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Premixed charge compression ignition (PCCI) is an advanced combustion mode that has the aim of simultaneously reducing particulate matter and nitrogen oxide exhaust emissions, compared with conventional diesel combustion, thanks to a partially premixed charge and low temperature combustion. In this work, PCCI combustion has been implemented by means of an early single-injection strategy and large amounts of recirculated exhaust gas. Starting from a commercial Euro VI on-road engine, the engine hardware has been modified to optimize PCCI operations. This has involved adopting a smaller turbo group, a new combustion chamber and injectors, and a dedicated high-pressure exhaust gas recirculation system. The results, in terms of engine performance and exhaust emissions, under steady-state operation conditions, are presented in this work, where the original Euro VI calibration of the conventional engine has been compared with the PCCI calibration of the optimized hardware engine.