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A fuel control method to reduce the harmful exhaust gas from SI engines is proposed. As is well known, both the amplitude and the frequency of the limit cycle in a conventional air-fuel ratio control system are determined uniquely by parameters in the system. And this limits our making full use of the oxygen storage effect of TWC. A simple model of TWC reaction revealed the relationship between maximum conversion efficiency and both the amplitude and the frequency in a air fuel control system. It also revealed that TWC conversion efficiency attained to maximum levels when both the amplitude and the frequency of the limit cycle are selected so as to make full use of the oxygen storage effect of TWC. In order to achieve this, it is necessary to vary both the amplitude and the frequency arbitrarily.

A flexible fuel vehicle (FFV) was evaluated through various tests for its potential as an alternative to the conventional gasoline vehicle. This paper presents the systems incorporated in the FFV and the test results. 50,000 mile emission durability tests were also performed and the potential of the FFV as a “Low Emission Vehicle” was assessed. As the result of extensive engineering work, we successfully developed a Galant FFV which exhibits very good durability and reliability. The emission control system which we have developed demonstrated that the vehicle has a good potential to comply with the California formaldehyde emission standard of 15 mg/mile. However, due to the large portion of unburnt methanol in the tail-pipe emissions, FFVs will have more difficulty than gasoline vehicles in meeting non-methane organic gas (NMOG) standards applicable to “Low Emission Vehicles”.

GDI (Gasoline Direct Injection) engine adopting new combustion control technologies was developed and introduced into Japanese domestic market in August of 1996. In order to extend its application to the European market, various system modifications have been performed. Injectors are located with a smaller angle to the vertical line in order to improve the combustion stability in the higher speed range. A new combustion control method named “two-stage mixing” is adopted to suppress the knock in the low speed range. As a result of this new method, the compression ratio was increased up to 12.5 to 1 while increasing the low-end torque significantly. Taking the high sulfur gasoline in the European market into account, a selective reduction lean-NOx catalyst with improved NOx conversion efficiency was employed. A warm-up catalyst can not be used because the selective reduction lean NOx catalyst requires HC for the NOx reduction.

Protection of the Earth's environment by means of energy saving and cleaning up of air pollution on a global scale is one of the most important subjects in the world today. Because of this, the requirements for better fuel economy and cleaner exhaust emissions of internal combustion engines have been getting stronger, and, in particular, simultaneous reduction in nitrogen oxides (NOx) and particulate matter (PM) from heavy-duty diesel engines (HDDEs) without degrading fuel economy has become a major subject. Mitsubishi Motors Corporation (MM) has been selling diesel-powered heavy-duty trucks in the U.S. market since 1985 and has agressively carried out development work for meeting the 1991 model year exhaust emission standards.

A newly developed small-sized IES (inductive energy storage) circuit with a semiconductor switch at turn-off action was successfully applied to an ignition system. This IES circuit can generate repetitive nanosecond pulse discharges. An ignition system using repetitive nanosecond pulse discharges was investigated as an alternative to conventional spark ignition systems in the previous papers. Experiments were conducted using constant volume chamber for CH₄ and C₃H₈-air mixtures. The ignition system using repetitive nanosecond pulse discharges was found to improve the inflammability of lean combustible mixtures, such as extended flammability limits, shorted ignition delay time, with increasing the number of pulses for CH₄ and C₃H₈-air mixtures under various conditions. The mechanisms for improving the inflammability were discussed and the effectiveness of IES circuit under EGR condition was also verified.

A two-stage combustion is one of the Mitsubishi GDI™ technologies for a quick catalyst warm-up on a cold-start. However, when the combustion is continued for a long time, an increase in the fuel consumption is a considerable problem. To solve the problem, a stratified slight-lean combustion is newly introduced for utilization of catalysis. The stratified mixture with slightly lean overall air-fuel ratio is prepared by the late stage injection during the compression stroke. By optimizing an interval between the injection and the spark timing, the combustion simultaneously supplies substantial CO and surplus O2 to a catalyst while avoiding the soot generation and the fouling of a spark plug. The CO oxidation on the catalyst is utilized to reduce the cold-start emissions. Immediately after the cold-start, the catalyst is preheated for the minimum time to start the CO oxidation by using the two-stage combustion. Following that, the stratified slight-lean combustion is performed.

