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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

One of the issues in stamping of advanced high strength steels (AHSS) is the stretch bending fracture on a sharp radius (commonly referred to as shear fracture). Shear fracture typically occurs at a strain level below the conventional forming limit curve (FLC). Therefore it is difficult to predict in computer simulations using the FLC as the failure criterion. A modified Mohr-Coulomb (M-C) fracture criterion has been developed to predict shear fracture. The model parameters for several AHSS have been calibrated using various tests including the butter-fly shaped shear test. In this paper, validation simulations are conducted using the modified (M-C) fracture criterion for a dual phase (DP) 780 steel to predict fracture in the stretch forming simulator (SFS) test and the bending under tension (BUT) test. Various deformation fracture modes are analyzed, and the range of usability of the criterion is identified.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Polyvinyl Butyral (PVB) laminated glass has been widely used in automotive industry as windshield material. Cracks on the PVB laminated glass contain large amount of impact information, which can contribute to accident reconstruction investigation. In this study, the impact-induced in-plane dynamic cracking of the PVB laminated glass is investigated. Firstly, a drop-weight combined with high-speed photography experiment device is set up to investigate the radial cracks propagation on the PVB laminated glass sheet. Both the morphology and the velocity time history curve of the radial cracks are recorded and analyzed to investigate the basic mechanism of the crack propagation process. Afterwards, a three-dimensional laminated plate finite element (FE) model is set up and dynamic cracking process is simulated based on the extended finite element method (XFEM).

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Polyvinyl butyral (PVB) film and SentryGlas® Plus (SGP) film have been widely used in automotive windshield and architecture curtain serving as protective interlayer materials. Viscoelasticity is the unique property of such film materials, which can contribute to improving impact resistance and energy absorbing characteristics of laminated glass. In this study, the uniaxial tensile creep and stress relaxation tests are conducted to investigate the viscoelasticity of PVB and SGP films used in laminated glass. Firstly, tensile creep and stress relaxation tests of PVB film (0.76mm) and SGP film with three thickness (0.89mm, 1.14mm and 1.52mm) are conducted using Instron universal testing machine to obtain creep and stress relaxation curves. Afterwards, both viscoelastic models (Burgers model, Maxwell-Weichert model) and empirical equations (Findley power law, Kohlrausch equation) are applied to simulate the creep and stress relaxation results.

Fuel quality has a significant influence on the combustion engine operation. In recent years the increasing concerns about environmental protection, energy saving, energy security and the requirements of protecting fuel injection and aftertreatment systems have been major driving forces for the Chinese fuel specification evolution. The major property changes in the evolution of Chinese national gasoline and diesel standards are introduced and the reasons behind these changes are analyzed in this paper. The gasoline fuel development from State I to State VI-B involved a decrease of sulfur, manganese, olefins, aromatics and benzene content. The diesel fuel quality improvement from State I to State VI included achieving low sulfur fuels and a cetane number (CN) increase. Provincial fuel standards, stricter than corresponding national standards, were implemented in economically developed areas in the past.

As mechanical damage induced thermal runaway of lithium-ion batteries has become one of the research hotspots, it is quite crucial to understand the mechanical behavior of component materials of lithium battery. This study focuses on the mechanical performance of separators and electrodes under different loading conditions and the error sources analysis for test results. Uniaxial tensile tests were conducted under both quasi-static and dynamic loading conditions. The strain was acquired through the combination of high speed camera and digital image correlation (DIC) method while the force was obtained with a customized load cell. Noticeable anisotropy and strain rate effect were observed for separators. The fracture mode of separators is highly correlated to the microscopic fiber orientation. To demonstrate the correlation microscopic images of separator material were obtained through SEM to match the facture edges of tensile tests at different loading directions.

This article is concerned with identification of true stress-strain curve under biaxial tension of thermoplastic polymers. A new type of biaxial tension attachment was embedded first in a universal material test machine, which is able to transform unidirectional loading of the test machine to biaxial loading on the specimen with constant velocity. Cruciform specimen geometry was optimized via FE modeling. Three methods of calculating true stress in biaxial tension tests were compared, based on incompressibility assumption, linear elastic theory and inverse engineering method, respectively. The inverse engineering method is more appropriate for thermoplastic polymers since it considers the practical volume change of the material during biaxial tension deformation. The strategy of data processing was established to obtain biaxial tension true stress-strain curves of different thermoplastic polymers.

