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Repeatabilities of PM measurements on a heavy-duty diesel engine equipped with a diesel particulate filter (DPF) using a filter weighing method and a number counting method with a full flow dilution system and a partial flow system were evaluated. The filter method with partial flow exhibited the best repeatability. However, a good correlation between the full flow and the partial flow number counting results suggests that the fluctuations observed using the number counting method were caused by changes in the engine exhaust. Applying a strict preconditioning procedure should improve the repeatability of the number counting method because this method is more sensitive than the filter weighing method. In addition, the effects of the specifications for the number counting method were evaluated. The results indicate that the hose length from the tip of the sampling probe to the inlet of the number counting system had a negligible effect.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

The formation pathway for poly aromatic hydrocarbons (PAHs) has been studied by not only fundamental chemists but also motor engineers due to the formation of nanoparticle precursors and soot in vehicle emissions. In this study, the formation process of up to triple-ring PAHs was investigated using a flow tube reactor. The gaseous products from the pyrolysis of benzene were analyzed by using GC-MS in the temperature range of 850 - 1277 K and pressure range of 50 - 760 mmHg. We found that PAH products formed at temperatures greater than 1050 K, and the formation process was pressure dependent.

The regulation of particulate matter (PM) from diesel engines is coming to be very stringent at present. The usage of diesel particulate filter (DPF) is now under consideration in many heavy-duty diesel vehicle manufacturers to reduce PM emission from a diesel engine. The possibility that very fine particles may pass through DPF is suggested. The understanding of fine particles emission behaviors and the countermeasure of reducing particle emissions from DPF will come to be important in near future. The behavior of particle size distribution after DPF has not been studied enough yet. In this study, fine particles generated by a diesel engine are introduced to honeycomb type and SiC (Silicon Carbite) fiber type DPFs and the collection performances of fine particles by various DPFs with different surface structures have been examined.

Recently, particulate matter (PM) emission from internal combustion engines, especially particles having the diameter of less than 100 nm (Nano-particles) are being considered for their potential hazards posed to human health and the environment. Nano-particles are unstable and easily influenced by the conditions of engine operation and measurement techniques. In this study, the influences of cooling and dilution processes on nano- particles are presented to understand the generation and dilution mechanisms, and to further development of an accurate measurement method. It is found that the thermo-dilurter is necessary for measuring the nano-particles with higher accuracy. Accurate measurement of nano-particles requires immediate dilution of the exhaust gases by hot air.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions from diesel engine. In general, high octane number and volatility fuels (gasoline components or gaseous fuels) are used for HCCI operation, because very lean mixture must be formed during ignition delay of the fuel. However, it is necessary to improve fuel injection systems, when these fuels are used in diesel engine. The purpose of the present study is the achievement of HCCI combustion in DI diesel engine without the large-scale improvements of engine components. Various high octane number fuels are mixed with diesel fuel as a base fuel, and the mixed fuels are directly applied to DI diesel engine. At first, the cylinder pressure and heat release rate of each mixed fuel are analyzed. The ignition delay of HCCI operation decreases with an increase in the operation load, although that of conventional diesel operation does not almost varied.

Particulate Matter (PM) from diesel engines is thought to be seriously hazardous for human health. Generally, it is said that the hazard depends on the total number and surface area of particles rather than total mass of PM. In the conventional gravimetric method, only the total mass of PM is measured. Therefore, it is very important to measure not only the mass of PM but also size and number density of particulates. Laser-Induced Incandescence (LII) is a useful diagnostic for transient measurement of soot particulate volume fraction and primary particle size. On the other hand, Scanning Mobility Particle Sizer (SMPS) is also used to measure the size distribution of soot aggregate particulates at a steady state condition. However, the measurement processes and the phenomena used to acquire the information on soot particulate are quite different between the LII and SMPS methods. Therefore, it is necessary to understand the detailed characteristics of both LII and SMPS.

