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Brake calipers for high-end cars are typically realized using Aluminum alloys, with Silicon as the most common alloying element. Despite the excellent castability and machinability of Aluminum-Silicon alloys (AlSix), anodization is often required in order to increase its corrosion resistance. This is particularly true in Chlorides-rich environments where Aluminum can easily corrode. Even if anodization process is known for almost 100 years, anodization of AlSix -based materials is particularly challenging due to the presence of eutectic Silicon precipitates. These show a poor electric conductivity and a slow oxidation kinetics, leading to inhomogeneous anodic layers. Continuous research and process optimization are required in order to develop anodic layers with enhanced morphological and electrochemical properties, targeting a prolonged resistance of brake calipers under endurance corrosive tests (e.g. >1000 hours Neutral Salt Spray (NSS) tests).

The work investigates the effect of different Iron and Manganese contents in ad-hoc cast specimens made from recycled EN AC-43200 alloy. Tensile tests and metallographic analyses coupled with energy dispersive X-ray spectroscopy measurements are carried out to elucidate the interplay between the microstructure and the quasi-static properties of the Aluminium-Silicon alloy under investigation. A strong correlation between the composition and morphology of Fe/Mn -based intermetallic precipitates and tensile properties is demonstrated. Moreover, it is found that specific intermetallic phases are present only for certain, relative and/or absolute contents of Fe and Mn.