Search Results

Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

The objective of this research is a detailed investigation of unburned hydrocarbon (UHC) in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the mechanisms that control the formation of UHC via experiments and simulations in a 0.48L signal-cylinder light duty engine operating at 2000 r/min and 5.5 bar IMEP with multiple injections. A multi-gas FTIR along with other gas and smoke emissions instruments are used to measure exhaust UHC species and other emissions. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, analysis of spray trajectory with a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2].

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The influence of soy- and palm-based biofuels on the in-cylinder sources of unburned hydrocarbons (UHC) and carbon monoxide (CO) was investigated in an optically accessible research engine operating in a partially premixed, low-temperature combustion regime. The biofuels were blended with an emissions certification grade diesel fuel and the soy-based biofuel was also tested neat. Cylinder pressure and emissions of UHC, CO, soot, and NOx were obtained to characterize global fuel effects on combustion and emissions. Planar laser-induced fluorescence was used to capture the spatial distribution of fuel and partial oxidation products within the clearance and bowl volumes of the combustion chamber. In addition, late-cycle (30° and 50° aTDC) semi-quantitative CO distributions were measured above the piston within the clearance volume using a deep-UV LIF technique.

The characteristics of ethanol autoignition and the associated HCCI performance are examined in this work. The experiments were conducted over wide ranges of engine speed, load and intake boost pressure (Piⁿ) in a single-cylinder HCCI research engine (0.98 liters) with a CR = 14 piston. The data show that pure ethanol is a true single-stage ignition fuel. It does not exhibit low-temperature heat release (LTHR), not even for boosted operation. This makes ethanol uniquely different from conventional distillate fuels and offers several benefits: a) The intake temperature (Tiⁿ) does not have to be adjusted much with changes of engine speed, load and intake boost pressure. b) High Piⁿ can be tolerated without running out of control authority because of an excessively low Tiⁿ requirement. However, by maintaining true single-stage ignition characteristics, ethanol also shows a relatively low temperature-rise rate just prior to its hot ignition point.

This paper first summarizes a new theoretical description that quantifies the effects of real-fluid thermodynamics on liquid fuel injection processes as a function of pressure at typical engine operating conditions. It then focuses on the implications this has on modeling such flows with emphasis on application of the Large Eddy Simulation (LES) technique. The theory explains and quantifies the major differences that occur in the jet dynamics compared to that described by classical spray theory in a manner consistent with experimental observations. In particular, the classical view of spray atomization as an appropriate model at some engine operating conditions is questionable. Instead, non-ideal real-fluid behavior must be taken into account using a multicomponent formulation that applies to hydrocarbon mixtures at high-pressure supercritical conditions.

Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel ϕ- sensitive so that partial fuel stratification (PFS) can be applied for higher loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion.

Negative valve overlap (NVO) is a viable control strategy that enables low-temperature gasoline combustion (LTGC) at low loads. Thermal effects of NVO fueling on main combustion are well understood, but fuel reforming chemistry during NVO has not been extensively studied. The objective of this work is to analyze the impact of global equivalence ratio and available oxidizer on NVO product concentrations. Experiments were performed in a LTGC single-cylinder engine under a sweep of NVO oxygen concentration and NVO fueling rates. Gas sampling at the start and end of the NVO period was performed via a custom dump-valve apparatus with detailed sample speciation by gas chromatography. Single-zone reactor models using detailed chemistry at relevant mixing and thermodynamic conditions were used in parallel to the experiments to evaluate expected yields of partially oxidized species under representative engine time scales.

Well-mixed lean SI engine operation can provide improvements of the fuel economy relative to that of traditional well-mixed stoichiometric SI operation. This work examines the use of two methods for improving the stability of lean operation, namely multi-pulse transient plasma ignition and intake air preheating. These two methods are compared to standard SI operation using a conventional high-energy inductive ignition system without intake air preheating. E85 is the fuel chosen for this study. The multi-pulse transient plasma ignition system utilizes custom electronics to generate 10 kHz bursts of 10 ultra-short (12ns), high-amplitude pulses (200 A). These pulses were applied to a custom spark plug with a semi-open ignition cavity. High-speed imaging reveals that ignition in this cavity generates a turbulent jet-like early flame spread that speeds up the transition from ignition to the main combustion event.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

Spark-ignition (SI) engine efficiency is typically limited by fuel auto-ignition resistance, which is described in practice by the Research Octane Number (RON) and the Motor Octane Number (MON). The goal of this work is to assess whether fuel properties (i.e. RON, MON, and heat of vaporization) are sufficient to describe the antiknock behavior of varying gasoline formulations in modern engines. To this end, the auto-ignition resistance of three compositionally dissimilar gasoline-like fuels with identical RON values and varying or non-varying MON values were evaluated in a modern, prototype, 12:1 compression ratio, high-swirl (by nature of intake valve deactivation), directly injected spark ignition (DISI) engine at 1400 RPM. The three gasolines are an alkylate blend (RON=98, MON=97), a blend with high aromatic content (RON=98, MON=88), and a blend of 30% ethanol by volume with a gasoline BOB (RON=98, MON=87; see Table 2 for details).

