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Technical Paper

Development of a Pilot Scale Apparatus for Control of Solid Waste Using Low Temperature Oxidation

2007-07-09
2007-01-3135
In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.
Technical Paper

On-Orbit and Ground Performance of the PGBA Plant Growth Facility

1997-07-01
972366
PGBA, a plant growth facility developed for commercial space biotechnology research, successfully grew a total of 50 plants (6 species) during 10 days aboard the Space Shuttle Endeavor (STS-77), and has reflown aboard the Space Shuttle Columbia (STS-83 for 4 days and STS-94 for 16 days) with 55 plants and 10 species. The PGBA life support system provides atmospheric, thermal, and humidity control as well as lighting and nutrient supply in a 33 liter microgravity plant growth chamber. The atmosphere treatment system removes ethylene and other hydrocarbons, actively controls CO2 replenishment, and provides passive O2 control. Temperature and humidity are actively controlled.
Technical Paper

Steady-State System Mass Balance for the BIO-Plex

1998-07-13
981747
A steady-state system mass balance calculation was performed to investigate design issues regarding the storage and/or processing of solid waste. In the initial stages of BIO-Plex, only a certain percentage of the food requirement will be satisfied through crop growth. Since some food will be supplied to the system, an equivalent amount of waste will accumulate somewhere in the system. It is a system design choice as to where the mass should accumulate in the system. Here we consider two approaches. One is to let solid waste accumulate in order to reduce the amount of material processing that is needed. The second is to process all of the solid waste to reduce solid waste storage and then either resupply oxygen or add physical/chemical (P/C) processors to recover oxygen from the excess carbon dioxide and water that is produced by the solid waste processor.
Technical Paper

Mass Transport in a Spaceflight Plant Growth Chamber

1998-07-13
981553
The Plant Generic BioProcessing Apparatus (PGBA), a plant growth facility developed for commercial space biotechnology research, has flown successfully on 3 spaceflight missions for 4, 10 and 16 days. The environmental control systems of this plant growth chamber (28 liter/0.075 m2) provide atmospheric, thermal, and humidity control, as well as lighting and nutrient supply. Typical performance profiles of water transpiration and dehumidification, carbon dioxide absorption (photosynthesis) and respiration rates in the PGBA unit (on orbit and ground) are presented. Data were collected on single and mixed crops. Design options and considerations for the different sub-systems are compared with those of similar hardware.
Technical Paper

Development Status of a Low-Power CO2 Removal and Compression System for Closed-Loop Air Revitalization

2008-06-29
2008-01-2095
The “low power-CO2 removal (LPCOR) system” is an advanced air revitalization system that is under development at NASA Ames Research Center. The LPCOR utilizes the fundamental design features of the ‘four bed molecular sieve’ (4BMS) CO2 removal technology of the International Space Station (ISS). LPCOR improves power efficiency by replacing the desiccant beds of the 4BMS with a membrane dryer and a state-of-the-art, structured adsorbent device that collectively require 25% of the thermal energy required by the 4BMS desiccant beds for regeneration. Compared to the 4BMS technology, it has the added functionality to deliver pure, compressed CO2 for oxygen recovery. The CO2 removal and recovery functions are performed in a two-stage adsorption compressor. CO2 is removed from the cabin air and partially compressed in the first stage. The second stage performs further compression and delivers the compressed CO2 to a reduction unit such as a Sabatier reactor for oxygen recovery.
Technical Paper

Evaluation of Commercial Off-the-Shelf Ammonia Sorbents and Carbon Monoxide Oxidation Catalysts

2008-06-29
2008-01-2097
Designers of future space vehicles envision simplifying the Atmosphere Revitalization (AR) system by combining the functions of trace contaminant (TC) control and carbon dioxide removal into one swing-bed system. Flow rates and bed sizes of the TC and CO2 systems have historically been very different. There is uncertainty about the ability of trace contaminant sorbents to adsorb adequately in a high-flow or short bed length configurations, and to desorb adequately during short vacuum exposures. This paper describes preliminary results of a comparative experimental investigation into adsorbents for trace contaminant control. Ammonia sorbents and low temperature catalysts for CO oxidation are the foci. The data will be useful to designers of AR systems for Constellation. Plans for extended and repeated vacuum exposure of ammonia sorbents are also presented.
Technical Paper

