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The influence of charge-gas dilution and cooling on incylinder combustion processes and engine-out smoke and NOx emissions was experimentally investigated in an optically accessible heavy-duty diesel engine using diethylene glycol diethyl ether (DGE) fuel, a viable diesel oxygenate. In-cylinder pressure and natural luminosity were measured simultaneously with engine-out smoke and NOx while varying the temperature, density, and nitrogen dilution of the charge gas; the quantity of fuel injected; and the injection timing. Measurements obtained using DGE at a reduced charge-gas temperature and with nitrogen dilution were compared to measurements obtained at typical diesel operating conditions using DGE and using a diesel reference fuel.