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A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

The use of fuel additives is one possible approach to reduce wear and corrosion in methanol fueled automobile engines. One hundred and six compounds added to M100 fuel in modest concentrations (1%) were tested in a Ball on Cylinder Machine (BOCM) for their ability to improve lubricity. The most promising candidates were then tested in an engine using a modified ASTM Sequence V-D wear screening test. Additive performance was measured by comparing the buildup of wear metals in the oil to that obtained from an engine fueled with neat M100. The BOCM method of evaluating the additive candidates proved inadequate in predicting abrasive engine wear under the test conditions utilized for this research program.

For NASA's Constellation Program, an Intravehicular Activity (IVA) and Extravehicular Activity (EVA) Life Support Umbilical System (LSUS) will be required to provide environmental protection to the suited crew during Crew Exploration Vehicle (CEV) cabin contamination or depressurization and contingency EVAs. The LSUS will provide the crewmember with ventilation, cooling, power, communication, and data, and will also serve as a crew safety restraint during contingency EVAs. The LSUS will interface with the Vehicle Interface Assembly (VIA) in the CEV and the Suit Connector on the suit. This paper describes the effort performed to develop concept designs for IVA and EVA umbilicals, universal multiple connectors, handling aids and stowage systems, and VIAs that meet NASA's mission needs while adhering to the important guiding principles of simplicity, reliability, and operability.

The International Space Station (ISS) program is nearing an assembly complete configuration with the addition of the final resource node module in early 2010. The Node 3 module will provide critical functionality in support of permanent long duration crews aboard ISS. The new module will permanently house the regenerative Environment Control and Life Support Systems (ECLSS) and will also provide important habitability functions such as waste management and exercise facilities. The ISS program has selected the Port side of the Node 1 “Unity” module as the permanent location for Node 3 which will necessitate architecture changes to provide the required interfaces. The USOS ECLSS fluid and ventilation systems, Internal Thermal Control Systems, and Avionics Systems require significant modifications in order to support Node 3 interfaces at the Node 1 Port location since it was not initially designed for that configuration.

Engine tests are widely used to measure the ability of lubricating oils to reduce fuel consumption through improved mechanical efficiency. Previous publications have correlated laboratory-scale tests with the well-established Sequence VI and VIA engine methods. The present paper uses a matrix of 66 oils to produce an empirical model for the recently developed Sequence VIB engine test. A smaller matrix of oils was available for correlation with Sequence VI and VIA results. The models combine a purposely-designed friction test with conventional measures of kinematic and high-temperature high-shear viscosity. Good correlation was obtained with the Sequence VI, VIA and VIB results, as well as each of the five stages in the Sequence VIB test. The effects of lubricant oxidation in the 96-hour FEI-2 portion of the Sequence VIB test were similar for each of the oils. As a result, good correlation was observed between FEI-1 and FEI-2 results from the VIB test.

The International Space Station (ISS) Active Thermal Control System (ATCS) (Ref. 1,2) has changed over the past several years to address problems and to improve its assembly and operation on-orbit. This paper captures the ways in which the Internal (I) ATCS and External (E) ATCS have changed design characteristics and operations both for the system currently operating on-orbit and the new elements of the system that are about to be added and/or activated. The rationale for changes in ATCS design, assembly and operation will provide insights into the lessons learned during ATCS development. The state of the assembly of the integrated ATCS will be presented to provide a status of the build-up of the system. The capabilities of the on-orbit system will be presented with a summary of the elements of the ISS ATCS that are functional on-orbit plus the plans for launch of remaining parts of the integrated ISS ATCS.

