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In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

Results of computations of flows, sprays and combustion performed in an optically- accessible Diesel engine are presented. These computed results are compared with measured values of chamber pressure, liquid penetration, and soot distribution, deduced from flame luminosity photographs obtained in the engine at Sandia National Laboratories and reported in the literature. The computations were performed for two operating conditions representing low load and high load conditions as reported in the experimental work. The computed and measured peak pressures agree within 5% for both the low load and the high load conditions. The heat release rates derived from the computations are consistent with expectations for Diesel combustion with a premixed phase of heat release and then a diffusion phase. The computed soot distribution shows noticeable differences from the measured one.

Numerical computations of combusting transient jets are performed under diesel-like conditions. Discussions of the structure of such jets are presented from global and detailed points of view. From a global point of view, we show that the computed flame heights agree with deductions from theory and that integrated soot mass and heat release rates are consistent with expected trends. We present results of several paramaters which characterise the details of the jet structure. These are fuel mass fractions, temperature, heat release rates, soot and NO. Some of these parameters are compared with the structure of a combusting diesel spray as deduced from measurements and reported in the literature. The heat release rate contours show that the region of chemical reactions is confined to a thin sheet as expected for a diffusion flame. The soot contour plots appear to agree qualitatively with the experimental observations.

A fast time-scale 1-D dynamic diesel particulate filter model capable of resolving the pressure pulsations due to individual cylinder firing events is presented. The purpose of this model is to investigate changes in the firing frequency component of the pulsating exhaust flow at different particulate loadings. Experimental validation data and simulation results clearly show that the magnitude and phase of the firing frequency components are directly correlated to the mass of particulate stored in a diesel particulate filter. This dynamic pressure signal information may prove particularly useful for monitoring particulate load during vehicle operation.

This paper provides a comparison of wall heat fluxes and quenching distances as one-dimensional hydrogen and heptane flames impinge head-on onto a wall. It is shown that the quenching distances for stoichiometric H2/air and C7H16/air flames under the specified conditions of this study are about the same, but the wall heat flux for the H2/air flames is approximately a factor of two greater. For lean H2/air mixtures, the quenching distance increases substantially and the wall heat flux decreases. To understand more clearly the interplay of flame speed, temperature, thermal diffusivity, and surface kinetics on the results, studies of H2/O2 flames are also carried out.

PGBA, a plant growth facility developed for commercial space biotechnology research, successfully grew a total of 50 plants (6 species) during 10 days aboard the Space Shuttle Endeavor (STS-77), and has reflown aboard the Space Shuttle Columbia (STS-83 for 4 days and STS-94 for 16 days) with 55 plants and 10 species. The PGBA life support system provides atmospheric, thermal, and humidity control as well as lighting and nutrient supply in a 33 liter microgravity plant growth chamber. The atmosphere treatment system removes ethylene and other hydrocarbons, actively controls CO2 replenishment, and provides passive O2 control. Temperature and humidity are actively controlled.

A steady-state system mass balance calculation was performed to investigate design issues regarding the storage and/or processing of solid waste. In the initial stages of BIO-Plex, only a certain percentage of the food requirement will be satisfied through crop growth. Since some food will be supplied to the system, an equivalent amount of waste will accumulate somewhere in the system. It is a system design choice as to where the mass should accumulate in the system. Here we consider two approaches. One is to let solid waste accumulate in order to reduce the amount of material processing that is needed. The second is to process all of the solid waste to reduce solid waste storage and then either resupply oxygen or add physical/chemical (P/C) processors to recover oxygen from the excess carbon dioxide and water that is produced by the solid waste processor.

The Plant Generic BioProcessing Apparatus (PGBA), a plant growth facility developed for commercial space biotechnology research, has flown successfully on 3 spaceflight missions for 4, 10 and 16 days. The environmental control systems of this plant growth chamber (28 liter/0.075 m2) provide atmospheric, thermal, and humidity control, as well as lighting and nutrient supply. Typical performance profiles of water transpiration and dehumidification, carbon dioxide absorption (photosynthesis) and respiration rates in the PGBA unit (on orbit and ground) are presented. Data were collected on single and mixed crops. Design options and considerations for the different sub-systems are compared with those of similar hardware.

