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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Catalysts and filters continue to be applied widely to meet particulate matter regulations across new and retrofit diesel engines. Soot management of the filter continues to be enhanced, including regeneration methodologies. Concerns regarding in-cylinder post-injection of fuel for active regeneration increases interests in directly injecting this fuel into the exhaust. Performance of secondary fuel injection layouts is discussed, and sensitivities on thermal uniformity are measured and analyzed, providing insight to packaging challenges and methods to characterize and improve application designs. Influences of end cone geometries, mixers, and injector mounting positions are quantified via thermal distribution at each substrate's outlet. A flow laboratory is applied for steady state characterization, repeated on an engine dynamometer, which also provides transient results across the NRTC.

This study presents a probabilistic life (failure) and damage assessment approach for components under general fatigue loadings, including constant amplitude loading, step-stress loading, and variable amplitude loading. The approach consists of two parts: (1) an empirical probabilistic distribution obtained by fitting the fatigue failure data at various stress range levels, and (2) an inverse technique, which transforms the probabilistic life distribution to the probabilistic damage distribution at any applied cycle. With this approach, closed-form solutions of damage as function of the applied cycle can be obtained for constant amplitude loading. Under step-stress and variable amplitude loadings, the damage distribution at any cycle can be calculated based on the accumulative damage model in a cycle-by-cycle manner. For Gaussian-type random loading, a cycle-by-cycle equivalent, but a much simpler closed-form solution can be derived.

In the Big Data era, the capability in statistical and probabilistic data characterization, data pattern identification, data modeling and analysis is critical to understand the data, to find the trends in the data, and to make better use of the data. In this paper the fundamental probability concepts and several commonly used probabilistic distribution functions, such as the Weibull for spectrum events and the Pareto for extreme/rare events, are described first. An event quadrant is subsequently established based on the commonality/rarity and impact/effect of the probabilistic events. Level of measurement, which is the key for quantitative measurement of the data, is also discussed based on the framework of probability. The damage density function, which is a measure of the relative damage contribution of each constituent is proposed. The new measure demonstrates its capability in distinguishing between the extreme/rare events and the spectrum events.

A new ring pack model has been developed based on the curved beam finite element method. This paper describes the first part of this model: simulating gas pressure in different regions above piston skirt and ring dynamic behavior of two compression rings and a twin-land oil control ring. The model allows separate grid divisions to resolve ring structure dynamics, local force/pressure generation, and gas pressure distribution. Doing so enables the model to capture both global and local processes at their proper length scales. The effects of bore distortion, piston secondary motion, and groove distortion are considered. Gas flows, gas pressure distribution in the ring pack, and ring structural dynamics are coupled with ring-groove and ring-liner interactions, and an implicit scheme is employed to ensure numerical stability. The model is applied to a passenger car engine to demonstrate its ability to predict global and local effects on ring dynamics and oil transport.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

Rare earths are a group of elements whose availability has been of concern due to monopolistic supply conditions and environmentally unsustainable mining practices. To evaluate the risks of rare earths availability to automakers, a first step is to determine raw material content and value in vehicles. This task is challenging because rare earth elements are used in small quantities, in a large number of components, and by suppliers far upstream in the supply chain. For this work, data on rare earth content reported by vehicle parts suppliers was assessed to estimate the rare earth usage of a typical conventional gasoline engine midsize sedan and a full hybrid sedan. Parts were selected from a large set of reported parts to build a hypothetical typical mid-size sedan. Estimates of rare earth content for vehicles with alternative powertrain and battery technologies were made based on the available parts' data.

In today's highly competitive automotive markets manufacturers must provide high quality products to survive. Manufacturers can achieve higher levels of quality by changing or improving their manufacturing process and/or by product inspection where many strategies with different cost implications are often available. Cost of Quality (CoQ) reconciles the competing objectives of quality maximization and cost minimization and serves as a useful framework for comparing available manufacturing process and inspection alternatives. In this paper, an analytic CoQ framework is discussed and some key findings are demonstrated using a set of basic inspection strategy scenarios. A case of a welded automotive assembly is chosen to explore the CoQ tradeoffs in inspection strategy selection and the value of welding process improvement. In the assembly process, many individual components are welded in series and each weld is inspected for quality.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

The fuel energy consumption of subsonic air transportation is examined. The focus is on identification and quantification of fundamental engineering design tradeoffs which drive the design of subsonic tube and wing transport aircraft. The sensitivities of energy efficiency to recent and forecast technology developments are also examined.

A rotating spacecraft which encloses an atmospheric pressure vessel poses unique challenges for thermal control. In any given location, the artificial gravity vector is directed from the center to the periphery of the vehicle. Its local magnitude is determined by the mathematics of centripetal acceleration and is directly proportional to the radius at which the measurement is taken. Accordingly, we have a system with cylindrical symmetry, featuring microgravity at its core and increasingly strong gravity toward the periphery. The tendency for heat to move by convection toward the center of the craft is one consequence which must be addressed. In addition, fluid flow and thermal transfer is markedly different in this unique environment. Our strategy for thermal control represents a novel approach to address these constraints. We present data to theoretically and experimentally justify design decisions behind the Mars Gravity Biosatellite's proposed payload thermal control subassembly.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

Battery packs for Hybrids, Plug-in Hybrids, and Electric Vehicles are assembled from a system of modules (sheets) with a tight sheet metal casing around them. Each module consists of an array of individual cells which vary in the composition of electrodes and separator from one manufacturer to another. In this paper a general procedure is outlined on the development of a constitutive and computational model of a cylindrical cell. Particular emphasis is placed on correct prediction of initiation and propagation of a tearing fracture of the steel can. The computational model correctly predicts rupture of the steel can which could release aggressive chemicals, fumes, or spread the ignited fire to the neighboring cells. The initiation site of skin fracture depends on many factors such as the ductility of the casing material, constitutive behavior of the system of electrodes, and type of loading.

