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A fuel control method to reduce the harmful exhaust gas from SI engines is proposed. As is well known, both the amplitude and the frequency of the limit cycle in a conventional air-fuel ratio control system are determined uniquely by parameters in the system. And this limits our making full use of the oxygen storage effect of TWC. A simple model of TWC reaction revealed the relationship between maximum conversion efficiency and both the amplitude and the frequency in a air fuel control system. It also revealed that TWC conversion efficiency attained to maximum levels when both the amplitude and the frequency of the limit cycle are selected so as to make full use of the oxygen storage effect of TWC. In order to achieve this, it is necessary to vary both the amplitude and the frequency arbitrarily.

Beta Ti alloy valve spring retainers are newly developed for use in mass produced automobiles for the first time. Ti alloy valve spring retainers vith a weight saving of 42%, compared to steel retainers, have reduced the inertial weight of the valve train components by 6%. And this weight reduction has the benefit of increasing the upper limit of the engine speed, which improves the engine performance. Ti alloy valve spring retainers are cold forged by the conventional fabrication facilities for steel retainers, using Ti-22V-4Al (the beta Ti alloy) which possesses excellent cold workability in a solution treated condition. Oxygen surface hardening is applied to protect Ti alloy valve spring retainers from wear damage. In addition, aging treatment and shot blasting are performed to improve strength and stiffness of valve retainers.

Austempered ductile iron (ADI) is a material having excellent mechanical properties and damping capacity. However practical mass production of ADI gears has not been possible due to ADI's poor machinability and distortion during the austempering heat treatment. With a new process method of carrying out hobbing before austempering when the material is in its soft condition, then austempering it and lastly, conducting the shave finishing process, we have diminished the above defects and developed practical ADI gears. These new gears generate less noise than ordinary nitrocarburized steel gears and are superior in pitting resistance.

GDI (Gasoline Direct Injection) engine adopting new combustion control technologies was developed and introduced into Japanese domestic market in August of 1996. In order to extend its application to the European market, various system modifications have been performed. Injectors are located with a smaller angle to the vertical line in order to improve the combustion stability in the higher speed range. A new combustion control method named “two-stage mixing” is adopted to suppress the knock in the low speed range. As a result of this new method, the compression ratio was increased up to 12.5 to 1 while increasing the low-end torque significantly. Taking the high sulfur gasoline in the European market into account, a selective reduction lean-NOx catalyst with improved NOx conversion efficiency was employed. A warm-up catalyst can not be used because the selective reduction lean NOx catalyst requires HC for the NOx reduction.

This paper describes a calculating method to predict the quasi-static collapsing behaviors of spot-welded closed-hat section curved beams under axial compression. The overall deformat ions and the local buckling modes of beams were calculated using a geometrical model. Force-displacement relations were predicted by a elastic-plastic structural analysis method using the ‘plastic hinge’ concept. Collapsing tests were made on beams which are differenting section size, rotation angle, and metal sheet thickness. Comparisons between the calculated and experimental results of deformed shapes of beams, the local buckling modes and the force displacement relations are discussed.

The authors developed, for use in diesel engines, ceramic tappets cast in aluminum alloy that drastically improved wear resistance and valve train dynamics. The ceramic tappets consist of two parts: a ceramic head, which contacts the cam and push rod, and a tappet body made of aluminum alloy. Concerning the ceramic, silicon nitride was the best material of the three ceramics evaluated in the tests and the sliding surface, in contact with the cam and push rod, was left unground. As for the aluminum alloy, hyper-eutectic aluminum-silicon alloy with a controlled pro-eutectic silicon size was selected. A reliability analysis using the finite-element method (FEM) was also made on the structure of the ceramic tappet for enhanced durability and reliability. The combination of this tappet and a cam made of hardened ductile cast iron, hardened steel, or chilled cast iron, respectively exhibits excellent wear resistance.

Vulcanized rubber hoses are difficult to recycle and have a complicated manufacturing process. Recently, we have developed the vacuum hose for engine control out of thermoplastic elastomers. As a result of this development, scrap material from the manufacturing process can be recycled and, in addition, about a 30 percent weight reduction and a 20 percent cost reduction are achievable by virtue of the lower specific gravity and by the more simplified manufacturing process. In order to assess the feasibility of using thermoplastic elastomers for vacuum hoses, we developed a heat aging simulation test method. This was achieved by first investigating the actual vehicle environmental conditions of currently used vacuum hoses by retrieving and examining these hoses from used vehicles. We then extrapolated what the condition of such hoses would be after being subjected to heat aging for 200,000 km of service in an actual vehicle, and applied this calculation to our newly developed hoses.

A two-stage combustion is one of the Mitsubishi GDI™ technologies for a quick catalyst warm-up on a cold-start. However, when the combustion is continued for a long time, an increase in the fuel consumption is a considerable problem. To solve the problem, a stratified slight-lean combustion is newly introduced for utilization of catalysis. The stratified mixture with slightly lean overall air-fuel ratio is prepared by the late stage injection during the compression stroke. By optimizing an interval between the injection and the spark timing, the combustion simultaneously supplies substantial CO and surplus O2 to a catalyst while avoiding the soot generation and the fouling of a spark plug. The CO oxidation on the catalyst is utilized to reduce the cold-start emissions. Immediately after the cold-start, the catalyst is preheated for the minimum time to start the CO oxidation by using the two-stage combustion. Following that, the stratified slight-lean combustion is performed.