An extensive effort has been made, at Mitsubishi Motors, in the technology field of new catalysts and of the catalyst reaction control for the purpose of further improvement of the emission control with the GDI engines [1-2]. A new NOx-trap catalyst has been developed to satisfy the required higher catalyst performance under high-temperature condition. The new catalyst contains potassium (K) of excellent NOx-storage capacity under high-temperature region in the catalytic atmosphere, and to retain K stability zeolite is mixed in the catalyst layer as well as the substrate is coated with silica (SiO2). This new catalyst has been proven of the improved NOx conversion efficiency, and solved the long-pending problems particularly those experienced under high-temperature operation.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

Ammonia Selective Catalytic Reduction (SCR) is adapted for a variety of applications to control nitrogen oxides (NOx) in diesel engine exhaust. The most commonly used catalyst for SCR in established markets is Cu-Zeolite (CuZ) due to excellent NOx conversion and thermal durability. However, most applications in emerging markets and certain applications in established markets utilize vanadia SCR. The operating temperature is typically maintained below 550°C to avoid vanadium sublimation due to active regeneration of the diesel particulate filter (DPF), or some OEMs may eliminate the DPF because they can achieve particulate matter (PM) standard with engine tuning. Further improvement of vanadia SCR durability and NOx conversion at low exhaust gas temperatures will be required in consideration of future emission standards.

Ammonia Selective Catalytic Reduction (SCR) is a key emission control component utilized in diesel engine applications for NOx reduction. There are several types of SCR catalyst currently in the market: Cu-Zeolite, Fe-Zeolite and Vanadia. Diesel vehicle and engine manufacturers down select their production SCR catalyst primarily based on vehicle exhaust gas temperature operation, ammonia dosing strategy, fuel quality, packaging envelope and cost. For Vanadia SCR, the operating temperature is normally controlled below 550oC to avoid vanadium sublimation. In emerging markets, the Vanadia SCR is typically installed alone or downstream of the DOC with low exhaust gas temperature exposure. Vanadia SCR is also utilized in some European applications with passive DPF soot regeneration. However, further improvement of Vanadia SCR NOx conversion at low exhaust gas temperatures will be required to meet future emission regulations (i.e.: HDD Phase 2 GHG).

The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.

A new prototype oxygen storage componented oxygen sensor has been developed which shows significant emission reductions of a 3-way catalyst system. This sensor is composed of ceria, as an oxygen storage component and supported pellets as a buffer layer surrounding the protective coating of the sensor element. This sensor offers a more rapid response than conventional ones under lean and rich fuel mixture excursions, which is caused by CO or O2 electrode poisoning.

The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

In order to reduce exhaust emission and combustion noise and to improve fuel consumption, the effects of the combustion system parameters of a diesel engine, such as injection pressure, injection nozzle hole diameter, swirl ratio, and EGR rate on exhaust emissions, combustion noise and fuel consumption are investigated and described in detail by analyzing rate of heat release, needle valve lift and injection pressure. Based on these results, reduction of exhaust emission and combustion noise and improvement of fuel consumption are described in the latter part of this paper. These results are shown as follows. The smaller nozzle hole diameter is effective for reducing smoke and PM, and by optimizing the injection timing and swirl ratio, NOx can also be reduced. In addition to the above, by applying EGR and higher injection pressure it is possible to improve the fuel consumption with the remaining low NOx and PM.