In order to satisfy tightening global emissions regulations, diesel truck manufacturers are striving to meet increasingly stringent Oxides of Nitrogen (NOx) reduction standards. The majority of heavy duty diesel trucks have integrated urea SCR NOx abatement strategies. To this end, aftertreatment systems need to be properly engineered to achieve high conversion efficiencies. A EuroV intent urea SCR system is evaluated and failed to meet NOx conversion targets with severe urea deposit formation. Systematic enhancements of the design have been performed to enable it to meet targets, including emission reduction efficiency via improved reagent mixing, evaporation, distribution, back pressure, and removing of urea deposits. Multiple urea mixers, injector mounting positions and various system layouts are developed and evaluated, including both CFD analysis and full scale laboratory tests.

With increasing applications of urea SCR for NOx emission reduction, improving the system performance and durability has become a high priority. A typical urea SCR system includes a urea injector, injector housing, mixer, and appropriate pipe configurations to allow continuous urea injection into the exhaust stream and evaporation of urea solution into gaseous products. Continuous operation at various conditions with high NOx reduction is possible, but one problem that threatens the life and performance of these systems is urea deposit. When urea or its byproducts become deposited on the inner surfaces of the system including walls, mixers, injector housings and substrates it can create concerns of backpressure and material deteriorations. In addition, deposits as a waste of reagents can negatively affect engine operation, emissions performance and DEF economy. Urea deposit behavior is explored in terms of heat transfer, pipe geometry, injector layout and mixing mechanisms.

The transportation sector in the United States is a major contributor to global energy consumption and carbon dioxide emission. To assess the future potentials of different technologies in addressing these two issues, we used a family of simulation programs to predict fuel consumption for passenger cars in 2020. The selected technology combinations that have good market potential and could be in mass production include: advanced gasoline and diesel internal combustion engine vehicles with automatically-shifting clutched transmissions, gasoline, diesel, and compressed natural gas hybrid electric vehicles with continuously variable transmissions, direct hydrogen, gasoline and methanol reformer fuel cell hybrid electric vehicles with direct ratio drive, and battery electric vehicle with direct ratio drive.

Determining the fundamental role of gravity in vital biological systems in space is one of six science and research areas that provides the philosophical underpinning for why NASA exists. The study of cells, tissues, and microorganisms in a spaceflight environment holds the promise of answering multiple intriguing questions about how gravity affects living systems. To enable these studies, specimens must be maintained in an environment similar to that used in a laboratory. Cell culture studies under normal laboratory conditions involve maintaining a highly specialized environment with the necessary temperature, humidity control, nutrient, and gas exchange conditions. These same cell life support conditions must be provided by the International Space Station (ISS) Cell Culture Unit (CCU) in the unique environment of space. The CCU is a perfusion-based system that must function in microgravity, at unit gravity (1g) on earth, and from 0.1g up to 2g aboard the ISS centrifuge rotor.

The US Air Force (USAF) has evolved a policy for the acquisition of fighter jet engines (FJE). In the 1970s and 1980s that policy placed a premium on FJE performance primarily measured by the metric: thrust/engine weight. In the 1990s, the USAF policy changed from an emphasis on performance to reduced life-cycle cost with a premium on sustainment. This paper reports the results of a study of how the USAF and Corporation Alpha (Alpha) have adapted their processes, practices, and policies to design, develop, manufacture, test, and sustain a family of FJEs. Each member of the family of FJEs is sequentially linked relative to insertion of technology designed to reduce sustainment costs. In addition to the technology linkages, the development of the family of FJEs selected for this case study is also tracked relative to US Department of Defense and USAF policy and industry design, build, and maintain processes, methods, and tools.

A probabilistic distribution function roughly consists of two parts: the middle part and the tails. The fatigue life distribution at a stress/load level is often described with two-parameter lognormal or Weibull distribution functions, which are more suitable for modeling the mean (middle) behaviors. The domains of the conventional probabilistic distribution functions are often unbounded, either infinite small (0 for the two-parameter Weibull) or infinite large or both. For most materials in low- and medium-cycle fatigue regimes, the domains of fatigue lives are usually bounded, and the inclusion of the bounds in a probabilistic model is often critical in some applications, such as product validation and life management. In this paper, four- and five-parameter Weibull distribution functions for the probabilistic distributions with bounds are developed. Finally, the applications of these new models in fatigue data analysis and damage assessment are provided and discussed.

Life testing or test-to-failure method and binomial testing method are the two most commonly used methods in product validation and reliability demonstration. The two-parameter Weibull distribution function is often used in the life testing and almost exclusively used in the extended time testing, which can be considered as an accelerated testing method by appropriately extending the testing time but with significantly reduced testing samples. However, the fatigue data from a wide variety of sources indicate that the three-parameter Weibull distribution function with a threshold parameter at the left tail is more appropriate for fatigue life data with large sample sizes. The uncertainties introduced from the assumptions about the underlying probabilistic distribution would significantly affect the interpretation of the test data and the assessment of the performance of the accelerated binomial testing methods, therefore, the selection of a probabilistic model is critically important.