The “low power-CO2 removal (LPCOR) system” is an advanced air revitalization system that is under development at NASA Ames Research Center. The LPCOR utilizes the fundamental design features of the ‘four bed molecular sieve’ (4BMS) CO2 removal technology of the International Space Station (ISS). LPCOR improves power efficiency by replacing the desiccant beds of the 4BMS with a membrane dryer and a state-of-the-art, structured adsorbent device that collectively require 25% of the thermal energy required by the 4BMS desiccant beds for regeneration. Compared to the 4BMS technology, it has the added functionality to deliver pure, compressed CO2 for oxygen recovery. The CO2 removal and recovery functions are performed in a two-stage adsorption compressor. CO2 is removed from the cabin air and partially compressed in the first stage. The second stage performs further compression and delivers the compressed CO2 to a reduction unit such as a Sabatier reactor for oxygen recovery.

Designers of future space vehicles envision simplifying the Atmosphere Revitalization (AR) system by combining the functions of trace contaminant (TC) control and carbon dioxide removal into one swing-bed system. Flow rates and bed sizes of the TC and CO2 systems have historically been very different. There is uncertainty about the ability of trace contaminant sorbents to adsorb adequately in a high-flow or short bed length configurations, and to desorb adequately during short vacuum exposures. This paper describes preliminary results of a comparative experimental investigation into adsorbents for trace contaminant control. Ammonia sorbents and low temperature catalysts for CO oxidation are the foci. The data will be useful to designers of AR systems for Constellation. Plans for extended and repeated vacuum exposure of ammonia sorbents are also presented.

Dynamic simulation of the lunar outpost habitat life support was undertaken to investigate the impact of life support failures and to investigate possible responses. Some preparatory static analysis for the Lunar Outpost life support model, an earlier version of the model, and an investigation into the impact of Extravehicular Activity (EVA) were reported previously. (Jones, 2008-01-2184, 2008-01-2017) The earlier model was modified to include possible resupply delays, power failures, recycling system failures, and atmosphere and other material storage failures. Most failures impact the lunar outpost water balance and can be mitigated by reducing water usage. Food solids and nitrogen can be obtained only by resupply from Earth. The most time urgent failure is a loss of carbon dioxide removal capability. Life support failures might be survivable if effective operational solutions are provided in the system design.

In February 2004 NASA released “The Vision for Space Exploration.” The goals outlined in this document include extending the human presence in the solar system, culminating in the exploration of Mars. A key requirement for this effort is to identify a safe and effective method to process waste. Methods currently under consideration include incineration, microbial oxidation, pyrolysis, drying, and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this work was to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. TDA and NASA Ames Research Center have developed a pilot scale low temperature ozone oxidation system to convert organic waste to CO2 and H2O.

In this paper, a wall-modified interactive flamelet model is developed for improving the modeling of Diesel combustion. The objective is to include the effects of wall heat loss on the transient flame structure. The essential idea is to compute several flamelets with several representative enthalpy defects which account for wall heat loss. Then, the averaged flamelet profile can be obtained through a linear fit between the flamelets according to the enthalpy defect of the local gas which results from the wall heat loss. The enthalpy defect is estimated as the difference between the enthalpy in a flamelet without wall heat loss, which would correspond to the enthalpy in the gas without wall heat loss, and the gas with wall heat loss. The improved model is applied to model combustion in a Diesel engine. In the application, two flamelets, one without wall heat loss and one with wall heat loss, are considered.

Multidimensional models are increasingly employed to predict NO and soot emissions from Diesel engines. In the traditional approach, the ensemble-averaged values of variables are employed in the expressions for NO and soot formation and oxidation. In the mixture fraction averaged approach, the values of state variables and species concentrations are obtained from the structure of laminar diffusion flames. The source terms for NO and soot are then obtained by averaging across the mixture fraction coordinate with a probability density function. The clipped-Gaussian probability density function and profiles obtained by employing the OPPDIF code (part of the CHEMKIN package) for the laminar flame structure are employed in this work. The Zeldovich mechanism for NO formation and the Moss et al. formation and Nagle-Strickland-Constable oxidation model for soot have been employed to study the qualitative trends of pollutants in transient combusting Diesel jets.

