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In this work, a quasi-dimensional, multi-zone combustion model is analytically presented, for the prediction of performance and nitric oxide (NO) emissions of a homogeneous charge spark ignition (SI) engine, fueled with biogas-H2 blends of variable composition. The combustion model is incorporated into a closed cycle simulation code, which is also fully described. Combustion is modeled on the basis of turbulent entrainment theory and flame stretch concepts. In this context, the entrainment speed, by which unburned gas enters the flame region, is simulated by the turbulent burning velocity of a flamelet model. A flame stretch submodel is also included, in order to assess the flame response on the combined effects of curvature, turbulent strain and nonunity Lewis number mixture. As far as the burned gas is concerned, this is treated using a multi-zone thermodynamic formulation, to account for the spatial distribution of temperature and NO concentration inside the burned volume.

This study investigates the impact of mid-high biodiesel blends on the criteria and PAH emissions from a modern pick-up diesel vehicle. The vehicle was a Euro 4 (category N1, subclass III) compliant common-rail light-duty goods pick-up truck fitted with a diesel oxidation catalyst. Emission and fuel consumption measurements were performed on a chassis dynamometer equipped with CVS, following the European regulations. All measurements were conducted over the certification New European Driving Cycle (NEDC) and the real traffic-based Artemis driving cycles. Aiming to evaluate the fuel impact on emissions, a soy-based biodiesel, a palm-based biodiesel, and an oxidized biodiesel obtained from used frying oils were blended with a typical automotive ultra-low-sulfur diesel at proportions of 30, 50 and 80% by volume. The experimental results revealed that CO₂ emissions and fuel consumption exhibited an increase with biodiesel over all driving conditions.

In this study, regulated, unregulated exhaust emissions and fuel consumption with ultra low sulphur diesel and soy-based biodiesel blends at proportions of 10 and 30% v/v have been investigated. A Euro 4 compliant SUV, equipped with a 2.2 litre common-rail diesel engine and an oxidation catalyst was tested on a chassis dynamometer with constant volume sampling (CVS) technique. Emission and fuel consumption measurements were performed over the New European Driving Cycle (NEDC) and the non-legislated Artemis driving cycles which simulate urban, rural, and highway driving conditions in Europe. The regulated pollutants were characterized by determined NOx, PM, CO, and HC. CO2 was also quantified in the exhaust. Overall, 16 PAHs, 4 nitro-PAHs, 6 oxy-PAHs, 13 carbonyl compounds and particulate alkanes ranged from C13 to C35 were determined in the exhaust.

In the frame of circular economy, wastes are perceived as sources not only for the recovery of high added-value compounds but also for energy production. Coffee is one of the most popular beverages with the consumption continuously increasing and generating huge amounts of solid residues in return. This solid waste after the extraction of the coffee beverage is known as Waste or Spent Coffee Grounds (WCG). Among others, the valorization has the potential to be directed as a bioresource for sustainable energy and particularly for the production of alternative liquid fuels for internal combustion engines. The aim of the current study is to formulate alternative fuel from WCG and to examine the fundamental properties per relevant specifications and requirements. Parameters related to stability, cold flow properties, lubricating characteristics and ignition quality are studied in comparison with other types of biodiesel fuel.

Many incidents associated with filter plugging have extensively been reported in microbially contaminated diesel and biodiesel fuel systems, especially under long term storage conditions. In this study a quantitative assessment of the undesirable insoluble solids produced in contaminated biodiesel fuels was carried out in order to evaluate their evolution rate during biodeterioration. For this purpose, a series of contaminated biodiesel fuel microcosms were prepared and stored for six months under stable conditions. The quantity of the particulate contaminants was monitored during storage by a multiple filtration technique which was followed at the end by a comparison with the active bioburden per ATP bioluminescence protocol. Additionally, identical microcosms were treated with a commercially available biocide in order to examine the latter’s activity both on solids formation and the microbial proliferation.

During recent years, the deterioration of greenhouse phenomenon, in conjunction with the continuous increase of worldwide fleet of vehicles and crude oil prices, raised heightened concerns over both the improvement of vehicle mileage and the reduction of pollutant emissions. Diesel engines have the highest fuel economy and thus, highest CO2 reduction potential among all other thermal propulsion engines due to their superior thermal efficiency. However, particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines are comparatively higher than those emitted from modern gasoline engines. Therefore, reduction of diesel emitted pollutants and especially, PM and NOx without increase of specific fuel consumption or let alone improvement of diesel fuel economy is a difficult problem, which requires immediate and drastic actions to be taken.

This study examines the impact of ETBE and ethanol addition on the main properties of motor gasoline. European Union mandates the use of biofuels in all transport fuels, according to the 2003/30/EC Directive. The addition of ethanol, a known octane enhancing component, in small proportions significantly increases the vapor pressure of the final gasoline, exceeding the maximum specification limits. ETBE (ethyl tert-butyl ether) is on the other hand an excellent but expensive octane enhancing component with beneficial impact on vapor pressure of the final gasoline. This paper examines the ability of ETBE to act as a stabilizer in gasoline - ethanol blends. Two gasoline samples with different chemical compositions and characteristics were prepared by blending basic refinery components. In each sample, ETBE was added in concentrations of 2, 4, and 6 % V/V respectively. In each of these ETBE - gasoline blends, ethanol was added in concentrations from 1 to 6 % V/V in 1% steps.

