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In 2006, Nissan began limited leasing of the X-TRAIL FCV equipped with their in-house developed Fuel Cell (FC) stack. Since then, the FC stack has been improved in cost, size, durability and cold start-up capability with the aim of promoting full-scale commercialization of FCVs. However, reduction of cost and size has remained a significant challenge because limited mass transport through the membrane electrode assembly (MEA) has made it difficult to increase the rated current density of the FC. Furthermore, it has been difficult to reduce the variety of FC stack components due to the complex stack configuration. In this study, improvements have been achieved mainly by adopting an advanced MEA to overcome these difficulties. First, the adoption of a new MEA and separators has improved mass transport through the MEA for increased rated current density. Second, an integrated molded frame (IMF) has been adopted as the MEA support.

To improve the fuel economy via high EGR, combustion stability is enhanced through the addition of hydrogen, with its high flame-speed in air-fuel mixture. So, in order to realize on-board hydrogen production we developed a fuel reformer which produces hydrogen rich gas. One of the main issues of the reformer engine is the effects of reformate gas components on combustion performance. To clarify the effect of reformate gas contents on combustion stability, chemical kinetic simulations and single-cylinder engine test, in which hydrogen, CO, methane and simulated gas were added to intake air, were executed. And it is confirmed that hydrogen additive rate is dominant on high EGR combustion. The other issue to realize the fuel reformer was the catalyst deterioration. Catalyst reforming and exposure test were carried out to understand the influence of actual exhaust gas on the catalyst performance.

The demands on valve seat insert materials, in terms of providing greater wear-resistance at higher temperatures, enhanced machinability and using non-environmentally hazardous materials at a reasonably low cost have intensified in recent years. Due therefore to these strong demands in the market, research was made into the possibility of producing a new valve seat insert material. As a result a high speed steel based new improved material was developed, which satisfies the necessary required demands and the evaluation trials, using actual gasoline engine endurance tests, were found to be very successful.

This paper describes the new inline 4-cylinder QR engine series that is available in 2.0-liter and 2.5-liter versions. The next-generation QR engine series incorporates new and improved technologies to provide an optimum balance of power, quietness and fuel economy. Its quiet operation results from the adoption of a compact balancer system and the reduced weight of major moving parts. Power and fuel economy have been enhanced by a two-stage cooling system, a continuous variable valve timing control system, a dual close coupled catalyst system, electronic throttle control and an improved direct-injection system. The latter includes an improved combustion chamber concept and improved fuel spray characteristics achieved by driving the injector by battery voltage. A lightweight and compact engine design has been achieved by adopting a high-pressure die cast aluminum cylinder block, resin intake manifold and rocker cover and a serpentine belt drive.

Generally, cobalt-contained sintered materials have mainly been applied for exhaust valve seat inserts (VSI). However, there is a trend to restrict the use of cobalt as well as lead environmental law, and cobalt is expensive. To solve these problems, a new exhaust VSI on the assumption of being cobalt and lead free, applicable for conventional engines, having good machinability, and with a reduced cost was developed. The new exhaust VSI is a material dispersed with two types of hard particles, Fe-Cr-C and Fe-Mo-Si, in the matrix of an Fe-3.5mass%Mo at the ratio of 15 mass % and 10 mass % respectively.

This paper describes a newly developed steel composition and surface modification methods for improving the rolling contact fatigue strength of parts used in transmission systems, especially continuously variable transmissions (CVTs) to increase their torque capacity. The mechanisms of two types of typical rolling contact fatigue phenomenon in case hardening steel were examined with the aim of improving rolling contact fatigue strength. One concerned white etching constituents (WEC) and the other one concerned peculiar microstructural changes caused by hydrogen originating from decomposition of the lubrication oil as a result of repeated rolling contact stress cycles. The rolling contact fatigue strength limit due to WEC has been improved markedly by dispersing fine M23C6 alloy carbides in the martensite matrix at the subsurface layer of parts.

A transient knock prediction technique has been developed by coupling a zero-dimensional knocking simulation with chemical kinetics and a one-dimensional gas exchange engine model to study the occurrence of transient knock in SI engines. A mixed chemical reaction mechanism of the primary reference fuels was implemented in the two-zone combustion chamber model as the auto-ignition model of the end-gas. An empirical correlation between end-gas auto-ignition and knock intensity obtained through intensive analysis of experimental data has been applied to the knocking simulation with the aim of obtaining better prediction accuracy. The results of calculations made under various engine operating parameters show good agreement with experimental data for trace knock sensitivity to spark advance.

