caused by the presence of certain quantities of carbon monoxide and/or hydrogen sulfide in the anode feed. AC impedance measurements of the anode and cathode potentials revealed that both electrode potentials showed deterioration in the presence of each type of poisoning gas. This suggests that the poisoning gases permeated the electrolyte membrane and transferred to the cathode, causing performance deterioration by poisoning the catalyst. In addition, AC impedance measurements indicated that the presence of hydrogen sulfide in the anode feed increased the membrane impedance, thus implying some poisoning effect even on the electrolyte membrane.

Reformed fuel from hydrocarbons or alcohol mainly consists of hydrogen, carbon monoxide and carbon dioxide. The composition of the reformed fuel can be varied to some extent with a combination of a thermal decomposition reaction and a water gas shift reaction. Methanol is known to decompose at a relatively low temperature. An application of the methanol reforming system to an internal combustion engine enables an exhaust heat recovery to increase the heating value of the reformed fuel. This research analyzed characteristics of combustion, exhaust emissions and cooling loss in an internal combustion engine fueled with several composition of model gases for methanol reformed fuels which consist of hydrogen, carbon monoxide and carbon dioxide. Experiments were made with both a bottom view type optical access single cylinder research engine and a constant volume combustion chamber.

This study analyzes the factors influencing the thermal efficiency of a homogeneous charge spark-injection (SI) engine fuelled with hydrogen, focusing on the degree of constant volume and cooling loss. The cooling loss from the burning gas to the cylinder walls is quantitatively evaluated by analyzing the cylinder pressure diagram and exhaust gas composition. The degree of constant volume burning and constant volume cooling are also obtained by fitting the Wiebe function to the rate of heat release calculated using the cylinder pressure diagram. A comparison of combustion and cooling characteristics of hydrogen and methane combustion reveals that cooling loss in hydrogen combustion is higher than that of methane combustion due to the short quenching distance and rapid burning velocity during hydrogen combustion. It is also suggested that the high cooling loss observed during hydrogen combustion reduces thermal efficiency.

The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties

Hydrogen is expected to be a clean and energy-efficient fuel for the next generation of power sources because it is CO2-free and has excellent combustion characteristics. In this study, an attempt was made to apply Homogeneous Charge Compression Ignition (HCCI) combustion to hydrogen with the aim of achieving low oxides of nitrogen (NOx) emissions and high fuel economy with the assistance of the di-methyl-ether (DME) fuel supplement. As a result, HCCI combustion of hydrogen mixed with 25 vol% DME achieved approximately a 30% improvement in fuel economy compared with HCCI of pure DME and spark-ignited lean-burn combustion of pure hydrogen under almost zero NOx emissions and low hydrocarbon (HC) emissions. This is attributed to control of the combustion process to attain the optimum onset of combustion and to a reduction of cooling losses.

According to authors' previous research, high pressure hydrogen engines with direct injection right before TDC and spark ignition obtain high performance and eliminate almost. abnormal combustion. This study has clarified the mooted points in the flame propagation to adjacent jets and the control of the optimum spark timing and large NOx emissions even in leaner than excess air ratio of λ=2. Nitric oxides (NOx) is the only the pollutant in the exhaust gases emitted by hydrogen engines. It has been found that the NOx formation largely depends on the mixture formation method. In order to operate the engine in a small amount of NOx, an experimental study was carried out to investigate the reduction of NOx and the output power by using dual mixture formation method, external mixture formation and direct injection.

In order to establish hydrogen engines for practical use, it is important to overcome difficulties caused by unique characteristics of hydrogen fuel. A hydrogen engine with direct injection right before top dead center(TDC) and spark ignition has advantages such as prevention of abnormal combustion and realization of high power output near the stoichiometric air-fuel ratio, in comparison with an engine with external mixture. On the other hand, it has been pointed out that ignition and combustion for this type of hydrogen engines should be improved and that further studies on mixture formation of air and injected hydrogen are necessary for the improvement. For the direct injection hydrogen engine, mixture is formed both by air flow inside the combustion chamber and by injected hydrogen jet.

