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A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.

In a state-of-the-art lean-burn spark ignition engine, a strong in-cylinder flow field with enhanced turbulence intensity is formed, and understanding the wall heat transfer mechanism of such a complex flow is required. The flow velocity and temperature profiles inside the wall boundary layer are strongly related to the heat transfer mechanism. In this study, two-dimensional three-component (2D3C) velocity distribution near the piston top surface was measured during the compression stroke in a strong tumble flow using a rapid compression and expansion machine (RCEM) and a stereoscopic micro-PIV system. The bore, stroke, compression ratio, and compression time were 75 mm, 128 mm, 15, and 30 ms (equivalent to 1000 rpm), respectively.

In order to investigate the mechanism of heat transfer on the chamber wall of direct-injection diesel engines, 2-D temperature imaging and heat flux measurement in the flame impinging region on the chamber wall were conducted using laser-induced phosphorescence technique. The temperature of the chamber wall surface was measured by the calibrated intensity variation of the 355nm-excited laser-induced phosphorescence from an electrophoretically deposited thin layer of La2O2S:Eu phosphor on a quartz glass plate placed in a rapid compression and expansion machine (RCEM). Instantaneous 2-D images of wall temperature at different timings after start of injection and time-resolved (10kHz) heat flux near the flame impinging region were obtained for combusting and non-combusting diesel sprays with impinging distance of 23.4mm at different injection pressures (80 and 120MPa).

In this study, the combustion characteristics of diesel flame achieved in a rapid compression and expansion machine (RCEM) at various patterns of oxygen distribution in the chamber are investigated in order to clarify the effect of heterogeneity of oxygen distribution in diesel engines induced by EGR on the soot and NOx emissions. To make the heterogeneous distribution of oxygen in a combustion chamber, the mixtures with different oxygen concentrations are injected through the each different port located on the cylinder wall. Results indicate that the amount of oxygen entrained into the spray upstream the luminous flame region affects the NO emission from diesel flame strongly.

Measurements of Excitation-Emission Matrix (EEM) of shock-heated vapors of polycyclic aromatic hydrocarbons (PAHs) at high temperature (750-1500K) and high pressure (0.3-1.3MPa) conditions were conducted using a multi-wavelength excitation laser in order to demonstrate the potential of the single-measurement EEM fluorometry for investigation of soot precursors. Argon-diluted vapors of naphthalene and pyrene, as PAH model compounds, were heated in an optically accessible shock tube. The PAH vapors were excited by a coherent multi-wavelength “rainbow” laser light generated by converting the 4th harmonic (266nm) of a pulsed Nd:YAG laser using a Raman cell frequency converter filled with high-pressure (2MPa) methane-hydrogen mixture.

The relation between the characteristics of a non-evaporating spray and those of a corresponding frame achieved in a rapid compression machine was investigated experimentally. The fuel injection pressure was changed in a range of 55 to 260 MPa and the other injection parameters such as orifice diameter and injection duration were changed systematically. The characteristics of the non-evaporating spray such as the Sauter mean diameter and the mean excess air ratio of the spray were measured by an image analysis technique. The time required for a pressure rise due to combustion was taken as an index to characterize the flame. It was concluded that the mean excess air ratio of a spray is the major factor which controls the burning rate and that the high injection pressure is effective in shortening the combustion duration and reducing soot formation.

The two-dimensional distribution of a soot cloud in an unsteady spray flame in a rapid compression machine(RCM) was visualized using the laser sheet scattering technique. A 40 mm x 50 mm cross section on the flame axis was illuminated by a thin laser sheet from a single pulsed Nd:YAG laser(wavelength 532 nm). Scattered light from soot particles was taken by a CCD camera via a high speed gated image intensifier. The temporal variation of the scattered light images were presented with the injection pressure as a parameter. The results showed that scattered light was intense near the periphery of the flame tip and that the scattered light becomes weaker significantly and disappears fast after the end of injection as injection pressure is increased. This technique was also applied to the visualization of the two-dimensional distribution of liquid droplets in the non-evaporating spray to correlate it with the soot concentration distribution.

The structure of dense sprays was investigated using 2-D imaging techniques. To investigate the mechanism of atomization, the liquid phase in a non-evaporating spray was visualized by a thin laser sheet formed by a single pulse from a Nd:YAG laser at the distance from 4 to 19 mm from the nozzle orifice with the injection pressure and the surrounding gas density as parameters. A new technique for the visualization of vapor phase in an evaporating spray, the SSI (Silicone particle Scattering Imaging) method, was proposed to investigate the structure of the vapor phase regions of the spray.

In order to investigate the combustion phenomena in a combustion chamber of the diesel engine at transient operations, the simultaneous measurements of temperatures of flame and wall surface in a combustion chamber were conducted. The new technique for simultaneous measurements of flame temperature and wall surface was developed. Laser-Induced phosphorescence was used for the measurement of wall surface temperature which was coupled with the flame temperature measurement by a two-color pyrometry. The NOx and soot emissions were also measured simultaneously in transient operations. The relation between the temporal changes of emissions and temperatures of flame and surface wall are discussed. The results show that the temporal change of NOx emission during transient operation is similar to that of the average gas temperature in a chamber. On the other hand, the temporal change of soot emission is similar to neither that of flame temperature nor that of average gas temperature.