Diesel emission control is being addressed worldwide to help preserve the global environment. In 1994, emission controls in the U.S. called for reduction of diesel particulate matter (PM) to 10 to 20% of 1986's initial limit. In the same year, we developed and marketed small and medium duty trucks which were equipped with PM reduction systems that oxidize soluble organic fraction (SOF) contained in the PM, in order to satisfy these new regulations. Prior to their marketing, a catalyst was selected from among several types of candidate catalysts. Durability tests were performed using a catalytic converter-equipped small duty truck to verify the durability of the chosen catalyst. The durability test course was set up combining urban areas and expressways in the southern part of California, U.S.A.. The cumulative total distance covered on the test course reached 200,000 km. During the durability test, the catalyst was evaluated by measurement of PM emission using a chassis dynamometer.

In this study three EGR methods were applied to a 12 liter turbocharged and intercooled Dl diesel engine, and the exhaust emission and fuel consumption characteristics were compared. One method is the Low Pressure Route system, in which the EGR is taken from down stream of the turbine to the compressor entrance. The other two systems are variations of the High Pressure Route system, in which the EGR is taken from the exhaust manifold to the intake manifold. One of the two High Pressure Route EGR systems is with back pressure valve located at downstream of the turbine and the other uses a variable geometry(VG) turbocharger. It was found that the High Pressure Route EGR system using VG turbocharger was the most effective and practical. With this method the EGR area could be enlarged and NOx reduced by 22% without increase in smoke or fuel consumption while maintaining an adequate excess air ratio.

A new combustion system - called MCA-JET- has been developed to improve combustion under the low speed, low load conditions typical of urban driving. Engines with this new system incorporate a special “jet valve”, in addition to the inlet and exhaust valves of the conventional combustion chamber, which directs air or a super-lean mixture towards the spark plug, and induces a strong swirling flow in the cylinder. This swirl persists during the compression and expansion processes, moves the mixture spirally and helps the flame to propagate. As a result, the combustion of lean mixtures, including those with exhaust gas recirculation, can be carried out rapidly and thus the fuel economy improved.

Three Japanese automobile manufacturers-Mitsubishi Motors Corp., Nissan Motor Co., Ltd., and Toyo Kogyo Co., Ltd.-have been making efforts over the past three years to design and develop effective thermal reactor-exhaust gas recirculation and catalytic converter systems suitable for small engines. The work is being done by members participating in the IIEC (Inter-Industry Emission Control) Program, and the exhaust emission levels of the concept vehicles developed by these companies have met the goal established by the IIEC Program at low mileage. Each system, however, has a characteristic relationship between exhaust emission level and loss of fuel economy. Much investigation is required, particularly with respect to durability, before any system that will fully satisfy all service requirements can be completed. This paper reports the progress of research and development of the individual concept vehicles.

The effect of the use of the EGR system on the lubrication of a passenger car diesel engine was investigated. The higher the EGR rate, the more soot in the oil. And the most detrimental effect was found in valve train wear. Some engine tests, including motoring tests, were carried out to investigate the contribution of soot to valve train wear. The mechanism of cam and rocker arm wear in used oils was studied by analyzing for elements on the lubricated metal surface and subsequently the mechanism was more thoroughly studied using the four-ball test. Soot seems to act as an abrasive on the anti-wear solid film formed by the oil on the metal surface and this film contains Ca, O, P and S. Some hardware modifications and oil formulations to reduce valve train wear are also discussed.

This paper describes the design and operation of the multi-layered zirconia heated exhaust gas oxygen sensor having small-sized and sheet-shaped sensing element. This sensor uses an electrode modified with a rhodium catalyst and heater by means of the thick-film technique. This modification of an electrode's composition and construction affects the reaction on unburned components in exhaust gas as well as the sensor performance. By the addition of a rhodium catalyst, the zirconia exhaust gas oxygen sensor shows acute sensitivity and faster response properties in the transient state on emission component(NOx) generation, in such a way that these sensors show better emission control properties for reduction of NOx emission in current emission control systems. The addition of a rhodium catalyst reduces the green effect of sensor properties, and no significant change of emission control properties is observed after 50,000 equivalent miles using the engine dynamometer durability test.