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The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.

The oil distribution system of an automotive light duty engine typically has an oil pump mechanically driven through the front-endancillaries-drive or directly off the crankshaft. Delivery pressure is regulated by a relief valve to provide an oil gallery pressure of typically 3 to 4 bar absolute at fully-warm engine running conditions. Electrification of the oil pump drive is one way to decouple pump delivery from engine speed, but this does not alter the flow distribution between parts of the engine requiring lubrication. Here, the behaviour and benefits of a system with an electrically driven, fixed displacement pump and a distributor providing control over flow to crankshaft main bearings and big end bearings is examined. The aim has been to demonstrate that by controlling flow to these bearings, without changing flow to other parts of the engine, significant reductions in engine friction can be achieved.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

The extent of oxidation of hydrocarbons desorbing from the oil layer has been measured directly in a hydrogen-fueled, spark-ignited engine in which the lubricant oil was doped with a single component hydrocarbon. The amount of hydrocarbon desorbed and oxidized could be measured simultaneously as the dopant was only source of carbon-containing species. The fraction oxidized was strongly dependent on engine load, hydrogen fuel-air ratio and dopant chemical reactivity, but only modestly dependent on spark timing and nitrogen dilution levels below 20 percent. Fast FID measurements at the cylinder exit showed that the surviving hydrocarbons emerge late in the exhaust stroke.

A reciprocating test apparatus was constructed in which the friction of a single piston ring against a liner segment was measured. The lubrication oil film thickness was also measured simultaneously at the mid stroke of the ring travel using a laser fluorescence technique. The apparatus development and operation are described. Results are presented from a test matrix consisting of five different lubrication oils of viscosity (at 30°C) ranging from 49 to 357 cP; at three mean piston speeds of 0.45, 0.89 and 1.34 m/s; and at three ring normal loading of 1.4, 2.9 and 5.7 MPa. At mid stroke, the oil film thickness under the ring was ∼0.5 to 4 μm; the frictional coefficient was ∼0.02 to 0.1. The frictional coefficient for all the lubricants tested increased with normal load, and decreased with piston velocity. Both mixed and hydrodynamic lubrication regimes were observed. The friction behaviors were consistent with the Stribeck diagram.

A method to collect and speciate the components of gasoline absorbed in the lubricant oil using gas chromatography has been developed. Samples were collected continuously from the piston skirt, baffle and sump in a Saturn engine. A long (18 hours) test was performed to determine the build up of hydrocarbons in the sump, and a shorter (25 min) test was performed to determine the build up of hydrocarbons in the piston skirt and baffle during engine warm-up. The first experiment showed that the total hydrocarbon concentration in the sump oil reached a steady state of about 1.35% mass fraction after 11 hours of engine operation. The relative concentration of individual fuel hydrocarbon species absorbed in the oil increases exponentially with boiling point. Most of the identified species in the oil consist of the heavy end aromatics. Similar compositions but lower concentrations were found for samples collected from the piston skirt during engine warm-up.

The Wankel rotary engine is more compact than conventional piston engines, but its oil and fuel consumption must be reduced to satisfy emission standards and customer expectations. A key step toward this goal is to develop a better understanding of the apex seal lubrication to reduce oil injection while reducing friction and maintaining adequate wear. This paper presents an apex seal dynamics model capable of estimating relative wear and predicting friction, by modeling the gas and oil flows at the seal interfaces with the rotor housing and groove flanks. Model predictions show that a thin oil film can reduce wear and friction, but to a limited extent as the apex seal running face profile is sharp due to the engine kinematics.

In internal combustion engines, the majority of the friction loss associated with the piston takes place on the thrust side in early expansion stroke. Research has shown that the Friction Mean Effective Pressure (FMEP) of the engine can be reduced if proper modifications to the piston skirt, which is traditionally barrel-shaped, are made. In this research, an existing model was applied for the first time to study the effects of different oil supply strategies for the piston assembly. The model is capable of tracking lubricating oil with the consideration of oil film separation from full film to partial film. It is then used to analyze how the optimized piston skirt profile investigated in a previous study reduces friction.

