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Over the last two decades, global emission regulations have become more stringent and have required the use of more advanced fuel injection systems. This includes the use of tighter tolerances, more rapid injections and internal components actuated by weaker injection forces. Unfortunately, these design features make the entire system more susceptible to fuel contaminants. Over the last six years, the composition of these contaminants has evolved from hard insoluble debris, such as dust and rocks, to soluble chemical contaminants. Recent research by the diesel engine manufacturers, fuel injection equipment suppliers and the fuel and fuel additive industry has discovered a major source of the soluble chemical contaminant that leads to injector deposits to be derived from cost effective and commonly used additives used to protect against pipeline corrosion.

The new devices and missions to achieve the aims of NASA's Science Mission Directorate (SMD) are creating increasingly demanding thermal environments and applications. In particular, the low conductance of metal-to-metal interfaces used in the thermal switches lengthen the cool-down phase and resource usage for spacecraft instruments. During this work, we developed and tested a vacuum-compatible, durable, heat-conduction interface that employs carbon nanotube (CNT) arrays directly anchored on the mating metal surfaces via microwave plasma-enhanced, chemical vapor deposition (PECVD). We demonstrated that CNT-based thermal interface materials have the potential to exceed the performance of currently available options for thermal switches and other applications.

Numerical computations of combusting transient jets are performed under diesel-like conditions. Discussions of the structure of such jets are presented from global and detailed points of view. From a global point of view, we show that the computed flame heights agree with deductions from theory and that integrated soot mass and heat release rates are consistent with expected trends. We present results of several paramaters which characterise the details of the jet structure. These are fuel mass fractions, temperature, heat release rates, soot and NO. Some of these parameters are compared with the structure of a combusting diesel spray as deduced from measurements and reported in the literature. The heat release rate contours show that the region of chemical reactions is confined to a thin sheet as expected for a diffusion flame. The soot contour plots appear to agree qualitatively with the experimental observations.

In Diesel engines, the vapor phase of the fuel jet is known to impinge on the walls. This impingement is likely to have an effect on mixing characteristics, the structure of the diffusion flame and on pollutant formation and oxidation. These effects have not been studied in detail in the literature. In this work, the structure of a laminar wall jet that is generated from the impingement of a free laminar jet on a wall is discussed. We study the laminar jet with the belief that the local structure of the reaction zone in the turbulent reacting jet is that of a laminar flame. Results from non-reacting and reacting jets will be presented. In the case of the non-reacting jets, the focus of the inquiry is on assessing the accuracy of the computed results by comparing them with analytical results. Velocity profiles in the wall jet, growth rates of the half-width of the jet and penetration rates are presented.

Accurate estimation of catalyst bed temperatures is very crucial for effective control and diagnostics of aftertreatment systems. The architecture of most aftertreatment systems contains temperature sensors for measuring the exhaust gas temperatures at the inlet and outlet of the aftertreatment systems. However, the temperature that correctly reflects the temperature of the chemical reactions taking place on the catalyst surface is the catalyst bed temperature. From the Arrhenius relationship which governs the chemical reaction kinetics occurring in different aftertreatment systems, the rate of chemical reaction is very sensitive to the reaction temperature. Considerable changes in tailpipe emissions can result from small changes in the reaction temperature and robust emissions control systems should be able to compensate for these changes in reaction temperature to achieve the desired tailpipe emissions.

Resource recovery, including that of urine water extraction, is one of the most crucial aspects of long-term life support in interplanetary space travel. This paper will consequently examine an innovative approach to processing raw, undiluted urine based on low-temperature freezing. This strategy is uniquely different from NASA's current emphasis on either ‘integrated’ (co-treatment of mixed urine, grey, and condensate waters) or ‘high-temperature’ (i.e., VCD [vapor compression distillation] or VPCAR [vapor phase catalytic ammonia removal]) processing strategies, whereby this liquid freeze-thaw (LiFT) procedure would avoid both chemical and microbial cross-contamination concerns while at the same time securing highly desirable reductions in likely ESM levels.

Three-way catalysts have been used in a variety of stoichiometric natural gas engines for emission control. During real-world operation, these catalysts have experienced a large number of temporary and permanent deactivations including thermal aging and chemical contamination. Thermal aging is typically induced either by high engine-out exhaust temperatures or the reaction exotherm generated on the catalysts. Chemical contamination originates from various inorganic species such as Phosphorous (P) and Sulfur (S) that contain in engine fluids, which can poison and/or mask the catalyst active components. Such deactivations are quite difficult to simulate under laboratory conditions, due to the fact that multiple deactivation modes may occur at the same time in the real-world operations. In this work, a set of field-aged TWCs has been analyzed through detailed laboratory research in order to identify and quantify the real-world aging mechanisms.

Inside an automobile, hundreds of connectors and electrical terminals in various locations experience different corrosive environments. These connectors and electrical terminals need to be corrosion-proof and provide a good electrical contact for a vehicle’s lifetime. Saltwater and sulfuric acid are some of the main corrosion concerns for these electrical terminals. Currently, various thin metallic layers such as gold (Au), silver (Ag), or tin (Sn) are plated with a nickel (Ni) layer on copper alloy (Cu) terminals to ensure reliable electrical conduction during service. Graphene due to its excellent chemical stability can serve as a corrosion protective layer and prevent electrochemical oxidation of metallic terminals. In this work, effects of thin graphene layers grown by plasma-enhanced chemical vapor deposition (PECVD) on Au and Ag terminals and thin-film devices were investigated. Various mechanical, thermal/humidity, and electrical tests were performed.