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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Due to the rapid development of road infrastructure and vehicle population in China, the fuel consumption and emission of on-road vehicles tested in China World Transient Vehicle Cycle (C-WTVC) cannot indicate the real driving results. But the test results in China Heavy-duty Commercial Vehicle Test Cycle-Coach (CHTC-C) based on the road driving conditions in China are closer to the actual driving data. In this paper, the model for predicting the performance of heavy-duty vehicles is established and validated. The fuel consumption and NOx emission of a Euro VI heavy-duty coach under C-WTVC and CHTC-C tests are calculated by employing the developed model. Furthermore, the fuel consumption of the test coach is optimized and its sensitivity to the driving factors is analyzed.

Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

In this paper, a hybrid combustion mode in four-stroke gasoline direct injection engines was studied. Switching cam profiles and injection strategies simultaneously was adopted to obtain a rapid and smooth switch between SI mode and HCCI mode. Based on the continuous pressure traces and corresponding emissions, HCCI steady operation, HCCI transient process (combustion phase adjustment, SI-HCCI, HCCI-SI, HCCI cold start) were studied. In HCCI mode, HCCI combustion phase can be adjusted rapidly by changing the split injection ratio. The HCCI control strategies had been demonstrated in a Chery GDI2.0 engine. The HCCI engine simulation results show that, oxygen and active radicals are stored due to negative valve overlap and split fuel injection under learn burn condition. This reduces the HCCI sensitivity on inlet boundary conditions, such as intake charge and intake temperature. The engine can be run from 1500rpm to 4000rpm in HCCI mode without spark ignition.

Advanced compression ignition combustion system which reduces simultaneously both nitride oxides (NOx) and particulate matter (PM) is a promising approach to meet future emission regulations. In order to achieve advanced compression ignition, flexible fuel injection is required for ultra-early and post-TDC injections, which conventional injector fails to accomplish due to wall-wetting effect. In this work, special injectors with the spray angle of 60 degree are applied on a 4 cylinder mass-production diesel engine without modification of the engine configuration. For application-oriented study, sweep experiments of injection timings and durations, fuel injection pressure and the boost pressure are carried out to investigate the relationships between the control parameters and the engine performance. Model based calibration and real application tests validate the maximum applicable operation range of maximum speed of 2200 RPM and IMEP of 8.0 bar.

Gasoline direct injection (GDI) engines have been developed rapidly in recent years, driven by stringent legislative requirements on vehicle fuel efficiency and emissions. However, one challenge facing GDI is the formation of particulate emissions, particularly with the presence of injector tip deposits. The Chinese market features some gasoline fuels that contain no detergent additives and are prone to deposit formation, which can affect engine performance and emissions. The use of detergent additives to mitigate the formation of injector deposits in a GDI engine was investigated in this study by testing a 1.5L turbocharged GDI engine available in the Chinese market. The engine was operated both on base gasoline and on gasoline dosed with detergent additives to evaluate the effect on injector deposit formation and engine performance and emissions.

Low temperature combustion (LTC) is an advanced combustion mode, which can achieve low emissions of NOx and PM simultaneously, and keep relatively high thermal efficiency at the same time. However, one of the major challenges for LTC is the cold condition. In cold conditions, stable compression ignition is hard to realize, while thermal efficiency and emissions deteriorate, especially for gasoline or fuel with high octane number. This study presents using pressure sensor glow plugs (PSG) to realize Glow plug assisted compression ignition (GA-CI) at cold conditions. Further, a glow plug control unit (GPCU) is developed, a closed-loop power feedback control algorithm is introduced based on GPCU. In the experiment, engine coolant temperature is swept. Experimental results show that GA-CI has earlier combustion phases, larger combustion duration and higher in-cylinder pressure. And misfire is avoided, cycle-to-cycle variations are greatly reduced.

This research focuses on the potential of Homogeneous Charge Induced Ignition (HCII) combustion meeting the Euro V emission standard on a heavy-duty multi-cylinder engine using a simple after-treatment system. However, in our previous studies, it was found that the gasoline ratio was limited in HCII by the over-high compression ratio (CR). In this paper, the effects of reducing CR on the performances of HCII at medium and high loads were explored by experimental methods. It was found that by reducing CR from 18:1 to 16:1 the peak in-cylinder pressure and the peak pressure rise rate were effectively reduced and the gasoline ratio range could be obviously extended. Thus, the combustion and emission characteristics of HCII at medium and high loads were noticeably improved. Soot emissions can be significantly reduced because of the increase of premixed combustion ratio. The reduction could be over 50% especially at high load and high speed conditions.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

