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Quantitative planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel-tracer has been used in an optically accessible engine, fueled by direct hydrogen injection. The purpose of this article is to assess the accuracy and precision of the measurement and the associated data reduction procedures. A detailed description of the acetone seeding system is given as well. The key features of the experiment are a high-pressure bubbler saturating the hydrogen fuel with acetone vapor, direct injection into an optical engine, excitation of acetone fluorescence with an Nd:YAG laser at 266 nm, and detection of the resulting fluorescence by an unintensified camera. Key steps in the quantification of the single-shot imaging data are an in-situ calibration and a correction for the effect of local temperature on the fluorescence measurement.

This paper examines the interaction of bulk flow and jet-induced fuel convection in an optically accessible hydrogen-fueled engine with direct injection. Planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel tracer was performed to obtain quantitative images of the hydrogen mole-fraction in the operating engine. With the engine motored, fuel was injected into inert bulk gas from a centrally located injector during the compression stroke. The injector had a single-hole nozzle with the jet angled at 50 degrees with respect to the vertical injector axis. Two parameters were varied in the experiments, injector orientation and tumble intensity, and for each of these, the injection timing was varied. Image series of the mean fuel mole-fraction between injection and near-TDC crank angles capture the mixture-formation process for each configuration and injection timing.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

In an optically accessible single-cylinder engine fueled with hydrogen, acetone planar laser-induced fluorescence (PLIF) and particle image velocimetry (PIV) are used to evaluate in-cylinder mixture formation. The experiments include measurements for engine operation with hydrogen injection in-cylinder either prior to or after intake valve closure (IVC). Pre-IVC injection is used to produce a near-homogeneous mixture for PLIF calibration experiments and to establish a baseline comparison for post-IVC injection. Calibration experiments and a temperature correction allow conversion of the acetone fluorescence signal to equivalence ratio. For post-IVC injection with start of injection (SOI) coincident with IVC, PLIF results are similar to pre-IVC injection. With retard of SOI from IVC, mixture inhomogeneities increase monotonically, with high hydrogen concentration spatially located near the injector and within a smaller volume.

Within the Engine Combustion Network (ECN) spray combustion research frame, simultaneous line-of-sight laser extinction measurements and laser-induced incandescence (LII) imaging were performed to derive the soot volume fraction (fv). Experiments are conducted at engine-relevant high-temperature and high-pressure conditions in a constant-volume pre-combustion type vessel. The target condition, called "Spray A," uses well-defined ambient (900 K, 60 bar, 22.8 kg/m₃, 15% oxygen) and injector conditions (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K). Extinction measurements are used to calibrate LII images for quantitative soot distribution measurements at cross sections intersecting the spray axis. LII images are taken after the start of injection where quasi-stationary combustion is already established.

Mechanisms responsible for enhanced charge reactivity with intake added ozone (O3) were explored in a single-cylinder, optically accessible, research engine configured for low-load advanced compression ignition (ACI) experiments. The influence of O3 concentration (0-40 ppm) on engine performance metrics was evaluated as a function of intake temperature and start of injection for the engine fueled by iso-octane, 1-hexene, or a 5-component gasoline surrogate. For the engine fueled by either the gasoline surrogate or 1-hexene, 25 ppm of added O3 reduced the intake temperature required for stable combustion by 65 and 80°C, respectively. An ultraviolet (UV) light absorption diagnostic was also used to measure crank angle (CA) resolved in-cylinder O3 concentrations for select motored and fired operating conditions. The O3 measurements were compared to results from complementary 0D chemical kinetic simulations that utilized detailed chemistry mechanisms augmented with O3 oxidation chemistry.

Knowledge of the concentration field and flammability envelope from a small-scale hydrogen leak is an issue of importance for the safe use of hydrogen. A combined experimental and modeling program is being carried out by Sandia National Laboratories to characterize and predict the behavior of small-scale hydrogen releases. In contrast to the previous work performed by Sandia on large, momentum-dominated hydrogen leaks, these studies are focusing on small leaks in the Froude number range where both buoyant and inertial forces are important or, in the limit, where buoyancy dominates leak behavior. In the slow leak regime buoyant forces affect the trajectory and rate of air entrainment of the hydrogen jet leak and significant curvature can occur in the jet trajectory. Slow leaks may occur from leaky fittings or o-ring seals on hydrogen vehicles or other hydrogen-based systems where large amounts of pressure drop occur across the leak path.

