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Technical Paper

Effects of Sulfate Adsorption on Performance of Diesel Oxidation Catalysts

1992-02-01
920852
Several types of oxidation catalyst material are tested in repeated particulate emission measurements over the US HDD transient test procedure. Particulates are effectively reduced in the initial stage of the measurements. However, particulates tend to increase when repeating the measurements. This is believed to be caused by sulfate adsorption on the catalyst surfaces. Hence, oxidation catalysts are tested after stabilizing surface adsorption. Test results show that an oxidation catalyst which forms more sulfates is not effective in reducing particulates because the sulfate increase offsets the SOF reduction effect. An effective catalyst for particulate reduction is developed by suppressing sulfate formation.
Technical Paper

Study of SiC Application to Diesel Particulate Filter (Part 1): Material Development

1993-03-01
930360
We studied the use of SiC porous material for diesel particulate filters. Crystallities of SiC grow into hexagonal plates during sintering,but their sizes have not been controllable yet. We developed a production process that makes the average pore diameter as desired in limiting the pore size distribution to a narrow range. Diesel particulate filters made of SiC greatly reduce pressure loss even when a large quantity of particulates accumulates as compared with conventional wall-flow type filter of cordierite of the same size. This enables particulate filter to be made smaller. The good thermal conductivity of SiC allows fast regeneration without a temperature spike, but its large coefficient of thermal expansion causes heat cracks during rig tests and engine bench tests. The rig tests showed that the heat cracking problem can be solved if the length and diameter are below a certain threshold for each.
Technical Paper

Study of SiC Application to Diesel Particulate Filter (Part 2): Engine Test Results

1993-03-01
930361
The characteristics of a new diesel particulate filter material made of SiC were studied through engine tests in varying material properties, such as average pore diameter, and wall thickness. Compared to a conventional cordierite filter of the same size, particulate trapping efficiency is almost the same, and the pressure loss and the deterioration of fuel consumption can be reduced to about half with the optimum material properties. If the same pressure loss is allowed, the filter size can be reduced by 30%. Its good thermal conductivity prevents local temperature increases, which doubles the permissible amount of trapped particulates. As heat crack problems occurred in integral-type filters due to the high thermal expansion of SiC, a split-type filter having 49 filter segments with a square section was developed.
Technical Paper

Development of a Heavy-Duty Turbocharged and Aftercooled CNG-Fueled Lean-Burn Engine - Conversion of a Naturally-Aspirated Diesel Engine into Otto-Type CNG Engine

1993-10-01
932818
A heavy-duty, naturally aspirated diesel engine was converted into a turbocharged, aftercooled, compressed natural gas engine. Engine test results show that excess air ratio and ignition timing strongly affect NOx and THC emissions. Leaning the air-fuel mixture reduces NOx emission, but it increases THC emission and combustion becomes unstable above a certain excess air ratio. Retarding the ignition timing reduces both the NOx and THC emissions. Dual-plug ignition improves brake thermal efficiency. The NOx emission level can be reduced to meet the Japanese long-term emission regulation limit for heavy-duty gasoline engines with a sufficient safety margin by appropriately selecting the air-fuel ratio and ignition timing so as to keep the THC emission level below the regulation limit without using any after-treatment. The engine full torque characteristics were almost the same as the base engine throughout the engine speed range, while the maximum exhaust gas temperature was lower.
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