Lunar Base Life Support Failure Analysis and Simulation

2009-07-12
2009-01-2482
Dynamic simulation of the lunar outpost habitat life support was undertaken to investigate the impact of life support failures and to investigate possible responses. Some preparatory static analysis for the Lunar Outpost life support model, an earlier version of the model, and an investigation into the impact of Extravehicular Activity (EVA) were reported previously. (Jones, 2008-01-2184, 2008-01-2017) The earlier model was modified to include possible resupply delays, power failures, recycling system failures, and atmosphere and other material storage failures. Most failures impact the lunar outpost water balance and can be mitigated by reducing water usage. Food solids and nitrogen can be obtained only by resupply from Earth. The most time urgent failure is a loss of carbon dioxide removal capability. Life support failures might be survivable if effective operational solutions are provided in the system design.
Technical Paper

A Pilot Scale System for Low Temperature Solid Waste Oxidation and Recovery of Water

2009-07-12
2009-01-2365
In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work was to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. TDA and NASA Ames Research Center have developed a pilot scale low temperature ozone oxidation system to convert organic waste to CO2 and H2O.
Technical Paper

Development of Next-Generation Membrane-Integrated Adsorption Processor for CO2 Removal and Compression for Closed-Loop Air Revitalization and Analysis of Desiccating Membrane

2003-07-07
2003-01-2367
The current CO2 removal technology of NASA is very energy intensive and contains many non-optimized subsystems. This paper discusses the concept of a next-generation, membrane-integrated, adsorption processor for CO2 removal and compression in closed-loop air revitalization systems. The membrane module removes water from the feed, passing it directly into the processor's exhaust stream; it replaces the desiccant beds in the current four-bed molecular sieve system, which must be thermally regenerated. Moreover, in the new processor, CO2 is removed and compressed in a single two-stage unit. This processor will use much less power than NASA's current CO2 removal technology and will be capable of maintaining a lower CO2 concentration in the cabin than that can be achieved by the existing CO2 removal systems.
Technical Paper

Testing and Development of New Catalysts for Vapor Phase Ammonia Oxidation

2003-07-07
2003-01-2502
Catalytic oxidation is an effective means of controlling the build up of ammonia and other trace gas contaminants within closed spaces. However, it sometimes leads to the formation of noxious gases that need to be removed in post-treatment systems. In addition, ammonia removal is an issue when regeneration of water from wastewater is considered since ammonia is a byproduct of urea decomposition. For example, the VPCAR (Vapor Phase Catalytic Ammonia Reduction) advanced water processor system includes an oxidation reactor for the destruction of ammonia and of other volatile organics that are not separated out in the evaporator due to their volatility. The oxidation of ammonia may produce nitrogen, nitrogen oxides (NO and NO2), nitrous oxide (N2O) and water vapor. The Spacecraft Maximum Allowable Concentration (SMAC) for NO and NO2 are respectively 4.5 and 0.5 ppm whereas the Threshold Limit Value (TLV) for N2O is 25 ppm.
Technical Paper

Status of ISS Oxygen Generation and Water Processor Assemblies

2003-07-07
2003-01-2691
Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the international Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, hand wash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.
Technical Paper

Incineration of Inedible Biomass in a Regenerative Life Support System - Update of Development Activities at ARC

2001-07-09
2001-01-2344
Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. Various factors are involved in the design of an optimum fluidized bed incinerator for inedible biomass. The factors include variability of moisture in the biomass, the ash content, and the amount of fuel nitrogen in the biomass. The crop mixture in the waste will vary; consequently the nature of the waste, the nitrogen content, and the biomass heating values will vary as well. Variation in feed will result in variation in the amount of contaminants such as nitrogen oxides that are produced in the combustion part of the incinerator. The incinerator must be robust enough to handle this variability. Research at NASA Ames Research Center using the fluidized bed incinerator has yielded valuable data on system parameters and variables.
Technical Paper

Development Status and Maintainability Features of ISS Oxygen Generation and Water Processor Assemblies

2001-07-09
2001-01-2314
Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.
Technical Paper

Modeling Separate and Combined Atmospheres in BIO-Plex

2001-07-09
2001-01-2361
We modeled BIO-Plex designs with separate or combined atmospheres and then simulated controlling the atmosphere composition. The BIO-Plex is the Bioregenerative Planetary Life Support Systems Test Complex, a large regenerative life support test facility under development at NASA Johnson Space Center. Although plants grow better at above-normal carbon dioxide levels, humans can tolerate even higher carbon dioxide levels. Incinerator exhaust has very high levels of carbon dioxide. An elaborate BIO-Plex design would maintain different atmospheres in the crew and plant chambers and isolate the incinerator exhaust in the airlock. This design option easily controls the crew and plant carbon dioxide levels but it uses many gas processors, buffers, and controllers. If all the crew’s food is grown inside BIO-Plex, all the carbon dioxide required by the plants can be supplied by crew respiration and the incineration of plant and food waste.
Technical Paper

