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An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

This study concerns a dissimilar materials joining technique for aluminum (Al) alloys and steel for the purpose of reducing the vehicle body weight. The tough oxide layer on the Al alloy surface and the ability to control the Fe-Al intermetallic compound (IMC) thickness are issues that have so far complicated the joining of Al alloys and steel. Removing the oxide layer has required a high heat input, resulting in the formation of a thick Fe-Al IMC layer at the joint interface, making it impossible to obtain satisfactory joint strength. To avoid that problem, we propose a unique joining concept that removes the oxide layer at low temperature by using the eutectic reaction between Al in the Al alloy and zinc (Zn) in the coating on galvanized steel (GI) and galvannealed steel (GA). This makes it possible to form a thin, uniform Fe-Al IMC layer at the joint interface. Welded joints of dissimilar materials require anticorrosion performance against electrochemical corrosion.

The ways in which vehicles are used in the field are continually becoming more diverse. In order to provide the optimum solution with respect to performance and weight, it is necessary to be able to assure vehicle endurance reliability with a high degree of accuracy in relation to the manner of use in each market. This situation has increased the importance of accurately quantifying the ways in which vehicles are used in the field and of designing vehicles with sufficient endurance reliability to match the usage requirements. This report presents a “market model” by which the manner of usage in the field can be treated quantitatively using combinations of environmental factors that influence the road load, drive load and corrosion load, representing typical loads vehicles must withstand.

The demands on valve seat insert materials, in terms of providing greater wear-resistance at higher temperatures, enhanced machinability and using non-environmentally hazardous materials at a reasonably low cost have intensified in recent years. Due therefore to these strong demands in the market, research was made into the possibility of producing a new valve seat insert material. As a result a high speed steel based new improved material was developed, which satisfies the necessary required demands and the evaluation trials, using actual gasoline engine endurance tests, were found to be very successful.

The life of automotive transmission gears today is often governed by pitting fatigue life. Being able to predict pitting fatigue life accurately is a crucial issue. Pitting fatigue life is substantially influenced by surface hardness and tooth surface geometry. For that reason, this study examined a new method of predicting pitting fatigue life that takes into account changes in these factors over time. This method makes it possible to predict the pitting fatigue life of automotive transmission gears under a wide range of evaluation conditions with markedly better accuracy than conventional methods used previously.

This paper describes the new inline 4-cylinder QR engine series that is available in 2.0-liter and 2.5-liter versions. The next-generation QR engine series incorporates new and improved technologies to provide an optimum balance of power, quietness and fuel economy. Its quiet operation results from the adoption of a compact balancer system and the reduced weight of major moving parts. Power and fuel economy have been enhanced by a two-stage cooling system, a continuous variable valve timing control system, a dual close coupled catalyst system, electronic throttle control and an improved direct-injection system. The latter includes an improved combustion chamber concept and improved fuel spray characteristics achieved by driving the injector by battery voltage. A lightweight and compact engine design has been achieved by adopting a high-pressure die cast aluminum cylinder block, resin intake manifold and rocker cover and a serpentine belt drive.

Generally, cobalt-contained sintered materials have mainly been applied for exhaust valve seat inserts (VSI). However, there is a trend to restrict the use of cobalt as well as lead environmental law, and cobalt is expensive. To solve these problems, a new exhaust VSI on the assumption of being cobalt and lead free, applicable for conventional engines, having good machinability, and with a reduced cost was developed. The new exhaust VSI is a material dispersed with two types of hard particles, Fe-Cr-C and Fe-Mo-Si, in the matrix of an Fe-3.5mass%Mo at the ratio of 15 mass % and 10 mass % respectively.

This paper describes a newly developed steel composition and surface modification methods for improving the rolling contact fatigue strength of parts used in transmission systems, especially continuously variable transmissions (CVTs) to increase their torque capacity. The mechanisms of two types of typical rolling contact fatigue phenomenon in case hardening steel were examined with the aim of improving rolling contact fatigue strength. One concerned white etching constituents (WEC) and the other one concerned peculiar microstructural changes caused by hydrogen originating from decomposition of the lubrication oil as a result of repeated rolling contact stress cycles. The rolling contact fatigue strength limit due to WEC has been improved markedly by dispersing fine M23C6 alloy carbides in the martensite matrix at the subsurface layer of parts.

The existing vehicle designs exhibit a high level of coupling. For instance the coupling in the suspension and steering systems manifests itself through the change in wheel alignment parameters (WAP) due to suspension travel. This change in the WAP causes directional instability and tire-wear. The approach of the industry to solve this problem has been twofold. The first approach has been optimization of suspension link lengths to reduce the change in WAP to zero. Since this is not possible with the existing architecture, the solution used is the optimization of the spring stiffness K to get a compromise solution for comfort (which requires significant suspension travel and hence a soft spring) and directional stability (which demands least possible change in wheel alignment parameters and hence a stiff spring).