It was found that pitting resistance of gears is strongly influenced by resistance to temper softening of carburized steel. The investigation about the influence of chemical compositions on hardness after tempering revealed that silicon, chromium and molybdenum are effective elements to improve resistance to temper softening and pitting resistance. Considering the production of gears, molybdenum is unfavorable because it increases hardness of normalized or annealed condition. Developed new steel contains about 0.5 mass% of silicon and 2.7 mass% chromium. The new steel has excellent pitting resistance and wear resistance. Fatigue and impact strength are equivalent to conventional carburized steels. Cold-formability and machinability of the new steel are adequate for manufacturing gears because of its ordinary hardness before carburizing. The new steel has already been put to practical use in automatic transmission gears. Application test results are also reported.

An engine cycle simulation code with detailed chemical kinetics has been developed to study Homogeneous Charge Compression Ignition (HCCI) combustion with hydrogen as the fuel. In order to attain adequate combustion duration, resulting from the self-accelerating nature of the chemical reaction, fuel and temperature inhomogeneities have been brought to the calculation by considering the combustion chamber to have various temperature and fuel distributions. Calculations have been done under various conditions including both perfectly homogeneous and inhomogeneous cases, changing the degree of inhomogeneity. The results show that intake gas temperature is more dominant on ignition timing of HCCI than equivalence ratio and that there is a possibility to control HCCI by introducing appropriate temperature inhomogeneity to in-cylinder mixture.

Improving the impact strength of the differential gears is one way to reduce the size and weight of the final drive unit. Previously, we developed high-strength steel for gear use by adding molybdenum and reducing impurities such as phosphorus and sulfur. However, additional improvement of impact strength is required these days due to higher engine torque and demands for further weight reductions. Toward that end, we focused on boron, which has been used as an element for improving hardenability, and analyzed what effect its addition would have on impact strength. Useful knowledge was obtained for improving impact strength through enhancement of grain boundary toughness. Various steels were then produced experimentally and used in gear strength tests. The results made it possible to improve impact strength while reducing the content of other alloys, resulting in the development of a chromium-molybdenum-boron case hardening steel with superior cold forgeabilty.

High strength transmission gears have been developed for use in the final gear set of front-wheel-drive vehicles. The steel used as the gear material has a higher molybdenum content, allowing more austenite to be retained following carburizing than is possible with chromium steel. As a result, the steel can be subjected to higher intensity shot peening by using harder peening particles which are projected by an air-nozzle peening system. With this procedure, the fatigue strength of the gears can be increased 1.6 times over that of conventional gears.

The purpose of this work was to gain a fundamental understanding of which fuel property parameters are responsible for particulate emission characteristics, associated with key intermediate behavior in the engine cylinder such as the fuel film and insufficient mixing. Accordingly, engine tests were carried out using various fuels having different volatility and chemical compositions under different coolant temperature conditions. In addition, a fundamental spray and film visualization analysis was also conducted using a constant volume vessel, assuming the engine test conditions. As for the physical effects, the test results showed that a low volatility fuel displayed high particulate number (PN) emissions when the injection timing was advanced. The fundamental test clearly showed that the amount of fuel film on the impingement plate increased under such operating conditions with a low volatility fuel.

Use of high strength steel (HSS) could be an important consideration in achieving competitive weight and safety performance of the body-in-white (BIW). This study covers key technical issues in the application development. Many aspects were studied such as formability, weldability and impact strength for application of this grade to the BIW. One of the key issues is spot weldability, especially in the assembly of heavy gauge materials for structural parts. The spot weld strength appears not to satisfy the target for some HSS applications, when hardness of the nugget is high. The relation between weld strength and the chemical composition of steel sheets was studied, because hardness can be controlled by chemical composition and welding conditions. It was found that using lower carbon content or carbon equivalent compared to conventional grades could improve weld strength.

