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Fuel quality has a significant influence on the combustion engine operation. In recent years the increasing concerns about environmental protection, energy saving, energy security and the requirements of protecting fuel injection and aftertreatment systems have been major driving forces for the Chinese fuel specification evolution. The major property changes in the evolution of Chinese national gasoline and diesel standards are introduced and the reasons behind these changes are analyzed in this paper. The gasoline fuel development from State I to State VI-B involved a decrease of sulfur, manganese, olefins, aromatics and benzene content. The diesel fuel quality improvement from State I to State VI included achieving low sulfur fuels and a cetane number (CN) increase. Provincial fuel standards, stricter than corresponding national standards, were implemented in economically developed areas in the past.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

The effects of different biodiesel blends on engine-out emissions under various transient conditions were investigated in this study using fast response diagnostic equipment. The experimental work was conducted on a modern 3.0 L, V6 high pressure common rail diesel engine fuelled with mineral diesel (B0) and three different blends of rapeseed methyl esters (RME) (B30, B60, B100 by volume) without any modifications of engine parameters. DMS500, Fast FID and Fast CLD were used to measure particulate matter (PM), total hydrocarbon (THC) and nitrogen monoxide (NO) respectively. The tests were conducted during a 12 seconds period with two tests in which load and speed were changed simultaneously and one test with only load changing. The results show that as biodiesel blend ratio increased, total particle number (PN) and THC were decreased whereas NO was increased for all the three transient conditions.

Owing to environmental and health concerns, tetraethyl lead was gradually phased out from the early 1970's to mid-1990's in most developed countries. Advances in refining, leading to more aromatics (via reformate) and iso-paraffins such as iso-octane, along with the introduction of (bio) oxygenates such as MTBE, ETBE and ethanol, facilitated the removal of lead without sacrificing RON and MON. In recent years, however, legislation has been moving in the direction of curbing aromatic and olefin content in gasoline, owing to similar concerns as was the case for lead. Meanwhile, concerns over global warming and energy security have motivated research into renewable fuels. Amongst which are those derived from biomass. The feedstock of interest in this study is lignin, which, together with hemicellulose and cellulose, is amongst the most abundant organic compounds on the planet.

We compare, with respect to vehicle characteristics (design, performance, fuel economy) and infrastructure requirements (cost of producing, transporting and delivering fuel), four possible energy carrier options for use with fuel cell vehicles: compressed hydrogen gas methanol with onboard steam reforming gasoline with onboard partial oxidation synthetic middle distillates (SMD) derived from natural gas with onboard partial oxidation. Our simulations indicate that hydrogen is the preferred fuel for fuel cell vehicles in terms of vehicle weight, simplicity, first cost and fuel economy. The total capital cost for equipment to bring hydrogen to the fuel cell (including both onboard fuel processors and off-vehicle fuel infrastructure) is comparable for methanol, gasoline and SMD, and lower for hydrogen.

Atomization of fuel sprays is a key factor in controlling the combustion quality in the direct-injection engines. In this present work, the effect of saturation ratio (Rs) on the near nozzle spray patterns of ethanol was investigated using an ultra-high speed imaging technique. The Rs range covered both flash-boiling and non-flash boiling regions. Ethanol was injected from a single-hole injector into an optically accessible constant volume chamber at a fixed injection pressure of 40 MPa with different fuel temperatures and back pressures. High-speed imaging was performed using an ultrahigh speed camera (1 million fps) coupled with a long-distance microscope. Under non-flash boiling conditions, the effect of Rs on fuel development was small but observable. Clear fuel collision can be observed at Rs=1.5 and 1.0. Under the flash boiling conditions, near-nozzle spray patterns were significant different from the non-flash boiling ones.

Polyoxymethylene dimethyl ethers (PODEn) are promising alternative fuel candidates for diesel engines because they present advantages in soot reduction. This study uses a PODEn mixture (contains PODE3-6) from mass production to provide oxygen component in blend fuels. The spray combustion of PODEn-diesel bend fuels in a constant volume vessel was studied using high speed imaging, PLII-LEM and OH* chemiluminescence. Fuels of several blend ratios are compared with pure diesel. Flame luminance data show a near linear decrease tendency with the blend ratio increasing. The OH* images reveal that the ignition positions of all the cases have small differences, which indicates that using a low PODEn blend ratio of no more than 30% does not need significant adjustment in engine combustion control strategies. It is found that 30% PODEn blended with diesel (P30) can effectively reduce the total soot by approximately 68% in comparison with pure diesel.

Homogeneous Charge Induced Ignition (HCII) combustion is believed to be a promising approach to achieve clean and high efficiency combustion. HCII can be realized by using port-injection of the high-volatile fuel (gasoline) to prepare in-cylinder homogeneous charge and direct injection of the high-ignitable fuel (diesel) near the top dead center to control the start of combustion. In the current study, a numerical study was carried out to understand the mixing and auto-ignition process in HCII combustion. A multicomponent chemical kinetic mechanism for gasoline and diesel, consisting of n-heptane, iso-octane, ethanol, toluene, diisobutylene and n-decane, has been developed for predicting their ignition and oxidation. The final mechanism consists of 104 species and 398 reactions. This mechanism was validated with the experimental data of ignition delay times and laminar flame speeds for each component and real transportation fuels.

