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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

The operation of a crop growth system in micro-gravity is an important part of the National Aeronautics and Space Administration's Closed Ecological Life Support System development program. Maintaining densely arrayed plants in a closed environment imposed to induce high growth rates must be expected to result in substantial levels of water transpiration rate. Since the environmental air is recirculated, the transpiration water must be removed. In an operating CELSS, it is expected that this water will provide potable water for use of the crew. There is already considerable knowledge about water removal from crew environmental air during orbital and transfer activities, and the difference between the conditions of the described requirement and the conditions for which experience has been gained is the quantities involved and the reliability implications due to the required periods of operation.

The least expensive life support for brief human missions is direct supply of all water and oxygen from Earth without any recycling. The currently most advanced human life support system was designed for the International Space Station (ISS) and will use physicochemical systems to recycle water and oxygen. This paper compares physicochemical to direct supply air and water life support systems using Equivalent Mass (EM). EM breakeven dates and EM ratios show that physicochemical systems are more cost effective for longer mission durations.

Waste management is a vital function of spacecraft life support systems as it is necessary to meet crew health and safety and quality of life requirements. Depending on the specific mission requirements, waste management operations can include waste collection, segregation, containment, processing, storage and disposal. For the Crew Exploration Vehicle (CEV), addressing volume and mass constraints is paramount. Reducing the volume of trash prior to storage is a viable means to recover habitable volume, and is therefore a particularly desirable waste management function to implement in the CEV, and potentially in other spacecraft as well. Research is currently being performed at NASA Ames Research Center to develop waste compaction systems that can provide both volume and mass savings for the CEV and other missions.

Waste management is a critical component of life support systems for manned space exploration. Human occupied spacecraft and extraterrestrial habitats must be able to effectively manage the waste generated throughout the entire mission duration. The requirements for waste systems may vary according to specific mission scenarios but all waste management operations must allow for the effective collection, containment, processing, and storage of unwanted materials. NASA's Crew Exploration Vehicle usually referred to as the CEV, will have limited volume for equipment and crew. Technologies that reduce waste storage volume free up valuable space for other equipment. Waste storage volume is a major driver for the Orion waste compactor design. Current efforts at NASA Ames Research Center involve the development of two different prototype compactors designed to minimize trash storage space.

This paper considers the design of a life support system for transit to Mars and return to Earth. Because of the extremely high cost of launching mass to Mars, the Mars transit life support system must minimize the amount of oxygen, water, and food transported. The three basic ways to provide life support are to directly supply all oxygen and water, or to recycle them using physicochemical equipment, or to produce them incidentally while growing food using crop plants. Comparing the costs of these three approaches shows that physicochemical recycling of oxygen and water is least costly for a Mars transit mission. The long mission duration also requires that the Mars transit life support system have high reliability and maintainability. Mars transit life support cannot make use of planetary resources or gravity. It should be tested in space on the International Space Station (ISS).

Terraforming of Mars is the long-term goal of colonization of Mars. However, this process is likely to be a very slow process and conservative estimates involving a synergetic, technocentric approach suggest that it may take around 10,000 years before the planet can be parallel to that of Earth and where humans can live in open systems (Fogg, 1995). Hence, for the foreseeable future, any missions will require habitation within small confined habitats with high biomass to atmospheric mass ratios, thereby requiring that all wastes be recycled. Processing of the wastes will ensure predictability and reliability of the ecosystem and reduce resupply logistics. Solid wastes, though smaller in volume and mass than the liquid wastes, contain more than 90% of the essential elements required by humans and plants.

For the last two years, the University of Utah and Reaction Engineering International, in cooperation with NASA Ames Research Center (ARC), have been developing a waste incineration system for regenerative life support systems. The system is designed to burn inedible plant biomass and human waste. The goal is to obtain an exhaust gas clean enough to recycle to either the plant or human habitats. The incineration system, a fluidized bed reactor, has been designed for a 4-person mission. This paper will detail the design of the units. In addition, results will be presented from testing at the University of Utah. Presently, the unit has been shipped to Ames Research Center for more tests prior to delivery to Johnson Space Center for testing in a 90-day, 4-person test.

