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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of using neat FAME (Fatty Acid Methyl Ester) in a modern small displacement passenger car diesel engine have been evaluated in this paper. In particular the effects on engine performance at full load with standard (i.e., without any special tuning) ECU calibration were analyzed, highlighting some issues in the low end torque due to the lower exhaust gas temperatures at the turbine inlet, which caused a remarkable decrease of the available boost, with a substantial decrease of the engine torque output, far beyond the expected engine derating due to the lower LHV of the fuel. However, further tests carried out after ECU recalibration, showed that the same torque levels measured under diesel operation can be obtained with neat biodiesel too, thus highlighting the potential for maintaining the same level of performance.

The aim of this work is to analyze particle number and size distribution from a small displacement Euro 5 common rail automotive diesel engine, equipped with a close coupled aftertreatment system, featuring a DOC and a DPF integrated in a single canning. In particular the effects of different combustion processes on PM characteristics were investigated, by comparing measurements made both under normal operating condition and under DPF regeneration mode. Exhaust gas was sampled at engine outlet, at DOC outlet and at DPF outlet, in order to fully characterize PM emissions through the whole exhaust line. After a two stage dilution system, sampled gas was analyzed by means of a TSI 3080 SMPS, in the range from 6 to 240 nm. Particle number and size distribution were evaluated at part load operating conditions, representative of urban driving.

Natural gas is a promising alternative fuel for internal combustion engine application due to its low carbon content and high knock resistance. Performance of natural gas engines is further improved if direct injection, high turbocharger boost level, and variable valve actuation (VVA) are adopted. Also, relevant efficiency benefits can be obtained through downsizing. However, mixture quality resulting from direct gas injection has proven to be problematic. This work aims at developing a mono-fuel small-displacement turbocharged compressed natural gas engine with side-mounted direct injector and advanced VVA system. An injector configuration was designed in order to enhance the overall engine tumble and thus overcome low penetration.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

Non-petroleum based liquid fuels are essential for reducing oil dependence and greenhouse gas generation. Increased substitution of alcohol fuel for petroleum based fuels could be achieved by 1) use in high efficiency spark ignition engines that are employed for heavy duty as well as light duty operation and 2) use of methanol as well as ethanol. Methanol is the liquid fuel that is most efficiently produced from thermo-chemical gasification of coal, natural gas, waste or biomass. Ethanol can also be produced by this process but at lower efficiency and higher cost. Coal derived methanol is in limited initial use as a transportation fuel in China. Methanol could potentially be produced from natural gas at an economically competitive fuel costs, and with essentially the same greenhouse gas impact as gasoline. Waste derived methanol could also be an affordable low carbon fuel.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

The transportation sector in the United States is a major contributor to global energy consumption and carbon dioxide emission. To assess the future potentials of different technologies in addressing these two issues, we used a family of simulation programs to predict fuel consumption for passenger cars in 2020. The selected technology combinations that have good market potential and could be in mass production include: advanced gasoline and diesel internal combustion engine vehicles with automatically-shifting clutched transmissions, gasoline, diesel, and compressed natural gas hybrid electric vehicles with continuously variable transmissions, direct hydrogen, gasoline and methanol reformer fuel cell hybrid electric vehicles with direct ratio drive, and battery electric vehicle with direct ratio drive.

In order to evaluate the potentialities of bioderived diesel fuels, the effect of fueling a 1.9 l displacement HSDI automotive Diesel engine with biodiesel and fossil/biodiesel blend on its emission and combustion characteristics has been investigated. The fuels tested were a typical European diesel, a 50% biodiesel blend in the reference diesel, and a 100% biodiesel, obtained by mixing rape seed methyl ester (RME) and recycled cooking oil (CME). Steady state tests were performed at two different engine speeds (2500 and 4000 rpm), and for a wide range of loads, in order to evaluate the behavior of the fuels under a large number of operating conditions. Engine performance and exhaust emissions were analyzed, along with the combustion process in terms of heat release analysis. Experimental evidences showed appreciably lower CO and HC specific emissions and a substantial increase in NOx levels. A significant reduction of smoke emissions was also obtained.

