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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The high load limit of a boosted homogeneous-charge-compression-ignition (HCCI) engine operating on negative-valve-overlap (NVO) was assessed. When operating under stoichiometric condition with no external dilution, the load, as measured by the net indicated mean effective pressure (NIMEP), increased with increase in manifold absolute pressure (MAP), and with decrease in trapped amount of residual gas. The maximum pressure rise rate (MPRR), however, also increased correspondingly. When the MAP and the amount of residual gas were adjusted so that the engine operating point could be held at a constant MPRR value, the NIMEP increased with the simultaneous decrease in MAP and residual until the misfire limit was reached. Therefore if a MPRR ceiling is imposed, the high load limit of an HCCI engine is at the intersection of the constraining MPRR line and the misfire line.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

One of the issues in stamping of advanced high strength steels (AHSS) is the stretch bending fracture on a sharp radius (commonly referred to as shear fracture). Shear fracture typically occurs at a strain level below the conventional forming limit curve (FLC). Therefore it is difficult to predict in computer simulations using the FLC as the failure criterion. A modified Mohr-Coulomb (M-C) fracture criterion has been developed to predict shear fracture. The model parameters for several AHSS have been calibrated using various tests including the butter-fly shaped shear test. In this paper, validation simulations are conducted using the modified (M-C) fracture criterion for a dual phase (DP) 780 steel to predict fracture in the stretch forming simulator (SFS) test and the bending under tension (BUT) test. Various deformation fracture modes are analyzed, and the range of usability of the criterion is identified.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

The effects of charge motion and laminar flame speeds on combustion and exhaust temperature have been studied by using an air jet in the intake flow to produce an adjustable swirl or tumble motion, and by replacing the nitrogen in the intake air by argon or CO₂, thereby increasing or decreasing the laminar flame speed. The objective is to examine the "Late Robust Combustion" concept: whether there are opportunities for producing a high exhaust temperature using retarded combustion to facilitate catalyst warm-up, while at the same time, keeping an acceptable cycle-to-cycle torque variation as measured by the coefficient of variation (COV) of the net indicated mean effective pressure (NIMEP). The operating condition of interest is at the fast idle period of a cold start with engine speed at 1400 RPM and NIMEP at 2.6 bar. A fast burn could be produced by appropriate charge motion. The combustion phasing is primarily a function of the spark timing.

Polyvinyl Butyral (PVB) laminated glass has been widely used in automotive industry as windshield material. Cracks on the PVB laminated glass contain large amount of impact information, which can contribute to accident reconstruction investigation. In this study, the impact-induced in-plane dynamic cracking of the PVB laminated glass is investigated. Firstly, a drop-weight combined with high-speed photography experiment device is set up to investigate the radial cracks propagation on the PVB laminated glass sheet. Both the morphology and the velocity time history curve of the radial cracks are recorded and analyzed to investigate the basic mechanism of the crack propagation process. Afterwards, a three-dimensional laminated plate finite element (FE) model is set up and dynamic cracking process is simulated based on the extended finite element method (XFEM).

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Polyvinyl butyral (PVB) film and SentryGlas® Plus (SGP) film have been widely used in automotive windshield and architecture curtain serving as protective interlayer materials. Viscoelasticity is the unique property of such film materials, which can contribute to improving impact resistance and energy absorbing characteristics of laminated glass. In this study, the uniaxial tensile creep and stress relaxation tests are conducted to investigate the viscoelasticity of PVB and SGP films used in laminated glass. Firstly, tensile creep and stress relaxation tests of PVB film (0.76mm) and SGP film with three thickness (0.89mm, 1.14mm and 1.52mm) are conducted using Instron universal testing machine to obtain creep and stress relaxation curves. Afterwards, both viscoelastic models (Burgers model, Maxwell-Weichert model) and empirical equations (Findley power law, Kohlrausch equation) are applied to simulate the creep and stress relaxation results.

Due to the rapid development of road infrastructure and vehicle population in China, the fuel consumption and emission of on-road vehicles tested in China World Transient Vehicle Cycle (C-WTVC) cannot indicate the real driving results. But the test results in China Heavy-duty Commercial Vehicle Test Cycle-Coach (CHTC-C) based on the road driving conditions in China are closer to the actual driving data. In this paper, the model for predicting the performance of heavy-duty vehicles is established and validated. The fuel consumption and NOx emission of a Euro VI heavy-duty coach under C-WTVC and CHTC-C tests are calculated by employing the developed model. Furthermore, the fuel consumption of the test coach is optimized and its sensitivity to the driving factors is analyzed.

As mechanical damage induced thermal runaway of lithium-ion batteries has become one of the research hotspots, it is quite crucial to understand the mechanical behavior of component materials of lithium battery. This study focuses on the mechanical performance of separators and electrodes under different loading conditions and the error sources analysis for test results. Uniaxial tensile tests were conducted under both quasi-static and dynamic loading conditions. The strain was acquired through the combination of high speed camera and digital image correlation (DIC) method while the force was obtained with a customized load cell. Noticeable anisotropy and strain rate effect were observed for separators. The fracture mode of separators is highly correlated to the microscopic fiber orientation. To demonstrate the correlation microscopic images of separator material were obtained through SEM to match the facture edges of tensile tests at different loading directions.