Sandia National Laboratories has been investigating a new, integrated approach to generating electricity with ultra low emissions and very high efficiency for low power (30 kW) applications such as hybrid vehicles and portable generators. Our approach utilizes a free piston in a double-ended cylinder. Combustion occurs alternately at each cylinder end, with intake/exhaust processes accomplished through a two stroke cycle. A linear alternator is mounted in the center section of the cylinder, serving to both generate useful electrical power and to control the compression ratio by varying the rate of electrical generation. Thus, a mechanically simple geometry results in an electronically controlled variable compression ratio configuration. The capability of the homogeneous charge compression ignition combustion process employed in this engine with regards to reduced emissions and improved thermal efficiency has been investigated using a rapid compression expansion machine.

This paper describes the motivation for developing hydrogen-fueled engines for use in hybrid electric vehicles of the future. The ultimate motivation for using hydrogen as an energy carrier is carbon management. However, air quality concerns also provide motivation for developing hydrogen-fueled vehicles. For this reason, we discuss the position of the hydrogen-powered hybrid vehicle within the California Air Resources Board requirement for Zero Emission Vehicles. We describe the expected performance of an electrical generation system powered by a four-stroke, spark-ignited, internal combustion engine for a hydrogen-powered hybrid vehicle. The data show that the engine-out emissions of NOx will allow the vehicle to operate below the Super Ultra-Low Emission Vehicle standard set by the California Air Resources Board. The engine can run on either hydrogen or blends of hydrogen and natural gas. The engine can be optimized for maximum efficiency with low emissions.

General corrosion protection of sheet materials such as steel used in automobile construction has reached a high level of performance, due primarily to the incorporation of mill-applied treatments such as electrogalvanizing, galvannealing and other coil-coating processes developed over the last half century. While such treatments have greatly extended the corrosion resistance of steel and its various body constructs, attention is now focused on aspects of the manufacturing process wherein these intended protections are compromised by such features as weldments, joins, cut edges and extreme metal deformations such as hems. A novel metal deposition process, based on high-velocity impact fusion of solid metal particles, has been used to extend the corrosion resistance of base steel and pre-galvanized sheet, by selectively placing highly controlled depositions of zinc and other sacrificial materials in close proximity to critical manufacturing details.

The in-cylinder charge motion during the compression stroke of an optically accessible engine equipped with direct injection of hydrogen fuel is measured via particle image velocimetry (PIV). The evolution of the mean flow field and the tumble ratio are examined with and without injection, each with the unmodified 4-valve pent-roof engine head and with the intake ports modified to yield higher tumble. The measurements in the vertical symmetry plane of the cylinder show that intake modification produces the desired drastic increase in tumble flow, changing the tumble ratio at BDC from 0.22 to 0.70. Either intake-induced flow is completely disrupted by the high-pressure hydrogen injection from an angled, centrally located single-hole nozzle. The injection event leads to sudden reversal of the tumble. Hence the tumble ratio is negative after injection. However, the two intake configurations still differ in tumble ratio by about the same magnitude as before injection.

This paper performs a parametric analysis of the influence of numerical grid resolution and turbulence model on jet penetration and mixture formation in a DI-H2 ICE. The cylinder geometry is typical of passenger-car sized spark-ignited engines, with a centrally located single-hole injector nozzle. The simulation includes the intake and exhaust port geometry, in order to account for the actual flow field within the cylinder when injection of hydrogen starts. A reduced geometry is then used to focus on the mixture formation process. The numerically predicted hydrogen mole-fraction fields are compared to experimental data from quantitative laser-based imaging in a corresponding optically accessible engine. In general, the results show that with proper mesh and turbulence settings, remarkable agreement between numerical and experimental data in terms of fuel jet evolution and mixture formation can be achieved.

With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.

A one-dimensional model for crevice HC post-flame oxidation is used to calculate and understand the effect of operating parameters and fuel type (propane and isooctane) on the extent of crevice hydrocarbon and the product distribution in the post flame environment. The calculations show that the main parameters controlling oxidation are: bulk burned gas temperatures, wall temperatures, turbulent diffusivity, and fuel oxidation rates. Calculated extents of oxidation agree well with experimental values, and the sensitivities to operating conditions (wall temperatures, equivalence ratio, fuel type) are reasonably well captured. Whereas the bulk gas temperatures largely determine the extent of oxidation, the hydrocarbon product distribution is not very much affected by the burned gas temperatures, but mostly by diffusion rates. Uncertainties in both turbulent diffusion rates as well as in mechanisms are an important factor limiting the predictive capabilities of the model.

Unlike other gases, hydrogen can promote embrittlement of structural metals at ambient temperature. The effects of high-pressure hydrogen gas on structural metals vary significantly depending on material, environmental, and mechanical variables as well as the metric used to evaluate performance. In this short review, we provide basic guidance on selection of materials for hydrogen gas service emphasizing the need for performing tests in relevant environments and using appropriate methods. Fracture mechanics and fitness-for-service type design approaches are highly recommended for ensuring robust yet efficient high-pressure designs for hydrogen gas service.