An extensive effort has been made, at Mitsubishi Motors, in the technology field of new catalysts and of the catalyst reaction control for the purpose of further improvement of the emission control with the GDI engines [1-2]. A new NOx-trap catalyst has been developed to satisfy the required higher catalyst performance under high-temperature condition. The new catalyst contains potassium (K) of excellent NOx-storage capacity under high-temperature region in the catalytic atmosphere, and to retain K stability zeolite is mixed in the catalyst layer as well as the substrate is coated with silica (SiO2). This new catalyst has been proven of the improved NOx conversion efficiency, and solved the long-pending problems particularly those experienced under high-temperature operation.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

A new prototype oxygen storage componented oxygen sensor has been developed which shows significant emission reductions of a 3-way catalyst system. This sensor is composed of ceria, as an oxygen storage component and supported pellets as a buffer layer surrounding the protective coating of the sensor element. This sensor offers a more rapid response than conventional ones under lean and rich fuel mixture excursions, which is caused by CO or O2 electrode poisoning.

The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

Mitsubishi Motors Corporation uses spiral bevel gears in the transfer system for 4-wheel drive passenger cars modified from the front wheel drive configuration. This transfer gear ratio is near 1:1, and gears have uniform depth teeth cutting by the continuous generating method of OERLIKON cutting machine. In this method, the cutter and the work rotations are timed together to accomplish continuous indexing and cutting in order to enable high productivity. In general, it is difficult to reduce the meshing noise of spiral bevel gears and control its quality. The authors established the tooth surface coordinates, to reduce the meshing noise, by studying the influence of tooth surface coordinates on the meshing transmission error (MTE).

This paper presents several methods for reducing engine weight primarily through substitution with light-weight materials. The efficiency and performance of the engine were reviewed using a light-weight experimental engine (hereinafter called “weight-reduced engine”) constructed by the authors in order to investigate the possibility of practical use of the proposed weight reduction measures. The weight-reduced engine is based on an in-line 4-cylinder, 2.0 liter, gasoline engine with the base engine weight of 162 kg excluding engine oil and coolant and was reduced by 37 kg by applying alternative light-weight materiaLs and new manufacturing techniques. This corresponds to 23 % weight reduction. The materials used in the weight-reduced engine are 53 % steel, 33 % aluminum, 7 % plastics and 7 % other light-weight materials. It was found that by application of light-weight materials, the engine performance of the weight-reduced engine could be improved.

An investigation of anti-corrosion steel sheets (non-galvanized) which contain copper for automobile body parts has been conducted. Copper additives accelerate the formation of amorphous substrates. These substrates decrease the rate of corrosion. In order to retain the steel's formability and weldability, the contents of the alloying elements have been optimized. As a result, this newly developed steel sheet can be used for many different applications such as door sashes and door panels of mass produced cars. This paper describes the key properties of the newly developed steel sheet and additionally the mechanism of corrosion prevention, weldability, formability, and so on.

Diesel emission control is being addressed worldwide to help preserve the global environment. In 1994, emission controls in the U.S. called for reduction of diesel particulate matter (PM) to 10 to 20% of 1986's initial limit. In the same year, we developed and marketed small and medium duty trucks which were equipped with PM reduction systems that oxidize soluble organic fraction (SOF) contained in the PM, in order to satisfy these new regulations. Prior to their marketing, a catalyst was selected from among several types of candidate catalysts. Durability tests were performed using a catalytic converter-equipped small duty truck to verify the durability of the chosen catalyst. The durability test course was set up combining urban areas and expressways in the southern part of California, U.S.A.. The cumulative total distance covered on the test course reached 200,000 km. During the durability test, the catalyst was evaluated by measurement of PM emission using a chassis dynamometer.

Applying micro-alloyed steel as a cost-effective method of forging engine parts eliminates quench and temper processes and saves energy. We have expanded this application to timing gears and crankshafts by changing the connecting rod material to carbon steel and vanadium, applied at the outset. Then, micro-alloyed steel treated with a soft nitriding process was used. Our recent studies have been focused on materials which exhibit both higher tensile strength and better machinability. This paper describes the results of applying different types of micro-alloyed steel to those engine parts.

A particulate trap oxidizer system to reduce diesel particulate emissions has been developed. This system consists of a ceramic foam filter with an optimum volume, shape, and mesh number in terms of collection efficiency, pressure loss and particulate blow-off; a catalyst with a low activated-temperature for particulate incineration and with no sulfate formation during highway driving; and a regeneration system which prevents particulate overcollection during long-term continuous low-load/low-speed driving where it is difficult to achieve self-burning of particulates with a catalytic reaction. This paper describes the development of the particulate trap oxidizer system with these technologies and presents the results of practicability evaluations and 50,000-mile vehicle durability tests.

The adoption of the diesel engine EGR systems, and increased uses of alcohol in spark ignited engines require wear resistant and low maintenance valve trains. Silicon nitride ceramic inserts were pressureless-sintered and successfully die-cast in rocker arms contacting the overhead cams in the valve trains. As fired, the insert sliding surface was fine and precise, eliminating any further processing. The comosite structure was machined with the sliding surface as a reference plane. Beside inherent high wear resistance, these lighter inserts reduced inertial forces of the trains and the torque required to drive the cams. The hard, brittle ceramics and a softer, more elastic aluminum alloy made the structure more durable and reliable. The process of development includes characterization, screening, manufacturing and quality control of the materials, and determination of wear resistance and reliability for this new structure.

The accuracy of real-time A/F measurement at engine test benches has been improved with a modified equation to calculate A/F from exhaust gas composition. In addition to CO, CO2, total hydrocarbon (THC) and O2, the proposed equation includes NO and NO2 concentration as variables. In an attempt to improve the accuracy of the assumed constants in the equation, experiments have been conducted using automotive exhaust H2O and H2 analyzers. The accuracy of the proposed equation was proven through experiments and it was also found useful for precise evaluation of three-way catalyst or oxygen sensor characteristics.