The current CO2 removal technology of NASA is very energy intensive and contains many non-optimized subsystems. This paper discusses the concept of a next-generation, membrane-integrated, adsorption processor for CO2 removal and compression in closed-loop air revitalization systems. The membrane module removes water from the feed, passing it directly into the processor's exhaust stream; it replaces the desiccant beds in the current four-bed molecular sieve system, which must be thermally regenerated. Moreover, in the new processor, CO2 is removed and compressed in a single two-stage unit. This processor will use much less power than NASA's current CO2 removal technology and will be capable of maintaining a lower CO2 concentration in the cabin than that can be achieved by the existing CO2 removal systems.

Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. Various factors are involved in the design of an optimum fluidized bed incinerator for inedible biomass. The factors include variability of moisture in the biomass, the ash content, and the amount of fuel nitrogen in the biomass. The crop mixture in the waste will vary; consequently the nature of the waste, the nitrogen content, and the biomass heating values will vary as well. Variation in feed will result in variation in the amount of contaminants such as nitrogen oxides that are produced in the combustion part of the incinerator. The incinerator must be robust enough to handle this variability. Research at NASA Ames Research Center using the fluidized bed incinerator has yielded valuable data on system parameters and variables.

We modeled BIO-Plex designs with separate or combined atmospheres and then simulated controlling the atmosphere composition. The BIO-Plex is the Bioregenerative Planetary Life Support Systems Test Complex, a large regenerative life support test facility under development at NASA Johnson Space Center. Although plants grow better at above-normal carbon dioxide levels, humans can tolerate even higher carbon dioxide levels. Incinerator exhaust has very high levels of carbon dioxide. An elaborate BIO-Plex design would maintain different atmospheres in the crew and plant chambers and isolate the incinerator exhaust in the airlock. This design option easily controls the crew and plant carbon dioxide levels but it uses many gas processors, buffers, and controllers. If all the crew’s food is grown inside BIO-Plex, all the carbon dioxide required by the plants can be supplied by crew respiration and the incineration of plant and food waste.

New variable environment Modified Energy Cascade (MEC) crop models were developed for all the Advanced Life Support (ALS) candidate crops and implemented in SIMULINK. The MEC models are based on the Volk, Bugbee, and Wheeler Energy Cascade (EC) model and are derived from more recent Top-Level Energy Cascade (TLEC) models. The MEC models were developed to simulate crop plant responses to day-to-day changes in photosynthetic photon flux, photoperiod, carbon dioxide level, temperature, and relative humidity. The original EC model allowed only changes in light energy and used a less accurate linear approximation. For constant nominal environmental conditions, the simulation outputs of the new MEC models are very similar to those of earlier EC models that use parameters produced by the TLEC models. There are a few differences. The new MEC models allow setting the time for seed emergence, have more realistic exponential canopy growth, and have corrected harvest dates for potato and tomato.

The standard model for predicting the outcome of drop-drop collisions in sprays is one developed based on measurements in rain drops under atmospheric pressure conditions. This model includes the possible outcomes of grazing collisions and coalescence. Recent measurements with hydrocarbon drops and at higher pressure (up to 12 bar) indicate the possibility of additional outcomes: bounce, reflexive separation and drop shattering. The measurements also indicate that the Weber number range over which bounce occurs is dependent on the gas pressure. The probability of a drop-drop collision resulting in bounce increases with gas pressure. A composite model that includes all these outcomes as possibilities is employed to carry out computations in a constant volume chamber and in a Diesel engine. A sub-model for bounce that includes the pressure effects is also part of the composite model.

In recent years, there has been an interest in early-injection Diesel engines as it has the potential of achieving a more homogeneous and leaner mixture close to top-dead-center (TDC) compared to standard Diesel engines. The more homogeneous mixture may result in reduced NOx and soot emissions and higher efficiency. Diesel engines in which a homogeneous mixture is achieved close to TDC are known as Homogenous Charge Compression Ignition (HCCI) engines. PREmixed lean DIesel Combustion (PREDIC) engines in which the start of fuel injection is considerably advanced in comparison with that of the standard Diesel engine is an attempt to achieve a mode of operation close to HCCI. Earlier studies have shown that in a PREDIC engine, the fuel injection timing affects the mixture formation and hence influences combustion and pollutant formation.