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Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

The effects of Hydrotreated vegetable oil (HVO) on combustion and emission characteristics in a diesel engine were investigated by using spray analyzer, engine dynamometer and vehicle tests. Spray analysis showed that spray characteristics was virtually the same for HVO and diesel. From the results of the engine dynamometer and the vehicle tests, it was found that the high cetane number and the zero aromatics of HVO could reduce in HC and PM emissions. Moreover, as a result of optimized engine calcification, HVO is capable of improving partial fuel consumption and full-load torque. These results indicate that HVO has beneficial fuel characteristics for diesel engine.

The impact of fatty acid methyl ester (FAME) blended diesel fuel on engine/vehicle systems was comprehensively investigated by vehicle, laboratory and engine tests. In this study, 20% FAME blended fuel (B20) was mainly used and soy bean oil methyl ester (SME) was primarily selected as the FAME. Vehicle testing with long-term fuel storage in vehicle fuel tanks was conducted, considering the most severe conditions in market use. Laboratory and engine tests were also conducted to better understand the vehicle test results. In the vehicle test, engine startability, idle roughness and fuel injection control were evaluated using nine vehicles with plastic or metal fuel tanks. All vehicles showed no problems up to 7 months. While five vehicles with plastic fuel tank did not show any problems throughout the test period up to 18 months, four vehicles with metal fuel tanks experienced malfunctions in engine start or fuel injection control following 8, 13, 13 and 18 months respectively.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

The stability of Diesel/Biodiesel blends can play an important role in deposits formation inside the fuel injection system (FIS). The impact of the stability of FAME/Diesel fuel blends on lacquer deposits formation and on the behavior and reliability of the FIS was investigated using blends of Rapeseed and Soybean methyl esters (RME, SME) and conventional Diesel fuel (volume fractions of RME and SME range from 0 to 20%v/v). Fuels were aged under accelerated conditions and tested on an injection test rig according to an operating cycle developed to provoke injector needle blocking. The soaking duration was found to affect injector fouling. A relationship between the injector fouling tendency and the fuel stability was established. Under current test condition, injectors fouling increased with fuel oxidation measured with Total-Acid-Number.

In order to investigate the effect of sulfur and distillation properties on exhaust emissions, emission tests were carried out using a California Low Emission Vehicle (LEV) in accordance with the 1975 Federal Test Procedure ('75 FTP). To study the fuel effect on the exhaust emissions from different systems, these test results were compared with the results obtained from our previous studies using a 92MY vehicle for California Tier 1 standards and a 94MY vehicle for California TLEV standards. (1)(2) First, the sulfur effect on three regulated exhaust emissions (HC, CO and NOx) was studied. As fuel sulfur was changed from 30 to 300 ppm, the exhaust emissions from the LEV increased about 20% in NMHC, 17% in CO and 46% in NOx. To investigate the recovery of the sulfur effect, the test fuel was changed to 30 ppm sulfur after the 300 ppm sulfur tests. The emission level did not recover to that of the initial 30 ppm sulfur during three repeats of the FTP.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

A study of diesel fuel as a lubricant for diesel engines was conducted with the aim of dramatically reducing engine friction and eliminating the need to change the lubricating oil. A prototype single-cylinder engine modified for diesel fuel lubrication was made, and it was confirmed that firing operation is possible. Piston friction during the firing operation was reduced by modifying the shape of the cylinder liner surface to improve the retention of the lubricating oil. The study produced valid findings concerning engine lubrication, not only with diesel fuel, but also with ultra-low viscosity oil.

A new method for measuring unregulated substances in the exhaust gas is being investigated to clarify the influence of the vehicles' exhaust emissions into the environment. This paper explains our work on developing an analysis method for detecting and quantifying trace substances in the exhaust gas. A new analysis method was examined that uses thermal desorption to analyze trace amounts of polycyclic aromatic hydrocarbons (PAHs) in vehicle exhaust gas. This technique is faster than conventional methods and does not require any preconditioning of the samples before analysis. While lead and chloromethane were detected in the exhaust gas samples, it was made clear that these substances did not originate in the engine system. Accordingly, the results of this study indicate that careful attention must be paid to the test environment and the presence of measurement interfering substances in exhaust samples when measuring trace constituents in the exhaust gas from low-emission vehicles.

