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The next generation of diesel engines will require substantial reductions in particulate matter (PM) emissions. In addition to strict regulations, one of the major problems in the development is the lack of sophisticated real-time PM analyzers. The current PM measurement technology consists of a dilution tunnel and filter weighing technique that was developed before the 1980s.(1) Such technology has reached its limit for today's diesel exhaust monitoring requirements in terms of response time and sensitivity. A flame ionization detector (FID), commonly used for measuring hydrocarbons, is proposed as a new analyzer for PM. In the past, spike signals observed from the FID when measuring diesel exhaust have been considered noise and a lot effort has been spent to reduce such interference from the slower FID signal. However, given a fast response time FID, these spike signals could be used to represent PM concentration in the sample.

Two new techniques have been applied to FTIR emission analysis which add significant potential to automotive emission measurement. One of these is the use of the mathematical multivariate analysis which is called the partial least squares method. This spectrum discrimination technique, in combination with high resolution spectrum data, enables superior analysis for heavy-overlapping species in the emission. The other technique is a flow conditioned gas sampling cell which is designed especially for real time emission measurement. The flow in the gas cell has been analyzed with computer simulation and the gas cell has a flow conditioner inside with a 10 meter optical path. Seven seconds of 90 percent gas replacement time can be achieved with this cell. As a result, highly accurate realtime data can be obtained with relatively fast response. In this paper, spectrum factors extracted from overlapping species and quantification simulations are shown using standard gases.

Particulate in the automotive emission gas is, whether the source of the engine is gasoline or diesel, a continuous target for the analysis because of its harmful feature to the environment, however, the actual measurement has been requiring various complicated procedures with lengthy time. The experiment is given by a measuring device which enables the direct measurement of a single particulate individually based on Helium Microwave Induced Plasma (MIP). This new device consists of three main parts: 1) the introducing section to induce a particulate on the filter as diffusing separately by He sonic velocity, 2) the exciting section with He plasma torch of high energy, and 3) the detecting section with 4 monochromators. Also, the automatic calibration function assures the accurate measurement, saving the manual calibration beforehand. The analyzer allows to measure the particles one by one. This consequence allows the high precision results with a fast, easy operation.

A detailed description of flow rate measurement technique for automotive exhaust is presented. The system consists of a sector field mass spectrometer for continuous analysis of helium concentration in the exhaust gas and a mass flow controller which injects pure helium at a constant rate into the intake manifold of an engine. The exhaust flow rate can be calculated by helium injection flow rate dividing by the concentration since the concentration value is a measure of the ratio of helium dilution taking place in the engine. The advantages of the technique consist of (1) no disturbance from strong pulsed flow present when an engine is idling, (2) easy time alignment with gas analyzers, and (3) measurement of dry based flow rate that can be directly multiplied by dry based gas concentration to obtain mass emission rate.