Biological water processors are currently being developed for application in microgravity environments. Work has been performed to develop a single-phase, gravity independent anoxic denitrification reactor for organic carbon removal [1]. As a follow on to this work it was necessary to develop a gravity independent nitrification reactor in order to provide sufficient nitrite and nitrate to the organic carbon oxidation reactor for the complete removal of organic carbon. One approach for providing the significant amounts of dissolved oxygen required for nitrification is to require the biological reactor design to process two-phase gas and liquid in micro-gravity. This paper addresses the design and test results overview for development of a tubular, two-phase, gravity independent nitrification biological water processor.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

Since the early 1980’s, the Shuttle Extra Vehicular Activity (EVA) glove design has evolved to meet the challenge of space based tasks. These tasks have typically been satellite retrieval and repair or EVA based flight experiments. With the start of the International Space Station (ISS) assembly, the number of EVA based missions is increasing far beyond what has been required in the past; this has commonly been referred to as the “Wall of EVA’s”. To meet this challenge, it was determined that the evolution of the current glove design would not meet future mission objectives. Instead, a revolution in glove design was needed to create a high performance tool that would effectively increase crewmember mission efficiency. The results of this effort have led to the design, certification and implementation of the Phase VI EVA glove into the Shuttle flight program.

In preparation for future planetary exploration, the Bioregenerative Planetary Life Support Systems Test Complex (BIO-Plex) is currently being built at the NASA Johnson Space Center. The BIO-Plex facility will allow for closed chamber Earth-based tests. Various prepackaged food systems are being considered for the first 120-day BIO-Plex test. These food systems will be based on the Shuttle Training Menu and the International Space Station (ISS) Assembly Complete food systems. This paper evaluates several prepackaged food system options for the surface portion of an early Mars mission, based on plans for the first BIO-Plex test. The five systems considered are listed in Table 1. The food system options are assessed using equivalent system mass (ESM), which evaluates each option based upon the mass, volume, power, cooling and crewtime requirements.

The current operation of the International Space Station (ISS) calls for the oxygen used by the occupants to be vented overboard in the form of CO2, after the CO2 is scrubbed from the cabin air. Likewise, H2 produced via electrolysis in the oxygen generator is also vented. NASA is investigating the use of the Sabatier process to combine these two product streams to form water and methane. The water is then used in the oxygen generator, thereby conserving this valuable resource. One of the technical challenges to developing the Sabatier reactor is transferring CO2 from the Carbon Dioxide Removal Assembly (CDRA) to the Sabatier reactor at the required rate, even though the CDRA and the Sabatier reactor operate on different schedules. One possible way to transfer and store CO2 is to use a mechanical compressor and a storage tank.

This paper provides an overview of the IMMWPS Integrated Ground Test Program, completed at the NASA Johnson Space Center (JSC) during October and November 2001. The JSC Crew and Thermal Systems Division (CTSD) has developed the IMMWPS orbital flight experiment to test the feasibility of a microbe-based water purifier for use in zero-gravity conditions. The IMMWPS design utilizes a Microbial Processor Assembly (MPA) inoculated with facultative anaerobes to convert organic contaminants in wastewater to carbon dioxide and biomass. The primary purpose of the ground test program was to verify functional operations and procedures. A secondary objective was to provide initial ground data for later comparison to on-orbit performance. This paper provides a description of the overall test program, including the test article hardware and the test sequence performed to simulate the anticipated space flight test program. In addition, a summary of significant results from the testing is provided.

Atmospheric corrosion of steels, aluminum alloys, and Al-clad aluminum alloys is a problem for many civil engineering structures, commercial and military vehicles, and aircraft. Paint is usually the primary means to prevent the corrosion of steel bridge components, automobiles, trucks, and aircraft. Under ideal conditions, the coating provides a continuous layer that is impervious to moisture. At present, maintenance cycles for commercial and military aircraft and ground vehicles, as well as engineered structures, is based on experience and appearance rather than a quantitative determination of coating integrity. To improve the maintenance process and reduce costs, sensors are often used to monitor corrosion. The present suite of sensors designed to detect corrosion and marketed to predict the lifetime of the engineered components, however, are not useful for determining the condition of the protective paint coatings.

