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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

The high load limit of a boosted homogeneous-charge-compression-ignition (HCCI) engine operating on negative-valve-overlap (NVO) was assessed. When operating under stoichiometric condition with no external dilution, the load, as measured by the net indicated mean effective pressure (NIMEP), increased with increase in manifold absolute pressure (MAP), and with decrease in trapped amount of residual gas. The maximum pressure rise rate (MPRR), however, also increased correspondingly. When the MAP and the amount of residual gas were adjusted so that the engine operating point could be held at a constant MPRR value, the NIMEP increased with the simultaneous decrease in MAP and residual until the misfire limit was reached. Therefore if a MPRR ceiling is imposed, the high load limit of an HCCI engine is at the intersection of the constraining MPRR line and the misfire line.

In diesel engines the optimization of engine-out emissions, combustion noise and fuel consumption requires the experimental investigation of the effects of different injection strategies as well as of a large number of engine operating variables, such as scheduling of pilot and after pulses, rail pressure, EGR rate and swirl level. Due to the high number of testing conditions involved full factorial approaches are not viable, whereas Design of Experiment techniques have demonstrated to be a valid methodology. However, the results obtained with such techniques require a subsequent critical analysis, so as to investigate the cause and effect relationships between the set of engine operating variables and the combustion process characteristics that affect pollutant formation, noise of combustion and engine efficiency.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.

New methodologies have been developed to optimize EGR rate and injection timing in diesel engines, with the aim of minimizing fuel consumption (FC) and NOx engine-out emissions. The approach entails the application of a recently developed control-oriented engine model, which includes the simulation of the heat release rate, of the in-cylinder pressure and brake torque, as well as of the NOx emission levels. The engine model was coupled with a C-class vehicle model, in order to derive the engine speed and torque demand for several driving cycles, including the NEDC, FTP, AUDC, ARDC and AMDC. The optimization process was based on the minimization of a target function, which takes into account FC and NOx emission levels. The selected control variables of the problem are the injection timing of the main pulse and the position of the EGR valve, which have been considered as the most influential engine parameters on both fuel consumption and NOx emissions.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.

In this study, a new EGR control technique, based on the estimate of the oxygen concentration in the intake manifold, was firstly investigated through numerical simulation and then experimentally tested, both under steady state and transient conditions. The robustness of the new control technique was also tested and compared with that of the conventional EGR control technique by means of both numerical simulation and experimental tests. Substantial reductions of the NOx emissions under transient operating conditions were achieved, and useful knowledge for controlling the EGR flow rate more accurately was obtained.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

Different EGR system layouts (a Long Route, a Short Route, and a combination of the two) were evaluated by means of both numerical simulation and experimental tests. In particular, a one-dimensional fluid-dynamic engine model was built in order to evaluate the potential of a Long Route EGR system as well as the potential of different EGR combinations between Long and Short Route. By means of the one-dimensional model, used as a virtual test bench, the estimations of the NOx emissions, based on the Extended Zeldovich Mechanism (EZM), for the different solutions, were compared and valuable information for the calibration of the coordinated EGR LR, EGR SR and Variable Geometry Turbine (VGT) control systems was obtained.

In this work different internal and external EGR strategies, combined with extreme Miller cycles, were analyzed by means of a one-dimensional CFD simulation code for a Wärtsilä 6-cylinder, 4-strokes, medium-speed marine diesel engine, to evaluate their potential in order to reach the IMO Tier 3 NOx emissions target. By means of extreme Miller cycles, with Early Intake Valve Closures (up to 100 crank angle degrees before BDC), a shorter compression stroke and lower charge temperatures inside the cylinder can be achieved and thanks to the cooler combustion process, the NOx-specific emissions can be effectively reduced. EIVC strategies can also be combined with reductions of the scavenging period (valve overlap) to increase the amount of exhaust gases in the combustion chamber. However, the remarkably high boost pressure levels needed for such extreme Miller cycles, require mandatorily the use of two-stage turbocharging systems.

The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.

A quasi-dimensional multizone combustion model, that was previously developed by the authors, has been refined and applied for the analysis of combustion and emission formation in a EURO V diesel engine equipped with a piezo indirect-acting injection system. The model is based on the integration of the predictive non-stationary variable-profile 1D spray model recently presented by Musculus and Kattke, with a diagnostic multizone thermodynamic model specifically developed by the authors. The multizone approach has been developed starting from the Dec conceptual scheme, and is based on the identification of several homogeneous zones in the combustion chamber, to which mass and energy conservation laws have been applied: an unburned gas zone, made up of air, EGR (Exhaust Gas Recirculation) and residual gas, several fuel/unburned gas mixture zones, premixed combustion burned gas zones and diffusive combustion burned gas zones.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

Nano-structured perovskite-type oxides catalysts La1-xAxFe1-yByO3 (where A = Na, K, Rb and B = Cu), prepared by the Solution Combustion Synthesis (SCS) method and characterized by BET, XRD, FESEM, AAS and catalytic activity tests in microreactors and engine bench, proved to be effective in the simultaneous removal of soot and NO, the two prevalent pollutants in diesel exhaust gases in the temperature range 350-450°C. The best compromise between soot and nitrogen oxide abatement was shown by La-K-Cu-FeO3 catalyst which displayed the highest catalytic activity towards carbon combustion and the highest NO conversion activity.

This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.

A novel engine management strategy for achieving fast catalyst light-off without the use of an exhaust air pump in a port-fuel-injected, spark ignition engine was developed. A conventional 4-cylinder engine was operated with three cylinders running rich and the fourth one as an air pump to supply air to the exhaust manifold. Under steady-state cold coolant conditions, this strategy achieved near total oxidation of CO and HC with sufficiently retarded spark timing, resulting in a 400% increase in feedgas enthalpy flow and a 90% reduction in feedgas HC emissions compared to conventional operation. The strategy was also evaluated for crank starts. Using the existing engine hardware, implementing the strategy resulted in a reduction in catalyst light-off time from 28.0 seconds under conventional operation to 9.1 seconds.

Although the use of Exhaust Gas Recirculation (EGR) is nowadays mandatory for automotive diesel engines to achieve NOx emissions levels complying with more and more stringent legislation requirements, electronically controlled EGR systems still represent an expensive technology, often unsuitable for small diesel engines for off-road applications or for two/three wheelers. An interesting option for these categories of small diesel engines is the so-called “internal EGR”, which is obtained by modifying the intake or the exhaust valve lift profile, in order to increase the fraction of exhaust residuals at the end of the intake stroke. Different valve lift profiles were therefore evaluated for a 2 cylinders, 700 cc, Lombardini IDI diesel engine, equipping a light 4 wheelers vehicle.

Introduction of an array of new electrical and electronic features into future vehicles is generating vehicle electrical power requirements that exceed the capabilities of today's 14 volt electrical systems. In the near term (5 to 10 years), the existing 14V system will be marginally capable of supporting the expected additional loads with escalating costs for the associated charging system. However, significant increases in vehicle functional content are expected as future requirements to meet longer-term (beyond 10 years) needs in the areas of emission control, fuel economy, safety, and passenger comfort. A higher voltage electrical system will be required to meet these future requirements. This paper explores the functional needs that will mandate a higher voltage system and the benefits derivable from its implementation.