The scope of this work is to examine the use of hydroprossed used cooking oils as substitute for automotive diesel fuel. Hydroprocessing is an alternative method for the transformation of vegetable oils into high quality transport fuels, even if the quality of the oils is low, such as used cooking oils. In the present work, the utilization of hydroprocessed used cooking oil (HUCO) as neat fuel was proved to be very difficult, due to its very poor cold flow properties; therefore, mixtures of the HUCO with low quality middle distillates (a low cetane number gasoil and a light cycle oil) were prepared and evaluated. Throughout the process the formed blends were evaluated according to the european standard EN 590. The following points were mainly recorded: The lower density of HUCO was beneficial, permitting the use of poor quality distillates, in specific concentrations, and the high cetane number of HUCO was appreciable, improving the worse behavior of the other components.

The need of a more realistic and dynamic driving cycle which simulates real-world driving conditions in the largest city in the greater area of Balkans, led to the development of the Athens Driving Cycle (ADC). Emission and fuel consumption measurements were conducted over the ADC and compared with those of the New European Driving Cycle (NEDC) using a chassis dynamometer. A Euro II compliant diesel vehicle was used in this study, fuelled with a typical automotive diesel fuel and biodiesel blends at proportions of 5, 10, and 20 % respectively. The unregulated emissions were characterized by determining the soluble organic fraction (SOF) in the particulate matter, together with qualitative hydrocarbon analysis present in the SOF fraction, and of carbonyl compounds (aldehydes, ketones). Emissions of NOx, CO, THC, CO2, and PM10 were also measured over the two test cycles.

This paper describes some of the recent work carried out in our laboratory regarding the effects of novel oxygen and nitrogen containing compounds on the antiknock quality of unleaded gasoline and their effects on some other gasoline properties. In particular, the research included Research Octane Number (RON) measurements and the evaluation of the effects of the most effective antiknock compounds on Dry Vapour Pressure Equivalent (DVPE), distillation temperatures, aromatic content, olefins, and oxygen content. Emphasis was given in studying chemical structures that can be derived from renewable raw materials. The compounds tested included substituted phenols, furan derivatives, aliphatic amines, various amide structures and Mannich base phenols. Methyl t-butyl ether (MTBE), the most widespread oxygenate currently used in gasoline, was used as a yardstick for assessing the quality of the compounds tested.

Despite the improvement in HD Diesel engine out emissions future emission legislation requires significant reduction of both NOx and particulate matter. To accomplish this task various solutions exist involving both internal and external measures. As widely recognized, it will be possibly required to employ both types of measures to meet future emission limits. Towards this direction, it is necessary to reduce NOx further using internal measures. Several solutions exist in that area, but the most feasible ones according to the present status of technical knowledge are EGR, water injection or fuel/water emulsions. These technologies aim to the reduction of both the gas temperature and oxygen concentration inside the combustion chamber that strongly affect NOx formation. However, there remain open points mainly concerning the effectiveness of water addition techniques and penalties related to bsfc and soot emissions.

In this study, the transesterification process of 4 different vegetable oils (sunflower, rapeseed, olive oil and used frying oil) took place utilizing ethanol, in order to characterize the ethyl esters and their blends with diesel fuel obtained as fuels for internal combustion engines. All ethyl esters were synthesized using calcium ethoxide as a heterogeneous solid base catalyst. The ester preparation involved a two-step transesterification reaction, followed by purification. The effects of the mass ratio of catalyst to oil, the molar ratio of ethanol to oil, and the reaction temperature were studied on conversion of sunflower oil to optimize the reaction conditions in both stages. The rest of the vegetable oils were converted to ethyl esters under optimum reaction parameters. The optimal conditions for first stage transesterification were an ethanol/oil molar ratio of 12:1, catalyst amount (3.5%), and 80 °C temperature, whereas the maximum yield of ethyl esters reached 80.5%.

The introduction to the European market of higher levels of biodiesel blends focuses the research interest on the compatibility problems of the diesel fuel distribution system. The influence of metals in the oxidation stability and lubricity of two different types of commercially available FAMEs (without antioxidant additive) was investigated. Zinc (Zn), Copper (Cu) and Tin (Sn), were added in the form of solid metals (heterogeneous catalysis in liquid phase oxidation) and examined for their impact on the oxidation stability of biodiesel fuel. Oxidation stability was determined by Rancimat accelerated oxidation method, according to European Standard EN14214. Additionally, in order to examine the effect of the above mentioned metals in the presence of antioxidant additive, BHT was added in both biodiesel samples and oxidation stability determinations were carried out, as well.

