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Battery Electric Vehicles and Extended Range Electric Vehicles, like the Chevrolet Volt, can use electrical energy from the Grid to meet the majority of a driver�s transportation needs. This has the positive societal effects of displace petroleum consumption and associated pollutants from combustion on a well to wheels basis, as well as reduced energy costs for the driver. CO2 may also be lower, but this depends upon the nature of the grid energy generation. There is a mix of sources � coal-fired, gas -fired, nuclear or renewables, like hydro, solar, wind or biomass for grid electrical energy. This mix changes by region, and also on the weather and time of day. By monitoring the grid mix and communicating it to drivers (or to their vehicles) in real-time, electrically driven vehicles may be recharged to take advantage of the lowest CO2, and potentially lower cost charging opportunities.

Emissions of nitrogen oxides (NOx) from heavy-duty diesel engines are subject to more stringent environmental legislation. Selective catalytic reduction (SCR) over metal ion-exchanged zeolites is in this connection an efficient method to reduce NOx. Understanding durability of the SCR catalyst is crucial for correct design of the aftertreatment system. In the present paper, thermal and chemical ageing of Fe-BEA as NH3-SCR catalyst is studied. Experimental results of hydrothermal ageing, and chemical ageing due to phosphorous and potassium exposure are presented. The catalyst is characterized by flow reactor experiments, nitrogen physisorption, DRIFTS, XRD, and XPS. Based on the experimental results, a multisite kinetic model is developed to describe the activity of the fresh Fe-BEA catalyst.

The interaction between a combusting diesel spray and a wall was studied by measuring the spray flame temperature time and spatially resolved. The influence of injection sequences, injection pressure and gas conditions on the heat transfer between the combusting spray and the wall was investigated by measuring the flame temperature during the complete injection event. The flame temperature was measured by an emission based optical method and determined by comparing the relative emission intensities from the soot in the flame at two wavelength intervals. The measurements were done by employing a monochromatic and non intensified high speed camera, an array of mirrors, interference filters and a beam splitter. The studies were carried out in the Chalmers High Pressure High Temperature (HP/HT) spray rig at conditions similar to those prevailing in a direct injected diesel engine prior to the injection of fuel.

A model of premixed turbulent combustion is modified for multi-dimensional computations of SI engines. This approach is based on the use of turbulent flame speed in order to suggest a closed balance equation for the mean combustion progress variable. The model includes a single unknown input parameter to be tuned. This model is tested against two sets of experimental data obtained by Bradley et al [17, 18 and 19] and Karpov and Severin [15] in fan-stirred bombs. The model quantitatively predicts the development of the turbulent flame speed, the effects of the initial pressure, temperature, and mixture composition on the turbulent flame speed, and the effects of r.m.s. turbulent velocity and burning mixture composition on the rate of the pressure rise. These results were computed with the same value of the aforementioned unknown input parameter of the model.

Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

Analysis of spray-wall interaction is a major issue in the study of the combustion process in DI diesel engines. Along with spray characteristics, the investigation of impinging sprays and of liquid wall film development is fundamental for predicting the mixture formation. Simulations of these phenomena for diesel sprays need to be validated and improved; nevertheless they can extend and complement experimental measurements. In this paper the wall film thickness for impinging sprays was investigated by evaluating the heat transfer across a temperature controlled wall. In fact, heat transfer is significantly affected by the wall film thickness, and both experiments and simulations were carried out to correlate the wall temperature variations and film height. The numerical simulations were carried out using the STAR-CD and the KIVA-3V, rel. 2, codes.

The effect of ammoniac deoxidizing agent (Urea) on the reduction of NOx produced in the Diesel engine was investigated numerically. Urea desolved in water was directly injected into the engine cylinder during the expansion stroke. The NOx deoxidizing process was described using a simplified chemical kinetic model coupled with the comprehensive kinetics of Diesel oil surrogate combustion. If the technology of DWI (Direct Water Injection) with the later injection timing is supposed to be used, the deoxidizing reactants could be delivered in a controlled amount directly into the flame plume zones, where NOx are forming. Numerical simulations for the Isotta Fraschini DI Diesel engine are carried out using the KIVA-3V code, modified to account for the “co-fuel” injection and reaction with combustion products. The results showed that the amount of NOx could be substantially reduced up to 80% with the injection timing and the fraction of Urea in the solution optimized.