Well-mixed lean or dilute SI engine operation can provide efficiency improvements relative to that of traditional well-mixed stoichiometric SI operation. However, the realized gains depend on the ability to ensure stable, complete and fast combustion. In this work, the influence of fuel type is examined for gasoline, E30 and E85. Several enabling techniques are compared. For enhanced ignition stability, a multi-pulse (MP) transient plasma ignition system is compared to a conventional high-energy inductive spark ignition system. Combined effects of fuel type and intake-gas preheating are examined. Also, the effects of dilution type (air or N2-simulated EGR) on lean efficiency gains and stability limits are clarified. The largest efficiency improvement is found for lean gasoline operation using intake preheating, showing the equivalent of a 20% fuel-economy gain relative to traditional non-dilute stoichiometric operation.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

Experiments conducted with a set of reference diesel fuels in an optically accessible, compression-ignition engine have revealed a strong correlation between hydrocarbon (HC) emissions and the flame lift-off length at the end of the premixed burn (EOPMB), with increasing HC emissions associated with longer lift-off lengths. The correlation is largely independent of fuel properties and charge-gas O2 mole fraction, but varies with fuel-injection pressure. A transient, one-dimensional jet model was used to investigate three separate mechanisms that could explain the observed impact of lift-off length on HC emissions. Each mechanism relies on the formation of mixtures that are too lean to support combustion, or “overlean.” First, overlean regions can be formed after the start of fuel injection but before the end of the premixed burn.

Detailed exhaust speciation measurements were made on an HCCI engine fueled with iso-octane over a range of fueling rates, and over a range of fuel-stratification levels. Fully premixed fueling was used for the fueling sweep. This sweep extended from a fuel/air equivalence ratio (ϕ) of 0.28, which is sufficiently high to achieve a combustion efficiency of 96%, down to a below-idle fueling rate of ϕ = 0.08, with a combustion efficiency of only 55%. The stratification sweep was conducted at an idle fueling rate, using an 8-hole GDI injector to vary stratification from well-mixed conditions for an early start of injection (SOI) (40°CA) to highly stratified conditions for an SOI well up the compression stroke (325°CA, 35°bTDC-compression). The engine speed was 1200 rpm. At each operating condition, exhaust samples were collected and analyzed by GC-FID for the C1 and C2 hydrocarbon (HC) species and by GC-MS for all other species except formaldehyde and acetaldehyde.

Low-temperature combustion (LTC) strategies for diesel engines are of increasing interest because of their potential to significantly reduce particulate matter (PM) and nitrogen oxide (NOx) emissions. LTC with late fuel injection further offers the benefit of combustion phasing control because ignition is closely coupled to the fuel injection event. But with a short ignition-delay, fuel jet mixing processes must be rapid to achieve adequate premixing before ignition. In the current study, mixing and pollutant formation of late-injection LTC are studied in a single-cylinder, direct-injection, optically accessible heavy-duty diesel engine using three laser-based imaging diagnostics. Simultaneous planar laser-induced fluorescence of the hydroxyl radical (OH) and combined formaldehyde (H2CO) and polycyclic aromatic hydrocarbons (PAH) are compared with vapor-fuel concentration measurements from a non-combusting condition.

Shadowgraph/schlieren imaging techniques have often been used for flow visualization of reacting and non-reacting systems. In this paper we show that high-speed shadowgraph visualization in a high-pressure chamber can also be used to identify cool-flame and high-temperature combustion regions of diesel sprays, thereby providing insight into the time sequence of diesel ignition and combustion. When coupled to simultaneous high-speed Mie-scatter imaging, chemiluminescence imaging, pressure measurement, and spatially-integrated jet luminosity measurements by photodiode, the shadowgraph visualization provides further information about spray penetration after vaporization, spatial location of ignition and high-temperature combustion, and inactive combustion regions where problematic unburned hydrocarbons exist. Examples of the joint application of high-speed diagnostics include transient non-reacting and reacting injections, as well as multiple injections.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.