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To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

Mexican automobile manufacturers will begin to phase in catalytic converters on new models during the early 1990's. A more immediate concern that needs to be addressed is the large remaining older car population that will continue to pollute the air. Retrofitting these vehicles with catalytic converters is one of the alternatives being considered in a collective effort to improve Mexico City's air quality. In collaboration with Mexico City government officials, a vehicle demonstration was designed to show the benefits of an oxidation catalyst retrofit. This paper presents emission results of Mexico City's taxi fleet vehicles and displays the effectiveness of a Pt/Pd oxidation catalyst system in lowering emission levels. Two fleet vehicles were emission tested before and after catalyst retrofit modifications with the U.S. FTP-75 vehicle test method. Carburetor modifications were also included to study the effects of engine tuning on engine emissions and catalyst performance.

Various noble metal compositions are used for three-way catalyst applications. The most typical composition contains platinum and rhodium at various loadings and ratios. Recently palladium and rhodium compositions have received considerable attention by automobile companies. The strengths and weaknesses of the various noble metal use strategies have been widely discussed. Unfortunately, the content for much of the discussion has been based on information generated in the early to mid-1970s with catalysts of relatively simple formulation when compared to today's higher technology products. The present study compares the relative durability performance of modern platinum/rhodium and palladium/rhodium catalysts of identical loading under a variety of aging and evaluation conditions. These conditions were chosen to simulate some of the operating conditions encountered in U.S. and European driving applications.

The successful design and especially the control of the SCR system is a challenging process that can be supported by the application of simulation tools. As a first step, we employ physico-chemically informed ‘off-line’ models that are calibrated with the help of targeted small- and full-scale tests. Despite their high level of sophistication, this SCR model is able to be integrated in a control-oriented simulation software platform and connected to other powertrain simulation blocks. The target is to use this simulation platform as a virtual environment for the development and optimization of SCR control strategies. The above process is demonstrated in the case of a passenger car SCR. The model is calibrated at both fresh and aged catalyst condition and validated using experimental data from the engine bench under a wide variety of operating conditions. Next, the calibrated model was coupled with embedded control models, developed for Euro 6 passenger car powertrains.

In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

Recent advances in three-way catalyst formulations have led to significant improvements in durability and performance. These advances for recent Pt/Rh catalyst formulations, for the most part/have been due to a reduction of thermal deactivation. Increased durability plays a critical role in the reducing noble metal usage/meeting tighter emission standards/and extending the durability warranty requirements. In reality, significant advances may be not be readily apparent because of the methods used to evaluate the technology. Some performance benefits may be transparent to particular durability and evaluation procedures, or certain vehicle emission systems. However, as part of an optimized vehicle/catalyst system, the performance benefits may be pronounced. This paper examines the benefits of improved three-way catalyst technologies in order to accelerate their application for tougher emission requirements.

The noble metal palladium (Pd) has the capability of simultaneously converting significant quantities of HC, CO and NOx in automotive exhaust. Primary interests in using palladium-containing TWC catalysts are overall noble metal cost reduction, reduction in rhodium usage and important performance advantages. Dynamometer aging experiments comparing palladium and platinum/rhodium catalysts were conducted under a variety of operating conditions. Vehicle evaluation of these aged catalysts under U.S. FTP-75, European ECE-15 and Japan 10-Mode conditions indicate that palladium-only TWC technology is viable for achieving high levels of three-way control. Vehicle aging studies (25K miles) were also conducted. They confirm the excellent durability results obtained from the dynamometer aging studies: the palladium-only TWC catalyst gave essentially equivalent U.S. FTP-75 and Japan 10-Mode performance to a high-tech platinum/rhodium catalyst.

An H2S odor problem has appeared for certain vehicles fitted with modern three-way catalysts. A sulfur storage/H2s release mechanism is proposed as a source of the odor problem. The effects of various operating parameters on the release of H2S are presented. Two methods of modifying three-way catalysts to minimize H2S release while maintaining good catalyst performance and high temperature durability are demonstrated.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.