The influence of size and concentration of carbon nanoparticle on the viscosity of an SAE 5W-30 lubricant oil has been investigated experimentally. Data were collected for oil samples drawn from sump of light duty automotive diesel engines. The average size of soot particles in the used oil samples was in the range of 180-320nm with concentrations ranging from 0 to 2 percentage by weight (wt. %.). A Brookfield DV-II Pro rotary viscometer was used to measure dynamic viscosity at low shear rates and temperatures of 40°C and 90°C. Nanoparticle concentration and particle size distribution were evaluated using Thermo-Gravimetric Analysis (TGA) and Dynamic Light Scattering (DLS) respectively. The viscosity of suspensions of graphite powder in lubricant oil was also investigated for concentrations ranging from 0 to 2 wt. %. The results show that dynamic viscosity increases with increasing soot content and decreasing temperature.

Three-piece oil control rings (TPOCR) are widely used in the majority of modern gasoline engines and they are critical for lubricant regulation and friction reduction. Despite their omnipresence, the TPOCRs’ motion and sealing mechanisms are not well studied. With stricter emission standards, gasoline engines are required to maintain lower oil consumption limits, since particulate emissions are strongly correlated with lubricant oil emissions. This piqued our interest in building a numerical model coupling TPOCR dynamics and oil transport to explain the physical mechanisms. In this work, a 2D dynamics model of all three pieces of the ring is built as the main frame. Oil transport in different zones are coupled into the dynamics model. Specifically, two mass-conserved fluid sub-models predict the oil movement between rail liner interface and rail groove clearance to capture the potential oil leakage through TPOCR. The model is applied on a 2D laser induced fluorescence (2D-LIF) engine.

The dilution of lubricating oil by fuel has adverse effects on engine wear, oil lubricity, air/fuel ratio control and feedgas emissions. Dilution is one of the factors limiting oil change intervals. The level and rate of accumulation depend on engine operating conditions and patterns of vehicle use. The work reported here develops and evaluates an empirical model to predict accumulation characteristics. This is aligned to requirements for predictions of dilution build-up in service. Predictions are shown to be in good agreement with data given in the literature. The model is used to investigate the influence of patterns of vehicle use on dilution.

The oil control ring (OCR) controls the supply of lubricating oil to the top two rings of the piston ring pack and has a significant contribution to friction of the system. This study investigates the two most prevalent types of OCR in the automotive market: the twin land oil control ring (TLOCR) and three piece oil control ring (TPOCR). First, the basis for TLOCR friction on varying liner roughness is established. Then the effect of changing the land width and spring tension on different liner surfaces for the TLOCR is investigated, and distinct trends are identified. A comparison is then done between the TLOCR and TPOCR on different liner surfaces. Results showed the TPOCR displayed different patterns of friction compared the TLOCR in certain cases.

The distribution of lubricating oil plays a critical role in determining the friction between piston skirt and cylinder liner, which is one of the major contributors to the total friction loss in internal combustion engines. In this work, based upon the experimental observation an existing model for the piston secondary motion and skirt lubrication was improved with a physics-based model describing the oil film separation from full film to partial film. Then the model was applied to a modern turbo-charged SI engine. The piston-skirt FMEP predicted by the model decreased with larger installation clearance, which was also observed from the measurements using IMEP method at the rated. It was found that the main period of the cycle exhibiting friction reduction is in the expansion stroke when the skirt only contacts the thrust side for all tested installation clearances.

In an engine system, the piston pin is subjected to high loading and severe lubrication conditions, and pin seizures still occur during new engine development. A better understanding of the lubricating oil behavior and the dynamics of the piston pin could lead to cost- effective solutions to mitigate these problems. However, research in this area is still limited due to the complexity of the lubrication and the pin dynamics. In this work, a numerical model that considers structure deformation and oil cavitation was developed to investigate the lubrication and dynamics of the piston pin. The model combines multi-body dynamics and elasto-hydrodynamic lubrication. A routine was established for generating and processing compliance matrices and further optimized to reduce computation time and improve the convergence of the equations. A simple built-in wear model was used to modify the pin bore and small end profiles based on the asperity contact pressures.