This study examines the effects of neat soy-based biodiesel (B100) and its 50% v/v blend (B50) with low sulphur automotive diesel on vehicle PAH emissions. The measurements were conducted on a chassis dynamometer with constant volume sampling (CVS) according to the European regulated technique. The vehicle was a Euro 2 compliant diesel passenger car, equipped with a 1.9 litre common-rail turbocharged direct injection engine and an oxidation catalyst. Emissions of PAHs, nitro-PAHs and oxy-PAHs were measured over the urban phase (UDC) and the extra-urban phase (EUDC) of the type approval cycle (NEDC). In addition, for evaluating realistic driving performance the non-legislated Artemis driving cycles (Urban, Road and Motorway) were used. Overall, 12 PAHs, 4 nitro-PAHs, and 6 oxy-PAHs were determined. The results indicated that PAH emissions exhibited a reduction with biodiesel during all driving modes.

To reduce the fuel related logistic burden, NATO Armed Forces are advancing the use of a single fuel for both aircraft and ground equipment. To this end, F-34 is replacing distillate diesel fuel in many applications. Yet, unacceptable wear due to poor lubricity was illustrated by tests conducted with kerosene on High Frequency Reciprocating Rig. Therefore, HFRR tests were performed with fatty acid methyl esters of sunflower, palm, cotton-seed, tobacco-seed, olive, rape-seed and used frying oils, at volume concentrations from 0.05% to 0.6%. This study showed that the biodiesels used, produced a significant decrease in the wear scar diameter at concentrations of 0.2% to 0.4 %. Biodiesels derived from non-polyunsaturated oils, such as palm and olive gave better lubrication at certain concentrations.

Homogeneous Charge Compression Ignition (HCCI) engines have the potential of reducing NOx emissions as compared to conventional Diesel or SI engines. Soot emissions are also very low due to the premixed nature of combustion. However, the unburned hydrocarbon emissions are relatively high and the same holds for CO emissions. The formation of these pollutants, for a given fuel, is strongly affected by the temperature distribution as well as by the charge motion within the engine cylinder. The foregoing physical mechanisms determine the local ignition timing and burning rate of the charge affecting engine efficiency, performance and stability. Obviously the success of any model describing HCCI combustion depends on its ability to describe adequately both the chemistry of combustion and the physical phenomena, i.e. heat and mass transfer within the cylinder charge. In the present study a multi-zone model is developed to describe the heat and mass transfer mechanism within the cylinder.

The direct injection diesel engine is one of the most efficient thermal engines known to man. For this reason DI diesel engines are widely used for heavy-duty applications and especially for the propulsion of trucks. Even though the efficiency of these engines is currently at a high level there still exist possibilities for further improvement. One way to accomplish this is by increasing the injection timing which usually improves, depending on the operating conditions, the indicated efficiency of the engine. On the other hand advanced injection timing has a negative effect on peak pressure causing a serious increase of its value, a negative effect on NO emissions which are also seriously increased and a positive effect on Soot emissions which are reduced. In the present work a theoretical and experimental investigation is presented to determine the effect of more advanced injection timing on engine performance and pollutant emissions.

Pollutant emissions and specifically NO and soot are one of the most important problems that engineers have to face when developing heavy duty DI diesel engines. Two main strategies exist as options for their control, reduction inside the engine cylinder using advanced combustion and fuel injection technologies and use of after-treatment systems. In the present work it is examined the use of EGR to control the formation of NO inside the cylinder of an engine with extremely high peak pressure. The work is applied on a single cylinder truck test engine developed under a project funded by the European Community focusing on the improvement of heavy duty DI diesel engine efficiency using increased injection timing. Use is made of a simulation model to predict the effect of more advanced injection timing on engine performance and emissions. The model has been modified to include the effect of EGR used to c ontrol the formation of NO which is considerably increased at high injection timings.

The current work uses a method developed by the authors for both combustion irreversibility and working medium availability computations in a high speed, naturally aspirated, four stroke, internal combustion engine cylinder. The objective of the study was to extrapolate already published results of the second-law analysis of diesel engine operation by studying parametrically the effect of main operating parameters such as engine speed of rotation, injection timing, and fuel composition. Extensive experimental data were available for the case of dodecane injection, which were used for the determination of the fuel reaction rate. Computationally, the same reaction rates were used for methane and methanol injection. The production rate of irreversibility during combustion was analytically calculated as a function of the fuel reaction rate with the combined use of first and second-law arguments and a chemical equilibrium hypothesis.

A comprehensive set of computational and experimental results for high- pressure diesel sprays are presented and discussed. The test cases investigated include injection of diesel into air under both atmospheric and high pressure/temperature chamber conditions, injection against pressurized and cross-flowing CF6 simulating respectively the density and flow conditions of a diesel engine at the time of injection, as well as injection into the piston bowl of both research and production turbocharged high-speed DI diesel engines. A variety of high-pressure injection systems and injector nozzles have been used including mechanical and electronic high-pressure pumps as well as common-rail systems connected to nozzles incorporating a varying number of holes with diameters ranging from conventional to micro-size.