The emissions from a direct injection diesel engine measured according to the ECE R49 13-mode cycle and as a function of exhaust gas recirculation are compared for diesel fuel without water addition, and for water-in-diesel as emulsion and microemulsion. The effect of water addition on the soot emissions was remarkably strong for both the emulsion and microemulsion fuels. The average weighted soot emission values for the 13-mode cycle were 0.0024 and 0.0023 g/kWh for the two most interesting emulsion and microemulsion fuels tested, respectively; 5-fold lower than the US 2007 emission limit.

In order to acquire knowledge about temperature vs. equivalence ratio, T-ϕ, conditions in which emissions are formed and destroyed, T-ϕ parametric maps were constructed for: 1 Soot and soot precursors (C2H2) 2 Nitrogen oxides (NO and NO2) 3 Unburnt intermediates (CH2O, H2 and CO) 4 Important radicals (HO2 and OH) Each map was obtained by plotting data from a large number of simulations for various T-ϕ combinations in a zero-dimensional, 0D, closed Perfectly Stirred Reactor, PSR. Initially, the influences of elapsed reaction time, pressure and EGR level were examined, varying one parameter at a time. Then, since both the elapsed time and pressure change in an engine cycle, the maps were constructed according to engine pressure traces obtained from Computational Fluid Dynamics, CFD, simulations. Since the pressure is changing in elapsed time intervals the maps are called transient.

In order to meet future emissions legislation for Diesel engines and reduce their CO2 emissions it is necessary to improve diesel combustion by reducing the emissions it generates, while maintaining high efficiency and low fuel consumption. Advanced injection strategies offer possible ways to improve the trade-offs between NOx, PM and fuel consumption. In particular, use of high EGR levels (⥸ 40%) together with multiple injection strategies provides possibilities to reduce both engine-out NOx and soot emissions. Comparisons of optical engine measurements with CFD simulations enable detailed analysis of such combustion concepts. Thus, CFD simulations are important aids to understanding combustion phenomena, but the models used need to be able to model cases with advanced injection strategies.

Optical studies of combusting diesel sprays were done on three different alternative liquid fuels and compared to Swedish environmental class 1 diesel fuel (MK1). The alternative fuels were Rapeseed Oil Methyl Ester (RME), Palm Oil Methyl Ester (PME) and Fischer-Tropsch (FT) fuel. The studies were carried out in the Chalmers High Pressure High Temperature spray rig under conditions similar to those prevailing in a direct-injected diesel engine prior to injection. High speed shadowgraphs were acquired to measure the penetration of the continuous liquid phase, droplets and ligaments, and vapor penetration. Flame temperatures and relative soot concentrations were measured by emission based, line-of-sight, optical methods. A comparison between previous engine tests and spray rig experiments was conducted in order to provide a deeper explanation of the combustion phenomena in the engine tests.

During the development of the aerodynamic properties of fore coming road vehicles down scaled models are often used in the initial phase. However, if scale models are to be utilised even further in the aerodynamic development they have to include geometrical representatives of most of the components found in the real vehicle. As the cooling package is one of the biggest single generators of aerodynamic drag the heat exchangers are essential to include in a wind tunnel model. However, due mainly to limitations in manufacturing techniques it is complicated to make a down scaled heat exchanger and instead functional dummy heat exchangers have to be developed for scaled wind tunnel models. In this work a Computational Fluid Dynamics (CFD) code has been used to show that it is important that the simplified heat exchanger model has to be of comparable size to that of the full scale unit.

The expansion of current driving cycles for emission regulations to higher load operation in the near future (such as the US06 supplement to the FTP-75 driving cycle) requires attention to low emission combustion concepts in medium to high load regimes. One possibility to reduce NO emissions is to increase the EGR rate. The combustion-temperature reducing effects of high EGR rates can significantly reduce NO formation, to the point where engine-out NOx emissions approach zero levels. However, engine-out soot and CO emissions typically increase at high EGR levels, due to the reduced soot and CO oxidation rates at reduced combustion temperatures and oxygen concentrations. The work presented in this paper focuses on different strategies to reduce soot and CO emissions associated with EGR rates of up to 50%, at which NO formation is largely avoided, but combustion temperatures are not low enough to consider the process as Low-Temperature Combustion (LTC).

The CFD model, based on the LANL KIVA-3 computer code, modified to account for the multi-step dimethyl ether, DME/air, oxidation chemistry, was developed and used to study the neat DME combustion dynamics in a constant volume at Diesel-like conditions and in the Volvo AH10A245DI Diesel engine. Constant volume simulations confirm high ignition quality of neat DME in air. The results of engine modeling illustrate that the injection schedule used for Diesel fuel is not optimal for DME. Surprisingly, the positive gain and peak pressure levels comparable with those for Diesel fuel were obtained using an early (∼ -20 ATDC) injection through a nozzle of a larger diameter at reduced injection pressures and velocities (∼150m/s) preventing too rapid spray atomization. At these conditions, combustion heat release has a specific two-stage character with a peak value placed behind the TDC.