PGBA, a plant growth facility developed for commercial space biotechnology research, successfully grew a total of 50 plants (6 species) during 10 days aboard the Space Shuttle Endeavor (STS-77), and has reflown aboard the Space Shuttle Columbia (STS-83 for 4 days and STS-94 for 16 days) with 55 plants and 10 species. The PGBA life support system provides atmospheric, thermal, and humidity control as well as lighting and nutrient supply in a 33 liter microgravity plant growth chamber. The atmosphere treatment system removes ethylene and other hydrocarbons, actively controls CO2 replenishment, and provides passive O2 control. Temperature and humidity are actively controlled.

The space environment presents many challenges to the operation and functioning of life support systems. These challenges include reduced gravity, near vacuum ambient, extreme temperatures, and radiation. Proper testing and modeling of system components to account for these factors will be important for their verification. This paper describes the modeling and design of a reduced gravity test rig for waste management studies. The first investigation planned relate to the functioning of components of the Flexible Membrane Commode (FMC) currently under development at NASA Ames Research Center. The planned reduced gravity tests will be carried out in NASA's C'9 aircraft which provides approximately 25 seconds of reduced gravity per parabolic trajectory. The filling of the commode bag under the influence of a directed air flow will be studied. Simulated waste will be injected and cabin air will be used for directing the waste into the bag.

Dynamic simulation of the Lunar Outpost habitat life support was undertaken to investigate the impact of Extravehicular Activity (EVA). The preparatory static analysis and some supporting data are reported in another paper. (Jones, 2008-01-2184) Dynamic simulation is useful in understanding systems interactions, buffer needs, control approaches, and responses to failures and changes. A simulation of the Lunar outpost habitat life support was developed in MATLAB/Simulink™. The simulation is modular and reconfigurable, and the components are reusable to model other physicochemical (P/C) based recycling systems. EVA impacts the Lunar Outpost life support system design by requiring a significant increase in the direct supply mass of oxygen and water and by reducing the net mass savings of using dehydrated food. The mass cost of EVA depends on the amount and difficulty of the EVA scheduled.

NASA is planning to return to the moon and then explore Mars. A permanent base at the south pole of the moon will be the test bed for Mars. At the moon base, two crewmembers are expected to conduct Extravehicular Activity (EVA) six days every week. Current spacesuits are cooled by the sublimation of water ice into vacuum. A single 7 hour EVA near the lunar equator in daylight can expend up to 5 kilograms of water. Because of the high cost of transporting spacesuit cooling water to the moon, the water for one EVA could cost hundreds of thousands of dollars. The lunar south pole and Mars have low surface temperatures that make cooling much easier than at the lunar equator. Alternate cooling methods and staying in cool environments can reduce or eliminate the use of water for spacesuit cooling. If cooling water is not needed, a recycling life support system can provide all the required crew water and oxygen without transporting additional water from Earth.

The design and mass cost of a starship and its life support system are investigated. The mission plan for a multigenerationai interstellar voyage to colonize a new planet is used to describe the starship design, including the crew habitat, accommodations, and life support. Cost is reduced if a small crew travels slowly and lands with minimal equipment. The first human interstellar colonization voyage will probably travel about 10 light years and last hundreds of years. The required travel velocity is achievable by nuclear propulsion using near future technology. To minimize mission mass, the entire starship would not decelerate at the destination. Only small descent vehicles would land on the destination planet. The most mass efficient colonization program would use colonizing crews of only a few dozen. Highly reliable life support can be achieved by providing selected spares and full replacement systems.

Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

The transportation sector in the United States is a major contributor to global energy consumption and carbon dioxide emission. To assess the future potentials of different technologies in addressing these two issues, we used a family of simulation programs to predict fuel consumption for passenger cars in 2020. The selected technology combinations that have good market potential and could be in mass production include: advanced gasoline and diesel internal combustion engine vehicles with automatically-shifting clutched transmissions, gasoline, diesel, and compressed natural gas hybrid electric vehicles with continuously variable transmissions, direct hydrogen, gasoline and methanol reformer fuel cell hybrid electric vehicles with direct ratio drive, and battery electric vehicle with direct ratio drive.