The mechanical behavior of polyvinyl butyral (PVB) film plays an important role in windshield crashworthiness and pedestrian protection and should be depth study. In this article, the uniaxial tension tests of PVB film at various strain rates (0.001 s-1, 0.01 s-1, 0.1 s-1, 1 s-1) and temperatures (-10°C, 0°C, 10°C, 23°C, 40°C, 55°C, 70°C) are conducted to investigate its mechanical behavior. Then, temperature and strain rate dependent viscoelastic characteristics of PVB are systematically studied. The results show that PVB is a kind of temperature and strain rate sensitive thermal viscoelastic material. Temperature increase and strain rate decrease have the same influence on mechanical properties of PVB. Besides, the mechanical characteristics of PVB change non-linearly with temperature and strain rate. Finally, two thermal viscoelastic constitutive model (ZWT model and DSGZ model) are suggested to describe the tension behavior of PVB film at various strain rates and temperatures.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

In recent years, structural adhesives have rapidly become the preferred alternative to resistance spot welding in fabricating stronger, lighter aluminum connections. Connections inevitably undergo and must withstand complex quasi-static and/or dynamic loads during their service life. Therefore, understanding how loading conditions affect the mechanical behavior of adhesive joints is vital to their design and the advancement of structural safety. Quasi-static and dynamic tests are performed to analyze both the strength and failure modes of aluminum 6062 substrates bonded by an adhesive (Darbond EP-1506) for an array of loading directions. An Arcan test device, which enables application of mixed-mode loads ranging from pure peel (mode I) to pure shear (mode II) to the adhesive layer, is employed in quasi-static testing. A self-designed medium-speed test machine is utilized to perform dynamic testing.

Metal foil is a widely used material in the automobile industry, which not only is the honeycomb barrier material but is also used as current collectors in Li-ion batteries. Plenty of studies proved that the mechanical property of the metal foil is quite different from that of the metal sheet because of the size effect on microscopic scale, as the metal foil shows a larger fracture stress and a lower ductility than the metal sheet. Meanwhile, the fracture behavior and accurate constitutive model of the metal foil with the consideration of the strain rate effect are widely concerned in further studies of battery safety and the honeycomb. This article conducted experiments on 8011H18 aluminum foil, aiming to explore the quasi-static and dynamic tension testing method and the anisotropic mechanical behavior of the very thin foil. Two metal foil dog-bone specimens and three types of notched specimens were tested with a strain rate ranging from 2 × 10−4/s to 40/s and various stress states.

The gasoline direct injection (GDI) engine particulate emission sources are assessed under cold start conditions: the fast idle and speed/load combinations representative of the 1st acceleration in the US FTP. The focus is on the accumulation mode particle number (PN) emission. The sources are non-fuel, combustion of the premixed charge, and liquid fuel film. The non-fuel emissions are measured by operating the engine with premixed methane/air or hydrogen/air. Then the PN level is substantially lower than what is obtained with normal GDI operation; thus non-fuel contribution to PN is small. When operating with stoichiometric premixed gasoline/air, the PN level is comparable to the non-fuel level; thus premixed-stoichiometric mixture combustion does not significantly generate particulates. For fuel rich premixed gasoline/air, PN increases dramatically when lambda is less than 0.7 to 0.8.

A new ring pack model has been developed based on the curved beam finite element method. This paper describes the first part of this model: simulating gas pressure in different regions above piston skirt and ring dynamic behavior of two compression rings and a twin-land oil control ring. The model allows separate grid divisions to resolve ring structure dynamics, local force/pressure generation, and gas pressure distribution. Doing so enables the model to capture both global and local processes at their proper length scales. The effects of bore distortion, piston secondary motion, and groove distortion are considered. Gas flows, gas pressure distribution in the ring pack, and ring structural dynamics are coupled with ring-groove and ring-liner interactions, and an implicit scheme is employed to ensure numerical stability. The model is applied to a passenger car engine to demonstrate its ability to predict global and local effects on ring dynamics and oil transport.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

This paper quantifies the potential of electric propulsion systems to reduce petroleum use and greenhouse gas (GHG) emissions in the 2030 U.S. light-duty vehicle fleet. The propulsion systems under consideration include gasoline hybrid-electric vehicles (HEVs), plug-in hybrid vehicles (PHEVs), fuel-cell hybrid vehicles (FCVs), and battery-electric vehicles (BEVs). The performance and cost of key enabling technologies were extrapolated over a 25-30 year time horizon. These results were integrated with software simulations to model vehicle performance and tank-to-wheel energy consumption. Well-to-wheel energy and GHG emissions of future vehicle technologies were estimated by integrating the vehicle technology evaluation with assessments of different fuel pathways. The results show that, if vehicle size and performance remain constant at present-day levels, these electric propulsion systems can reduce or eliminate the transport sector's reliance on petroleum.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

Combustion visualizations were carried out in a constant volume vessel to study the partially premixed combustion of a gasoline-like fuel using high speed imaging. The test fuel (G80H20) is composed by volume 80% commercial gasoline and 20% n-heptane. The effects of ambient gas composition, ambient temperature and injection pressure on G80H20 combustion characteristics were analyzed. Meanwhile, a comparison of the EGR effect on combustion process between G80H20 and diesel was made. Four ambient gas conditions that represent the in-cylinder gas compositions of a heavy-duty diesel engine with EGR ratios of 0%, 20%, 40% and 60% were used to simulate EGR conditions. Variables also include two ambient temperature (910K and 870K) and two injection pressure (20 MPa and 50 MPa) conditions.