It was found that pitting resistance of gears is strongly influenced by resistance to temper softening of carburized steel. The investigation about the influence of chemical compositions on hardness after tempering revealed that silicon, chromium and molybdenum are effective elements to improve resistance to temper softening and pitting resistance. Considering the production of gears, molybdenum is unfavorable because it increases hardness of normalized or annealed condition. Developed new steel contains about 0.5 mass% of silicon and 2.7 mass% chromium. The new steel has excellent pitting resistance and wear resistance. Fatigue and impact strength are equivalent to conventional carburized steels. Cold-formability and machinability of the new steel are adequate for manufacturing gears because of its ordinary hardness before carburizing. The new steel has already been put to practical use in automatic transmission gears. Application test results are also reported.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

Improving the impact strength of the differential gears is one way to reduce the size and weight of the final drive unit. Previously, we developed high-strength steel for gear use by adding molybdenum and reducing impurities such as phosphorus and sulfur. However, additional improvement of impact strength is required these days due to higher engine torque and demands for further weight reductions. Toward that end, we focused on boron, which has been used as an element for improving hardenability, and analyzed what effect its addition would have on impact strength. Useful knowledge was obtained for improving impact strength through enhancement of grain boundary toughness. Various steels were then produced experimentally and used in gear strength tests. The results made it possible to improve impact strength while reducing the content of other alloys, resulting in the development of a chromium-molybdenum-boron case hardening steel with superior cold forgeabilty.

Semi-solid metal (SSM) casting has long been identified as a high-volume process for producing safety-critical and structural automotive castings, but cost and complexity issues have limited its widespread commercial acceptance. Rheocasting, an SSM process that creates semi-solid slurry directly from liquid metal, eliminates the cost disadvantages of the process. However, the majority of rheocasting processes are complex and difficult to operate in the foundry environment. Recent work at MIT has led to the fundamental discovery that application of heat removal and convection as a molten alloy cools through the liquidus creates a non-dendritic, semi-solid slurry. A new process based on this understanding, S.S.R.™ (Semi-Solid Rheocasting), simplifies the rheocasting process by controlling heat removal and convection of an alloy during cooling using an external device. Solution heat treatable castings have been produced in a horizontal die casting machine with the S.S.R.™ process.

High strength transmission gears have been developed for use in the final gear set of front-wheel-drive vehicles. The steel used as the gear material has a higher molybdenum content, allowing more austenite to be retained following carburizing than is possible with chromium steel. As a result, the steel can be subjected to higher intensity shot peening by using harder peening particles which are projected by an air-nozzle peening system. With this procedure, the fatigue strength of the gears can be increased 1.6 times over that of conventional gears.

The effects of lubricant oil and fuel properties on low speed pre-ignition (LSPI) occurrence in boosted S.I. engines were experimentally evaluated with multi-cylinder engine and de-correlated oil and fuel matrices. Further, the auto-ignitability of fuel spray droplets and evaporated homogeneous fuel/oil mixtures were evaluated in a combustion bomb and pressure differential scanning calorimetry (PDSC) tests to analyze the fundamental ignition process. The work investigated the effect of engine conditions, fuel volatility and various lubricant additives on LSPI occurrence. The results support the validity of aspects of the LSPI mechanism hypothesis based on the phenomenon of droplets of lubricant oil/fuel mixture (caused by adhesion of fuel spray on the liner wall) flying into the chamber and autoigniting before spark ignition.

The quest for higher efficiency and performance of automotive vehicles requires application of materials with high strength, stiffness and lower weight in their construction. Particulate-reinforced aluminum-matrix composites are cost-competitive materials, which can meet these requirements. MMCC, Inc. has been optimizing particulate-reinforced alloy systems and developing the Advanced Pressure Infiltration Casting (APIC™) process for the manufacture of components from these materials. This paper discusses the results of a recent study in which composites reinforced with 55 vol.% alumina were cast using two sizes of alumina particulate and eight different matrix alloys based on Al-4.5 wt.% Cu with varying amounts of silicon and magnesium. Optimum heat treatments for each alloy were determined utilizing microhardness studies. The tensile strength and fracture toughness were evaluated as a function of alloy chemistry, particulate size, and heat treatment.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

The application of both high strength gear steels and shot peening technology has succeeded in strengthening automotive transmission gears. This technology, though, improves mainly the fatigue strength at the tooth root, but not the pitting property at the tooth face. Therefore, demand has moved to the development of new gear steels with good pitting resistance. In order to improve pitting resistance, the authors studied super carburizing which is characterized by carbide dispersion in the case, especially processed with a plasma carburizing furnace. Firstly, the influence of the carburizing temperature and carburizing period on the carbide morphology was investigated and the optimum carburizing conditions were determined. Secondly, the fatigue strength and pitting resistance was evaluated using carbide dispersed specimens.

This paper presents a new-generation, lightweight, 3-liter V6 engine that has been developed for use in the next Nissan Maxima. The distinctive features of this new engine, VQ30DE, is its compact, lightweight design and excellent fuel economy. The basic construction of the engine is characterized by its 60-degree V6 configuration, chain-driven DOHC and high-pressure die cast aluminum cylinder block. A two-way cooling system was adopted with the aim of shortening the warm-up time of the cylinder liners. The new engine has been designed to comply with the tougher emission standards, the OBD-II requirements and California's new evaporative emission standard.

The oxidation chemistry of paraffins, aromatics, olefins and MTBE were examined. Detailed chemical kinetics calculations were carried out for oxidation of these compounds in the engine cycle. The oxidation rates are very sensitive to temperature. At temperatures of over 1400 K (depending on the fuel), all the hydrocarbons are essentially oxidized for typical residence time in the engine. Based on the kinetics calculations, a threshold temperature is defined for the conversion of the fuel species to CO, CO2, H2O and partially oxidized products. The difference in the survival fraction between aromatics and non-aromatics is attributed to the higher threshold temperature of the aromatics.