Exhaust emissions of non-methane hydrocarbon (NMHC) and methane were measured from a Tier 3 dual-fuel demonstration locomotive running diesel-natural gas blend. Measurements were performed with the typical flame ionization detector (FID) method in accordance with EPA CFR Title 40 Part 1065 and with an alternative Fourier-Transform Infrared (FTIR) Spectroscopy method. Measurements were performed with and without oxidation catalyst exhaust aftertreatment. FTIR may have potential for improved accuracy over the FID when NMHC is dominated by light hydrocarbons. In the dual fuel tests, the FTIR measurement was 1-4% higher than the FID measurement of. NMHC results between the two methods differed considerably, in some cases reporting concentrations as much as four times those of the FID. However, in comparing these data it is important to note that the FTIR method has several advantages over the FID method, so the differences do not necessarily represent error in the FTIR.

The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.

The Flash Evaporator Subsystem (FES) provides active cooling for the Shuttle Orbiter vehicle during the ascent and re-entry phases of the flight and provides supplemental cooling to the radiators while on-orbit. This paper describes the design and operation of the FES and summarizes the operational flight experience to date. As the fleet of orbiters grows older, contamination and corrosion are two issues on which attention has focused. A discussion of these conditions and the subsequent design changes and operational workarounds will be summarized.

Supply of oxygen (O2) and hydrogen (H2) by electrolyzing water in space will play an important role in meeting the National Aeronautics and Space Administration's (NASA's) needs and goals for future space missions. Both O2 and H2 are envisioned to be used in a variety of processes including crew life support, spacecraft propulsion, extravehicular activity, electrical power generation/storage as well as in scientific experiment and manufacturing processes. Life Systems, Inc., in conjunction with NASA, has been developing an alkaline-based Static Feed Electrolyzer (SFE). During the development of the water electrolysis technology over the past 23 years, an extensive engineering and scientific data base has been assembled.

Two simulated spacecraft water systems are being used to evaluate the effectiveness of iodine for controlling microbial contamination within such systems. An iodine concentration of about 2.0 mg/L is maintained in one system by passing ultrapure water through an iodinated ion exchange resin. Stainless steel coupons with electropolished and mechanically-polished sides are being used to monitor biofilm formation. Results after three years of operation show a single episode of significant bacterial growth in the iodinated system when the iodine level dropped to 1.9 mg/L. This growth was apparently controlled by replacing the iodinated ion exchange resin, thereby increasing the iodine level. The second batch of resin has remained effective in controlling microbial growth down to an iodine level of 1.0 mg/L. Scanning electron microscopy indicates that the iodine has impeded but may have not completely eliminated the formation of biofilm.

Among the many firsts which will occur on STS-49, the maiden voyage of the Space Shuttle Endeavour, a Space Station Freedom (SSF) experiment entitled Assembly of Station by Extravehicular Activity (EVA) Methods (ASEM) promises to test the boundaries of EVA operational capabilities. Should the results be favorable, station and other major users of EVA stand to benefit from increased capabilities. Even the preparation for the ASEM experiment is serving as a pathfinder for complex SSF operations. This paper reviews the major tasks planned for ASEM and discusses the operational analogies investigators are attempting to draw between ASEM and SSF. How these findings may be applied to simplify station assembly and maintenance will also be discussed.

This paper describes the development and evaluation of an operative catalyst for the reduction of NOx in lean exhaust. A catalyst that incorporates iron (II)-complex impregnated modified mesoporous molecular sieves (MCM-41) has been synthesized and further treated with [pd(NH3)4]Cl2 [1]. Experimental results suggest a hydrocarbon-independent reduction of NOx takes place on the iron center, and oxidation of CO is assisted by the palladium ion. The catalytic activity toward HC CO, and NOx removal was studied with simulated and real engine exhaust in the laboratory and on an engine, respectively. Engine test results demonstrate a reduction of NOx of up to 10 percent at catalyst inlet temperatures in the range of 260°C to 280°C. In this paper, possible NOx reduction pathways are also discussed.