The original Toyota Hybrid System (THS) was installed in the Prius and was introduced in 1997 as the world's first mass-produced hybrid passenger car. Since then, THS has been continuously improved. In 2003 THS-II (marketed as Hybrid Synergy Drive [HSD]), was installed in a new larger Prius. In 2006 HSD was installed in a Rear Wheel Drive Vehicle: the LEXUS GS450h. This system achieved both 4.5-liter class power performance and compact class fuel economy with outstanding emissions performance. In 2007, this system is expanded to a mechanical all-wheel-drive(AWD) in the LEXUS LS600hL(with new V8 engine). This paper will explain this hybrid system which achieved both V12 class power performance and mid-size class fuel economy, while meeting the most stringent emission standard SULEV as a full-size vehicle.

In order to clarify the diesel fuel spray characteristics inside the cylinder, we developed two novel techniques, which are preparation of same level of temperature and pressure ambient as inside cylinder and quantitative measurement of vapor concentration. The first one utilizes combustion-type constant-volume chamber (inner volume 110cc), which allows 5 MPa and 873K by igniting the pre-mixture (n-pentane and air) with two spark plugs. In the second technique, TMPD vapor concentration is measured by using Laser Induced Exciplex Fluorescence method (LIEF). The concentration is compensated by investigation of the influence of ambient pressure (from 3 to 5 MPa) and temperature (from 550 to 900 K) on TMPD fluorescence intensity. By using two techniques, we investigated the influence of nozzle hole diameter, injection pressure and ambient condition on spray characteristics.

The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.

Combustion and exhaust emission characteristics were compared among three representative diesel fuels called “Base (corresponding to a Japanese market fuel)”, “Improved” and Swedish “Class-1” using both a modern small and an optically accessible single-cylinder DI diesel engines. In these tests, the relative amount of PM collected in the exhaust was “Base” >“Class-1” >“Improved” at almost all of the operating conditions. This means that “Class-1” generated more PM than “Improved”, even though “Class-1” has significantly lower distillation temperatures, aromatic content, sulfur, and density compared with “Improved”. There was little difference in combustion characteristics such as heat release rate pattern, mixture formation and flame development processes between these two fuels. However, it was found that “Class-1” contained more branches in the paraffin fraction and more naphthenes.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

The design of the newly developed Toyota AZ series 4 cylinder engine has been optimized through both simulations and experiments to improve heat transfer, cooling water flow, vibration noise and other characteristics. The AZ engine was developed to achieve good power performance and significantly reduced vibration noise. The new engine meets the LEV regulations due to the improved combustion and optimized exhaust gas flow. A major reduction in friction has resulted in a significant improvement in fuel economy compared with conventional models. It also pioneered a newly developed resin gear drive balance shaft.

Toyota Hybrid System (THS), the powertrain that combines a gasoline engine and an electric motor was first introduced in December 1997. It became the first mass-produced hybrid passenger vehicle in the world, gaining a reputation as a highly innovative vehicle, and its cumulative worldwide sales have exceeded 120,000 units. In 2003, THS had a further evolution. The “new-generation Toyota Hybrid System (THS II)” would be introduced on the new Prius. This report shall explain “THS II”, which achieved drastic improvements in power performance and fuel economy, while securing the most stringent emission standard Advanced Technology Partial Zero Emission Vehicle (ATPZEV).

CARB (California Air Resources Board) has required the evaporative emissions to be restricted to 1/4th of the parameter stated in the 1995 regulations. Furthermore, hydrocarbons (hereafter, HC) from the fuel system must be reduced to near 0.0 grams, according to the PZEV (Partial Zero Emission Vehicle) regulations enforced from 2003. The wet film in intake ports and fuel leaking from the injector nozzles evaporate and diffuse while the car is parked, and consequently may cause HC to leak the air cleaner inlet. The air cleaner which prevents HC leakage from the air intake system is already in mass production. In the course of designing this product to be installed in a vehicle, the authors developed a method to estimate the amount of HC that reaches the air cleaner. Based on detailed investigation on HC distribution and the changes that occur during parking, the HC amount reaching the air cleaner was calculated by both the equation of diffusion and the equation of state.

Experimental investigations were conducted with a direct-injection diesel engine to improve exhaust emission, especially nitrogen oxide (NOx) and particulate matter (PM), without increasing fuel consumption. As a result of this work, a new combustion concept, called Modulated Kinetics (MK) combustion, has been developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion, respectively. The characteristics of a new combustion concept were investigated using a single cylinder DI diesel engine and combustion photographs. The low compression ratio, EGR cooling and high injection pressure was applied with a multi-cylinder test engine to accomplish premixed combustion at high load region. Combustion chamber specifications have been optimized to avoid the increase of cold-start HC emissions due to a low compression ratio.