The extent of oxidation of hydrocarbons desorbing from the oil layer has been measured directly in a hydrogen-fueled, spark-ignited engine in which the lubricant oil was doped with a single component hydrocarbon. The amount of hydrocarbon desorbed and oxidized could be measured simultaneously as the dopant was only source of carbon-containing species. The fraction oxidized was strongly dependent on engine load, hydrogen fuel-air ratio and dopant chemical reactivity, but only modestly dependent on spark timing and nitrogen dilution levels below 20 percent. Fast FID measurements at the cylinder exit showed that the surviving hydrocarbons emerge late in the exhaust stroke.

The aim of this research was to analyze the lubrication conditions of piston pin boss bearings used in the press-fit piston pins of automobile gasoline engines. An original pin boss friction measuring device was developed and used to successfully obtain measurements. It was revealed that the friction force peaks twice every cycle at high engine loads, and non-fluid lubrication characteristics are displayed. The friction forces for various differing piston pins and pin boss bearings were analyzed, and it was shown that reducing piston pin length or thickness to reduce piston weight, or reducing the pin boss bearing clearance to reduce noise worsen the friction characteristics and increase the possibility of abnormal bearing friction as well as seizure.

It is a well-known fact that the exhaust emission characteristics of hydrogen fueled engines are extremely good. The external mixture formation - a hydrogen fuel supply method - has the merit of practically zero NOx emission level in the lean mixture range with the excess air ratio λ set at 2.0 or greater as well as the merits of simple mechanism and easy operation. However, the practical use of such engines has been impeded partly due to the occurrence of backfire where the excess air ratio λ is 2 to 3. In order to allow the practical use of the hydrogen fueled engines with external mixture formation, it is vital to determine the causes of backfire and to establish proper countermeasures. It is found through a recent study conducted on the mechanism of backfire that the abnormal electric discharge in the intake stroke is one of the causes of backfire.

The objective was to rank piston friction and noise for three piston architectures at three cold clearance conditions. Piston secondary motion was measured using four gap sensors mounted on each piston skirt to better understand the friction and noise results. One noticeable difference in friction performance from conventional designs was as engine speed increased the friction force during the expansion stroke decreased. This was accompanied by relatively small increases in friction force during the other strokes so Friction Mean Effective Pressure (FMEP) for the whole cycle was reduced. Taguchi's Design of Experiment method was used to analyze the variances in friction and noise.

EQUIPMENT for measuring vibration in airplane structures and powerplants during actual flight is described in this paper. This development is the result of a cooperative research program carried out by the Bureau of Aeronautics of the U. S. Navy and the Massachusetts Institute of Technology with contributions of improvements in design and new features by the Sperry Gyroscope Co., Inc. In its essentials, the M.I.T.-Sperry Apparatus consists of a number of electrical pickup units which operate a central amplifying and recording unit. The recorder is a double-element photographic oscillograph. Each pickup is adapted especially to the type of vibration that it is intended to measure and is made so small that it does not appreciably affect the vibration characteristics of the member to which it is attached rigidly. By using a number of systematically placed pickups, all the necessary vibration information on an airplane can be recorded during a few short flights.

It is desired to minimize clearance between the piston and the cylinder to reduce noise and suppress vibration. Although significant effort has been made for this purpose, increased piston friction force and the occurrence of seizure still prevent the ideal clearance from being realized. In order to determine the lower limit of the piston clearance, it is crucial to clarify the following unknowns; which part of piston contributes to friction increase as the piston clearance is decreased, during which phase of the piston motion the friction increase occurs, and how the piston clearance affects lubrication phenomena. Measurements of piston friction force under operating conditions were made by applying the Floating Liner Method(1),(2)* to a single-cylinder test gasoline engine. The measurement revealed how the piston friction varied as the piston clearance decreased. Lateral motion of the piston was also measured.

The hydrogen combustion characteristics have been studied in a late-injection (near TDC) hot surface ignition engine. As a supplemental experiment, the mode of combustion was observed in a constant volume combustion chamber by the schlieren method. Consequently the combustion process, that was the flame propagation initiated by a hot surface through heterogeneous hydrogen jets, was not the same as that of a diesel engine. The experimental results in test engine showed the optimum number of injection holes and the effect of intake air swirl for better mixture formation. It was observed that the combustion was frequently accompanied by non-negligible combustion pressure vibrations at all engine operating conditions.