The application of both high strength gear steels and shot peening technology has succeeded in strengthening automotive transmission gears. This technology, though, improves mainly the fatigue strength at the tooth root, but not the pitting property at the tooth face. Therefore, demand has moved to the development of new gear steels with good pitting resistance. In order to improve pitting resistance, the authors studied super carburizing which is characterized by carbide dispersion in the case, especially processed with a plasma carburizing furnace. Firstly, the influence of the carburizing temperature and carburizing period on the carbide morphology was investigated and the optimum carburizing conditions were determined. Secondly, the fatigue strength and pitting resistance was evaluated using carbide dispersed specimens.

This paper presents a new-generation, lightweight, 3-liter V6 engine that has been developed for use in the next Nissan Maxima. The distinctive features of this new engine, VQ30DE, is its compact, lightweight design and excellent fuel economy. The basic construction of the engine is characterized by its 60-degree V6 configuration, chain-driven DOHC and high-pressure die cast aluminum cylinder block. A two-way cooling system was adopted with the aim of shortening the warm-up time of the cylinder liners. The new engine has been designed to comply with the tougher emission standards, the OBD-II requirements and California's new evaporative emission standard.

The key-points in the diffusion bonding technique of green compacts during sintering, are the material compositions, which should be chosen according to their dimensional change during sintering, and the fitting clearance, which should be maintained in the range of press fit. Applying this technique, we have developed sinter-diffusion bonded idler sprockets for automotive engines by comfirming the bonding strength and torsional fatigue strength. And we also have developed a nondestructive analysis method for assuring the joint strength of idler sprockets in the mass production.

A new high-performance and lightweight TiA1 intermetallic compound exhaust valve has been developed. The TiA1 valve can improve power output and fuel economy by contributing higher engine speeds and a reduction in valvetrain friction. It was achieved by developing a Ti-33.5A1-0.5Si-1Nb-0.5Cr (mass%) intermetallic compound, a precision casting method for TiA1 that provides a low-cost, high-quality process, and a plasma carburizing technique for assuring good wear resistance on the valve stem end, stem and face.

JIS SCM440M (SAE4140H), heat treated to the strength level of 120 to 140 kgf/mm2(171 to 199 ksi) -ISO 12.9 class-, is currently used for cylinder head bolts of Japanese passenger cars. Lower alloy steels, such as SAE 1541 for example, have not been substituted for JIS SCM440H so far because of their high susceptibility to delayed fracture. Daido Steel has tackled this problem and succeeded in applying the lower alloy SAE 1541 steel to 12.9 class cylinder head bolts by enhancing the resistance to delayed fracture by reducing impurities, especially sulphur. In this paper mechanical properties and delayed fracture characteristics of SAE 1541-ULS (Ultra Low Sulphur) steel are reported. 1541-ULS (S<0.005%, S+P< 0.020%) shows outstanding resistance to delayed fracture compared to conventional steel. Furthermore, the amount of MnS inclusions decreases remarkably in ULS steel, which results in high toughness.

The exhaust system is often one of the main sources of vehicle noise. A new type of exhaust silencer made of porous sintered aluminum and installed at the end of the exhaust tube considerably reduces this noise, with no rise in back pressure. The mechanism of noise abatement is analyzed utilizing fluid dynamic analysis techniques. It is concluded that noise reduction results mainly from the fluid dynamic effects arising from the gas permeability of the material. Among these effects are the boundary layer control effect of the inner flow, flattening of the velocity profile, heat dispersion effect, decrease in turbulence of flow, smoothing of exhaust pulsation, contraction of the mixing region, and the resulting large decrease in the volume of the noise source. In regard to acoustical effect, the sintered metal can be thought of as Helmholtz resonators. The change in the end condition as an acoustic tube also reduces the peak level of acoustic resonance.

Cold forging has been applied to form a component of the constant velocity joint. This part, slide joint housing, is made of JIS S48C (SAE 1048) high carbon steel. As it has been very difficult to form this part by cold forging, it has been formed by hot forging up until now. Success was obtained in forming this part by cold forging through improving the chemical composition of S48C high carbon steel and tool design, determining the optimum condition for heat treating the slug, and using a TiC coated punch. Since this slide joint housing, which is nearly net shape, was able to be formed through this cold forging technique, material saving was improved about 40% and machining time was reduced much in comparison with hot forging. Manufacturing cost can be greatly reduced through this cold forging which has been developed.