An expanding cylindrical laminar flame kernel affected by random external strain rates and diffusivity is numerically simulated in order to gain insight into the influence of small-scale turbulence on the combustion variability in engines. In the simulations, the kernel is strained, as a whole, by external velocity gradients randomly generated with either Gaussian or log-normal probability density functions. The influence of small-scale turbulent heat and mass transfer is modeled by turbulent diffusivity, the randomness of which is controlled by the fluctuations in the viscous dissipation averaged over the kernel volume. The computed results show that small-scale phenomena can substantially affect the quenching characteristics of a small flame kernel and the kernel growth history rj(t); the scatter of the computed curves of rf(t) being mainly controlled by the scatter of the duration of the initial stage of kernel development.

Wall wetting can occur irrespective of combustion concept in diesel engines, e.g. during the compression stroke. This action has been related to engine-out emissions in different ways, and an experimental investigation of impinging diesel sprays is thus made for a standard diesel fuel and a two-component model fuel (IDEA). The experiment was performed at conditions corresponding to those found during the compression stroke in a heavy duty diesel engine. The spray characteristics of two fuels were measured using two different optical methods: a Phase Doppler Particle Analyzer (PDPA) and high-speed imaging. A temperature controlled wall equipped with rapid, coaxial thermocouples was used to record the change in surface temperature from the heat transfer of the impinging sprays.

This paper describes an analysis of the Diesel Oil Surrogate (DOS) model used at Chalmers University (Sweden), including 70 species participating in 310 reactions, and subsequent improvements prompted by the model's systematic tendency to under-predict the combustion intensity in simulations of kinetically-driven combustion modes, e.g. Homogeneous Charged Compression Ignition (HCCI). Key bases of the model are the properties of a model Diesel fuel with the molecular formula C14H28. In the vapor phase, a global reaction decomposes the starting fuel, C14H28, into its constituent components; n-heptane (C7H16) and toluene (C7H8). This global reaction was modified to yield a higher n-heptane:toluene ratio, due to the importance of preserving an n-heptane-like cetane number.

It has been previously shown that engine-out soot emissions can be reduced by using Fischer-Tropsch (FT) fuels, due to their lack of aromatics, compared to conventional Diesel fuels. In this investigation the engine-out emissions and fuel consumption parameters of an FT fuel derived from natural gas were compared to those of Swedish low sulfur diesel (MK1) when used in Low Temperature Combustion mode in a single cylinder heavy-duty diesel engine. The effects of varying Needle Opening Pressure (NOP), Charge Air Pressure (CAP) and Exhaust Gas Recirculation (EGR) according to an experimental design on the measured variables were also assessed. CAP and EGR were found to be the most significant factors for the combustion and emission parameters of both fuels. Increases in CAP resulted in lower soot emissions due to enhanced charge mixing, however NOx emissions rose as CAP increased.

Soot formation and oxidation are complex and competing processes during diesel combustion. The balance between the two processes and their history determines engine-out soot values. Besides the efforts to lower soot formation with measures to influence the flame lift-off distance for example or to use HCCI-combustion, enhancement of late soot oxidation is of equal importance for low-λ diffusion-controlled low emissions combustion with EGR. The purpose of this study is to investigate soot oxidation in a heavy duty diesel engine by statistical analysis of engine data and in-cylinder endoscopic high speed photography together with CFD simulations with a main focus on large scale in-cylinder gas motion. Results from CFD simulations using a detailed soot model were used to reveal details about the soot oxidation.

The purpose of the investigation presented here was to compare the effects of fuel composition on combustion parameters, emissions and fuel consumption in engine tests and simulations with five fuels: a Diesel-water emulsion, a Diesel-ethanol blend, a Diesel-ethanol blend with EHN (cetane number improver), a Fischer-Tropsch Diesel and an ultra-low sulfur content Diesel. The engine used in the experiments was a light duty, single cylinder, direct injection, common rail Diesel engine equipped with a cylinder head and piston from a Volvo NED5 engine. In tests with each fuel the engine was operated at two load points (3 bar IMEP and 10 bar IMEP), and a pilot-main fuel injection strategy was applied under both load conditions. Data were also obtained from 3-D CFD simulations, using the KIVA code, to compare to the experimental results and to further analyze the effects of water and ethanol on combustion.