Development, Testing, and Packaging of a Redundant Regenerable Carbon Dioxide Removal System (RRCRS)

2002-07-15
2002-01-2530
Enhancements to the Regenerable Carbon Dioxide Removal System (RCRS) have undergone full-scale, pre-prototype development and testing to demonstrate a redundant system within the volume allotted for the RCRS on the Space Shuttle Orbiter. The concept for a Redundant Regenerable Carbon Dioxide Removal System (RRCRS) utilizes the existing canister of the RCRS, but partitions it into two, independent, two-bed systems. This partitioning allows for two, fully capable RCRS units to be packaged within the original volume, thus reducing stowage volume and launch weight when compared to the flight RCRS plus the backup LiOH system. This paper presents the results of development and testing of a full-scale, pre-prototype RRCRS and includes an overview of the design concept for a redundant system that can be packaged within the existing envelope.
Technical Paper

Crop Models for Varying Environmental Conditions

2002-07-15
2002-01-2520
New variable environment Modified Energy Cascade (MEC) crop models were developed for all the Advanced Life Support (ALS) candidate crops and implemented in SIMULINK. The MEC models are based on the Volk, Bugbee, and Wheeler Energy Cascade (EC) model and are derived from more recent Top-Level Energy Cascade (TLEC) models. The MEC models were developed to simulate crop plant responses to day-to-day changes in photosynthetic photon flux, photoperiod, carbon dioxide level, temperature, and relative humidity. The original EC model allowed only changes in light energy and used a less accurate linear approximation. For constant nominal environmental conditions, the simulation outputs of the new MEC models are very similar to those of earlier EC models that use parameters produced by the TLEC models. There are a few differences. The new MEC models allow setting the time for seed emergence, have more realistic exponential canopy growth, and have corrected harvest dates for potato and tomato.
Technical Paper

Sabatier CO2 Reduction System Design Status

2002-07-15
2002-01-2531
Carbon dioxide reduction in a closed loop life support system recovers water from otherwise waste carbon dioxide and hydrogen. Incorporation of a carbon dioxide reduction assembly (CRA) into the International Space Station life support system frees up thousands of pounds of payload capacity in the supporting Space Shuttle that would otherwise be required to transport water. Achievement of this water recovery goal requires coordination of the CRA design to work within the existing framework of the interface systems that are either already on orbit or well advanced in their development; namely, the Oxygen Generator Assembly (OGA), Carbon Dioxide Removal Assembly (CDRA) and Water Processor Assembly (WPA). The Oxygen Generation System (OGS) rack is in its final design phase and is scarred to accept later installation of the CRA.
Technical Paper

Catalyst Development for the Space Station Water Processor Assembly

2002-07-15
2002-01-2362
Hamilton Sundstrand Space Systems International (HSSSI) is currently under contract with NASA MSFC to design, fabricate and deliver the Water Processor Assembly (WPA) for the International Space Station (ISS). As part of this effort HSSSI has developed an oxidation catalyst for the catalytic reactor assembly in the WPA. This paper discusses full-scale development reactor testing and the status of the life testing of the oxidation catalyst used in the reactor.
Technical Paper

Development Status of ISS Water Processor Assembly

2002-07-15
2002-01-2363
Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene wastewaters. All planned development testing has been completed and this paper provides the status of the development activities and results for the WPA.
Technical Paper

An Improved Pyrolyzer for Solid Waste Resource Recovery in Space

2002-07-15
2002-01-2402
Pyrolysis processing is one of several options for solid waste resource recovery in space. It has the advantage of being relatively simple and adaptable to a wide variety of feedstocks and it can produce several usable products from typical waste streams. The overall objective of this study was to produce a prototype mixed solid waste pyrolyzer for spacecraft applications. A two-stage reactor system was developed which can process a maximum of about 0.5 kg of waste per cycle. The reactor includes a pyrolysis chamber where the waste is heated to temperatures above 600 °C for primary pyrolysis. The volatile products (liquids, gases) are transported by a N2 purge gas to a second chamber which contains a catalyst bed for cracking the tars at temperatures of about 1000-1100 °C. The tars are cracked into carbon and additional gases. Most of the deposited carbon is subsequently gasified by oxygenated volatiles (CO2, H2O) from the first stage.
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