Compressed Natural Gas (CNG), because of its low cost, high H/C ratio, and high octane number, has great potential in automotive industry, especially for heavy-duty commercial vehicles. However, relative slow flame speed of natural gas leads to long combustion duration and low thermal efficiency and tends to cause knock combustion at high load, which will aggravate engine thermal load and reliability. Enhancing turbulence intensity in combustion chamber is an effective way to accelerate flame propagation speed and improve combustion performance. In this study, the flow simulations of several piston bowls with different inner-convex forms were carried out using three-dimensional computational fluid dynamics (3D-CFD) software CONVERGE. The numerical results showed the piston bowls with inner-convex could disturb the charge swirl motion and enhance turbulence of different intensity. A hexagram geometry bowl was proved to have the best function in strengthening turbulence intensity.

This study investigates the performance of a diesel engine fueled with naphtha under different load by varying injection parameters and exhaust gas recirculation (EGR) rate. The experiments were conducted on a 1.9-liter common rail diesel engine with a compression ratio of 17.5. Naphtha with a research octane number of 60.5 was tested. Three multi-injection strategies were designed. Each injection strategy, aided with EGR, conducts a characteristic combustion mode. Multi-injection strategies and single-injection strategy were tested and compared at one operating point under different main injection timing and EGR conditions. Results indicate that the well-designed multi-injection strategy has advantages over the single injection strategy in lowering noise, emissions and improving combustion efficiency. Among the three strategies, the strategy with 15-degree pilot timing and 2mg/cycle pilot injection could achieve both low NOx and PM emissions without sacrificing much fuel efficiency.

Internal combustion engines for plug-in hybrid heavy duty trucks, especially long haul trucks, could play an important role in facilitating use of battery power. Power from a low carbon electricity source could thereby be employed without an unattractive vehicle cost increase or range limitation. The ideal engine should be powered by a widely available affordable liquid fuel, should minimize air pollutant emissions, and should provide lower greenhouse gas emissions. Diesel engines could fall short in meeting these objectives, especially because of high emissions. In this paper we analyze the potential for a flex fuel gasoline-alcohol engine approach for a series hybrid powertrain. In this approach the engine would provide comparable (or possibly greater) efficiency than a diesel engine while also providing 90 around lower NOx emissions than present cleanest diesel engine vehicles. Ethanol or methanol would be employed to increase knock resistance.

Gasoline direct injection (GDI) engine technology is now widely used due to its high fuel efficiency and low CO2 emissions. However, particulate emissions pose one challenge to GDI technology, particularly in the presence of fuel injector deposits. In this paper, a 4-cylinder turbocharged GDI engine in the Chinese market was selected and operated at 2000rpm and 3bar BMEP condition for 55 hours to accumulate injector deposits. The engine spark timing, cylinder pressure, combustion duration, brake specific fuel consumption (BSFC), gaseous pollutants which include total hydro carbon (THC), NOx (NO and NO2) and carbon dioxide (CO), and particulate emissions were measured before and after the injector fouling test at eight different operating conditions. Test results indicated that mild injector fouling can result in an effect on engine combustion and emissions despite a small change in injector flow rate and pulse width.

Ammonia is employed as the carbon-free fuel in the future engine, which is consistent with the requirements of the current national dual-carbon policy. However, the great amount of NOx and unburned NH3/H2 in the exhaust emissions is produced from combustion of ammonia and is one kind of the most strictly controlled pollutants in the emission regulation. This paper aims to investigate the NOx and unburned NH3/H2 generative process and emission characteristics by CFD simulation during the engine combustion. The results show that the unburned ammonia and hydrogen emissions increase with an increase of equivalence ratio and hydrogen blending ratio. In contrast, the emission concentrations of NOx, NO, and NO2 decrease with the increasing of equivalence ratio, but increase with hydrogen blending ratio rising. The emission concentration of N2O is highly sensitive to the O/H group and temperature, and it is precisely opposite to that of NO and NO2.

The NOx emissions during the crank-start and cold fast-idle phases of a GDI engine are analyzed in detail. The NOx emissions of the first 3 firing cycles are studied under a wide set of parameters including the mass of fuel injected, start of injection, and ignition timing. The results show a strong dependence of the NOx emissions with injection timing; they are significantly reduced as the mixture is stratified. The impact of different valve timings on crank-start NOx emissions was analyzed. Late intake and early exhaust timings show similar potential for NOx reduction; 26-30% lower than the baseline. The combined strategy, resulting in a large symmetric negative valve overlap, shows the greatest reduction; 59% lower than the baseline. The cold fast-idle NOx emissions were studied under different equivalence ratios, injection strategies, combustion phasing, and valve timings. Slightly lean air-fuel mixtures result in a significant reduction of NOx.