The potentialities in terms of engine performance and emissions reduction of pure biodiesel were examined on a Common Rail HSDI Diesel engine, trying to define a proper tuning of the injection strategies to bio-fuel characteristics. An experimental investigation was therefore carried out on a typical European passenger car Diesel engine, fuelled with a soybean oil derived biodiesel. A standard European diesel fuel was also used as a reference. In particular, the effects of an equal relative air/fuel ratio at full load condition were analysed; further, a sensitivity study on the outcome of the pilot injection timing and duration at part load on engine emissions was performed. Potentialities in recovering the performance gap between fossil fuel and biodiesel and in reducing NOx specific emissions, affecting only to a limited extent the biodiesel emission benefit in terms of CO, HC and FSN, were highlighted.

Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.

One of the major issues coming out from low temperature fuel cells concerns the production of water vapor as a chemical reaction (between hydrogen and oxygen) by-product and its consequent condensation (at certain operating conditions), determining the presence of an amount of liquid water affecting the performance of the fuel cell stack: the production and the quantity of liquid water are strictly influenced by boundaries and power output conditions. Starting from this point, this work focuses on collecting all the required information available in literature and defining a suitable CFD model able to predict the production of liquid water within the fuel cell, while at the same time localizing it and determining the consequences on the PEM cell performances.

Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

The fuel effects on HCCI operation in a spark assisted direct injection gasoline engine are assessed. The low load limit has been extended with a pilot fuel injection during the negative valve overlap (NVO) period. The fuel matrix consists of hydrocarbon fuels and various ethanol blends and a butanol blend, plus fuels with added ignition improvers. The hydrocarbon fuels and the butanol blend do not significantly alter the high or the low limits of operation. The HCCI operation appears to be controlled more by the thermal environment than by the fuel properties. For E85, the engine behavior depends on the extent that the heat release from the pilot injected fuel in the NVO period compensates for the evaporative cooling of the fuel.

Future exploration missions, including human missions to the Moon and Mars, are expected to have increasingly demanding operational requirements. Generating electrical power, and also maintaining a specific thermal environment, are both critical capabilities for any mission. In the case of exploration, both a wide range of mission types (robotic, human, ISRU etc.) and a variety of environments exist: from interplanetary space, to the shadow of a lunar crater, to the attenuated and red-shifted lighting on the Martian surface, power requirements must be met. This objective could be met with different technologies. The choice is dictated by the operating conditions and the different types of mission. TAS-I is historically mainly involved in missions related to the space exploration with the presence of astronauts. A typical example is the exploration of the Moon with the installation on the Moon surface of a base inclusive of pressurized habitats and rovers.

The effects of using neat and blended (30% vol.) biodiesel, obtained from Rapeseed Methyl Ester (RME) and Jatropha Methyl Ester (JME), in a Euro 5 small displacement passenger car diesel engine have been evaluated in this paper. The impact of biodiesel usage on engine performance at full load was analyzed for a specifically adjusted ECU calibration: the same torque levels measured under diesel operation could be obtained, with lower smoke levels, thus highlighting the potential for maintaining the same level of performance while achieving substantial emissions benefits. In addition, the effects of biodiesel blends on brake-specific fuel consumption and on engine-out exhaust emissions (CO₂, CO, HC, NOx and smoke) were also evaluated at 6 different part load operating conditions, representative of the New European Driving Cycle. Emissions were also measured at the DPF outlet, thus providing information about after-treatment devices efficiencies with biodiesel.

In Motorsports the understanding of the real engine performance within a complete circuit lap is a crucial topic. On the basis of the telemetry data the engineers are able to monitor this performance and try to adapt the engine to the vehicle's and race track's characteristics and driver's needs. However, quite often the telemetry is the sole analysis instrument for the Engine-Vehicle-Driver (EVD) system and it has no prediction capability. The engine optimization for best lap-time or best fuel economy is therefore a topic which is not trivial to solve, without the aid of suitable, reliable and predictive engineering tools. A complete EVD model was therefore built in a GT-SUITE™ environment for a Motorsport racing car (STCC-VW-Scirocco) equipped with a Compressed Natural Gas (CNG) turbocharged S.I. engine and calibrated on the basis of telemetry and test bench data.