The authors have developed a new partial flow dilution tunnel (hereafter referred to as PPFT), whose principal device is a flux splitting gas divider, as a new means of measuring particulate emissions which can be applied to transient cycle testing of diesel engines. The advantage of this system is that it can achieve perfect constant velocity splitting by means of its structure, and theoretically can also maintain high splitting performance despite fluctuations in the exhaust flow rate, including those due to engine exhaust pulsation. We compared this system with a full tunnel by analyzing the basic performance of the system and measuring particulate matter (PM) using an actual vehicle engine.

The full-flow dilution tunnel (hereinafter referred to as full tunnel) measurement method has become the de facto standard for the evaluation of particulate matter (hereinafter referred to as PM) emitted from diesel-powered vehicles. However, due to its drawbacks such as bulkiness and expensiveness, a method that uses a very small partial dilution tunnel (hereinafter referred to as micro tunnel) has been developed, mainly in Europe, nearly to the level of practicality. With this method, a higher degree of freedom in controlling sampling flow and temperature can be obtained. Another advantage of the micro tunnel is that the system is compact. However, the micro tunnel's measurement accuracy remains uncertain because the accumulation of measurement data is not yet sufficient. Measuring PM while varying micro tunnel operating parameters permitted a check on the equivalency with a full tunnel system.

Particulate matter (PM) and polynuclear aromatic hydrocarbons (PAH) were measured under steady state engine operating conditions in the exhaust of a DI diesel engine that meets the Japanese 1994 heavy-duty vehicle standards. In this study, to examine and discuss the effects of pyrene and sulfur contents in fuels on PM and PAH emissions, experiments were performed using both ordinary diesel fuel and a specified fuel having simple hydrocarbon components and very few aromatics. In the experiments, pyrene and sulfur contents in the fuels were changed by the addition of reagents to the fuel. The following conclusions were obtained. (1) From the experiments using ordinary JIS No. 2 diesel fuel with a pyrene reagent added to yield 400ppm pyrene, it was found that pyrene addition brings about an increase in soluble organic fraction (SOF) under low load engine operating conditions.

Fuel composition is investigated as a parameter influencing fuel/air mixing of direct injected fuel and the subsequent consequences for particulate emissions. Presumably, enhanced mixing prior to ignition results in a larger portion of fuel burning as a premixture and a smaller portion of diffusion burning around fuel-rich regions. This would potentially lower particulate emissions without overly compromising hydrocarbon emissions or high load operation. Using mixtures of n-paraffin fuels, particulate emissions were measured and the results were compared with in-cylinder visualization of the injection process and two-color method calculations of flame temperature. In general, lower boiling point fuels exhibited higher flame temperatures, less visible flame, and lower particulate emissions.

Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

A new PM measurement method, such as particle measurement equipments, samplings and so on, is being studied at present for a type approval test in the future. Particles emitted from diesel engines, especially the particles that are called “Nuclei Mode Particles” are very unstable and easily influenced by the engine operating conditions and the measurement conditions. Most of nuclei mode particles are said to consist of volatile organic particles with mainly high carbon numbers. It is said that a continuous regenerative type DPF (Diesel Particulate Filter) consisting of oxidation catalyst and ceramic filter will prevail in the near future. These particles may be able to be reduced by an oxidation catalyst in this DPF.

The prototype solid particle counting system (SPCS) has been used to study solid particle emission from gasoline and diesel vehicles. As recommended by the PMP draft proposal, exhaust is diluted by a Constant Volume Sampler (CVS). The SPCS takes the sample from the CVS tunnel. Transient test cycles such as EPA FTP 75, EPA HWFET (EPA Highway Fuel Economy Cycle), and NEDC (New European Driving Cycle) were tested. The repeatability of the instrument was evaluated on the diesel vehicle for three continuous days. The instrument exhibits good repeatability. The differences for the EPA ftp 75, the EPA HWFET, and the NEDC in three continuous tests are ± 3.5%. The instrument is very sensitive as well and detects the driving differences. A large number of solid particles are found during the hard acceleration from both the gasoline and the diesel vehicles. Solid particle emissions decrease quickly at deceleration and when vehicles approach constant speed.