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

In earlier research, a new class of bio-fuels, so-called cyclic oxygenates, was reported to have a favorable impact on the soot-NOx trade-off experience in diesel engines. In this paper, the soot-NOx trade-off is compared for two types of cyclic oxygenates. 2-phenyl ethanol has an aromatic and cyclohexane ethanol a saturated or aliphatic ring structure. Accordingly, the research is focused on the effect of aromaticity on the aforementioned emissions trade-off. This research is relevant because, starting from lignin, a biomass component with a complex poly-aromatic structure, the production of 2-phenyl ethanol requires less hydrogen and can therefore be produced at lower cost than is the case for cyclohexane ethanol.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

The ethanol has potential to be a renewable alternative fuel for internal combustion engines and contributes to lower global CO2 emission. In this study, vegetable methyl ester is added in the ethanol-diesel fuel to prevent separation of the ethanol from diesel, thus the ethanol blend ratio can be set up to 30% in volume. This work pays more attention on its spray, effects of the ethanol percentage on the detailed PM components. To investigate the spray behavior of ethanol, diesel and their blends, experiments in a constant volume chamber were carried out combining numerical simulation. Properties of the ethanol-diesel blended fuels were obtained through some measurements and empirical calculations. The breakup sub-model, Wave-KH model considering the blend fuel properties were adopted in an engine simulation code KIVA-3V. The simulation had a good agreement with experiments.

Results are presented of 3-D computations of direct injection of gaseous methane and of liquid tetradecane through a multi-hole injector into a Diesel engine. The study focusses on the distribution of fuel/air ratio within the resulting gas and spray jets under typical Diesel conditions prior to ignition. It is shown that for a significant time after start of injection, the fraction of the vapor fuel which is in richer-than-flammable mixtures is greater in gas jets than in sprays. For methane injection, it is also shown that changing some of the flow conditions in the engine or going to a poppet-type injector, does not result in improved mixing. An explanation of these results is provided also through an analysis of the self-similar gas jet and 2-D computations of gas and spray jets into constant pressure gas. A scaling for time and axial distance in the self-similar gas jet also clarifies the results.

The combustion characteristics of three gaseous fuels (hydrogen, methane and ethane) in a direct-injection stratified-charge single-cylinder engine with a centered square head-cup operated at 800 rpm (compression ratio = 10.8, squish ratio = 75%, nominal swirl ratio = 4) were studied to assess the extent to which the combustion is controlled by turbulent mixing, laminar mixing and chemical kinetics. The injection of gaseous fuels was via a Ford AFI injector, originally designed for the air-forced injection of liquid fuel. Pressure measurements in the engine cylinder and in the injector body, coupled with optical measurements of the injector poppet lift and shadowgraph images of the fuel jets provided both quantitative and qualitative information about the in-cylinder processes. To make the cases comparable, the total momentum of the fuel jets and the total heat released by the three fuels was kept the same (equivalence ratio = 0.316, 0.363, 0.329 for H2, CH4 and C2H6, respectively).

Octane number (ON) and octane sensitivity (S), the fuel anti-knock indices, are critical for the design of advanced jet ignition engines. In this study, ten fuels with different research octane number (RON) and varying S were formulated based on ethanol reference fuels (ERFs) to investigate the effect of S on combustion of jet ignition engine. To fully understand S effects, the combustion characteristics under EGR dilution and lean burn were further investigated. The results indicated that increasing S resulted in higher reactivity with shorter ignition delay and combustion duration. The increase of reactivity led to heavier knocking intensity. The competition between the flame speed and the reactivity of the mixture determined the auto-ignition fraction of mixture and the knocking onset crank angle as S varied. Medium S (S=3) was helpful to improve the combustion speed, reduce the auto-ignition fraction of mixture and retard the knocking onset crank angle.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

N-butanol, as a biomass-based renewable fuel, has many superior fuel properties. It has a higher energy content and cetane number than its alcohol competitors, methanol and ethanol. Previous studies have proved that n-butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency when blended with diesel. However, most studies on n-butanol are limited to low blending ratios, which restricts the improvement of emissions. In this paper, 80% by volume of n-butanol was blended with 20% by volume of n-heptane (namely BH80). The influences of various engine parameters (combustion phasing, EGR ratio, injection timing and intake pressure, respectively) on its combustion and emission characteristics are tested at different loads. The results showed that when BH80 uses more than 40% EGR, the emitted soot and nitrogen oxides (NOx) emissions are below the EURO VI legislation.

Recent research has shown that butanol, instead of ethanol, has the potential of introducing a more suitable blend in diesel engines. This is because butanol has properties similar to current transportation fuels in comparison to ethanol. However, the main downside is the high cost of the butanol production process. Acetone-butanol-ethanol (ABE) is an intermediate product of the fermentation process of butanol production. By eliminating the separation and purification processes, using ABE directly in diesel blends has the potential of greatly decreasing the overall cost for fuel production. This could lead to a vast commercial use of ABE-diesel blends on the market. Much research has been done in the past five years concerning spray and combustion processes of both neat ABE and ABE-diesel mixtures. Additionally, different compositions of ABE mixtures had been characterized with a similar experimental approach.