This article is concerned with identification of true stress-strain curve under biaxial tension of thermoplastic polymers. A new type of biaxial tension attachment was embedded first in a universal material test machine, which is able to transform unidirectional loading of the test machine to biaxial loading on the specimen with constant velocity. Cruciform specimen geometry was optimized via FE modeling. Three methods of calculating true stress in biaxial tension tests were compared, based on incompressibility assumption, linear elastic theory and inverse engineering method, respectively. The inverse engineering method is more appropriate for thermoplastic polymers since it considers the practical volume change of the material during biaxial tension deformation. The strategy of data processing was established to obtain biaxial tension true stress-strain curves of different thermoplastic polymers.

The mechanical behavior of polyvinyl butyral (PVB) film plays an important role in windshield crashworthiness and pedestrian protection and should be depth study. In this article, the uniaxial tension tests of PVB film at various strain rates (0.001 s-1, 0.01 s-1, 0.1 s-1, 1 s-1) and temperatures (-10°C, 0°C, 10°C, 23°C, 40°C, 55°C, 70°C) are conducted to investigate its mechanical behavior. Then, temperature and strain rate dependent viscoelastic characteristics of PVB are systematically studied. The results show that PVB is a kind of temperature and strain rate sensitive thermal viscoelastic material. Temperature increase and strain rate decrease have the same influence on mechanical properties of PVB. Besides, the mechanical characteristics of PVB change non-linearly with temperature and strain rate. Finally, two thermal viscoelastic constitutive model (ZWT model and DSGZ model) are suggested to describe the tension behavior of PVB film at various strain rates and temperatures.

Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

The first 3 cycles in the cold crank-start process at 20°C are studied in a GDI engine. The focus is on the dependence of the HC and PM/PN emissions of each cycle on the injection strategy and combustion phasing of the current and previous cycles. The PM/PN emissions per cycle decrease by more than an order of magnitude as the crank-start progresses from the 1st to the 3rd cycle, while the HC emissions stay relatively constant. The wall heat transfer, as controlled by the combustion phasing, during the previous cycles has a more significant influence on the mixture formation process for the current cycle than the amount of residual fuel. The results show that the rise in HC emissions caused by the injection spray interacting with the intake valves and piston crown is reduced as the cranking process progresses. Combustion phasing retard significantly reduces the PM emission. The HC emissions, however, are relatively not sensitive to combustion phasing in the range of interest.

This work examines the effect of valve timing during cold crank-start and cold fast-idle (1200 rpm, 2 bar NIMEP) on the emissions of hydrocarbons (HC) and particulate mass and number (PM/PN). Four different cam-phaser configurations are studied in detail: 1. Baseline stock valve timing. 2. Late intake opening/closing. 3. Early exhaust opening/closing. 4. Late intake phasing combined with early exhaust phasing. Delaying the intake valve opening improves the mixture formation process and results in more than 25% reduction of the HC and of the PM/PN emissions during cold crank-start. Early exhaust valve phasing results in a deterioration of the HC and PM/PN emissions performance during cold crank-start. Nevertheless, early exhaust valve phasing slightly improves the HC emissions and substantially reduces the particulate emissions at cold fast-idle.

The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.

In recent years, structural adhesives have rapidly become the preferred alternative to resistance spot welding in fabricating stronger, lighter aluminum connections. Connections inevitably undergo and must withstand complex quasi-static and/or dynamic loads during their service life. Therefore, understanding how loading conditions affect the mechanical behavior of adhesive joints is vital to their design and the advancement of structural safety. Quasi-static and dynamic tests are performed to analyze both the strength and failure modes of aluminum 6062 substrates bonded by an adhesive (Darbond EP-1506) for an array of loading directions. An Arcan test device, which enables application of mixed-mode loads ranging from pure peel (mode I) to pure shear (mode II) to the adhesive layer, is employed in quasi-static testing. A self-designed medium-speed test machine is utilized to perform dynamic testing.

Metal foil is a widely used material in the automobile industry, which not only is the honeycomb barrier material but is also used as current collectors in Li-ion batteries. Plenty of studies proved that the mechanical property of the metal foil is quite different from that of the metal sheet because of the size effect on microscopic scale, as the metal foil shows a larger fracture stress and a lower ductility than the metal sheet. Meanwhile, the fracture behavior and accurate constitutive model of the metal foil with the consideration of the strain rate effect are widely concerned in further studies of battery safety and the honeycomb. This article conducted experiments on 8011H18 aluminum foil, aiming to explore the quasi-static and dynamic tension testing method and the anisotropic mechanical behavior of the very thin foil. Two metal foil dog-bone specimens and three types of notched specimens were tested with a strain rate ranging from 2 × 10−4/s to 40/s and various stress states.