To understand further the mixing process between the injected fuel and air in the combustion chamber of a diesel engine, the turbulent mixing process in a one-phase, two-dimensional transient jet was theoretically studied using the discrete vortex simulation. First, the simulation model was evaluated by comparisons between calculated and experimental data on two-dimensional turbulent jets. Second, the trajectories of the injected fluid elements marked with different colors were graphically demonstrated. Also the process of entrainment of the surrounding fluid into the jet was visually presented using colored tracers.

To measure the fuel vapor concentration in an unsteady evaporating spray injected into nitrogen atmosphere, the exciplex-forming method, which produces spectrally separated fluorescence from the liquid and vapor phase, was applied in this study. Two experiments were conducted to investigate the qualitative and quantitative applicability of the technique in a high temperature and high pressure atmosphere during the fuel injection period. One is to examine the thermal decomposition of TMPD dopant at a high temperature and a high pressure nitrogen atmosphere during a short period of time. The other is to calibrate the relationship between fluorescence intensity and vapor concentration of TMPD at different vapor temperatures. And then, the qualitative measurement of fuel vapor concentration distributions in diesel sprays was made by applying the technique.

Local heat flux from the flame to the combustion chamber wall, q̇, was measured the wall surfaces of a rapid compression-expansion machine which can simulate diesel combustion. Temperature of the flame zone, T1, was calculated by a thermodynamic two-zone model using measured values of cylinder pressure and flame volume. A local heat transfer coefficient was proposed which is defined as q̇/(T1-Tw). Experiments showed that the local heat transfer coefficient depends slightly on the temperature difference, T1-Tw, but depends significantly on the velocity of the flame which contacts the wall surface.

Soot concentration is very high in the periphery near the head of an unsteady spray flame which is achieved in a quiescent atmosphere in a rapid compression machine. To reduce soot concentration in this region, it was intended to improve fuel-air mixing by letting the flame impinge on a turbulence-generating plate. Two types of turbulence-generating plates, one donut-type, the other cross-type, were tested. Soot concentration in the flame was imaged using the laser shadow technique. The effect of injection pressure on soot reduction by the flame impingement was also investigated. The overall soot concentration is reduced significantly in the case when the flame impinges on the cross-type turbulence-generating plate at 50 mm (333 nozzle diameters) from the nozzle exit. The flame impingement on the cross-type turbulence-generating plate at 333 nozzle diameters makes soot reduction little dependent on injection pressures.

Air-entrainment characteristics of non-evaporating sprays and flames were measured by means of high-speed photography including ordinary shadowgraphy of sprays, back diffused light illumination photography and laser shadow photography of flames. Effects of injection pressure and nozzle orifice diameter on air-entrainment characteristics were investigated parametrically. The amount of air entrained into a flame was calculated by a two-zone thermodynamic model with data obtained from the photographs and the pressure measurement in the combustion chamber. The air-entrainment characteristics of flames were compared with those of the corresponding sprays. It showed that immediately after the start of ignition, the air entrainment into a flame increased more rapidly as compared with the corresponding spray and then, with the development of diffusion combustion, the air entrainment gradually approached that of the spray.

A new method to determine simultaneously the temperature and the fuel vapor concentration inside an evaporating spray was described by using a laser-induced fluorescence technique. A TMPD doped base fuel composed of C12H26: 22%, C13H28: 54% and C14H30: 30% was injected into the combustion chamber of a rapid compression machine which is filled with a high temperature and high pressure nitrogen. The laser sheet was used for incident light, which was reflected by a prism located inside the combustion chamber and propagated through the center of an evaporating spray. The laser induced fluorescence intensity was imaged by a high speed-gated intensifier from a direction perpendicular to the incident light. The results shows that mixtures with high equivalence ratio are observed in the central region, while low equivalence ratio mixtures are observed in the periphery of the spray. It is also observed that the temperature of richest mixture is 50 K as low as the surrounding gas temperature.

A rapid compression-expansion machine was developed, which can simulate intake, compression, expansion and exhaust strokes in a single Diesel cycle by an electrically controlled and hydraulically actuated driving system. The whole system which is composed of a hydraulic actuator, fuel injector and a valve driving device, is sequentially controlled by a micro-computer. The machine features; 1) accurate control of piston position at TDC, 2) no effect of lubricant on HC emission due to the use of dry piston rings; 3) independent control of local wall temperature; and 4) high power output to drive heavy piston at high frequency. The single cycle operation permits Diesel combustion experiments under a wide range of operating conditions and easy access of optical diagnostics with minimized amount of test fuel. The performance test showed that the machine can drive a DI Diesel type piston with a 100 mm bore at a maximum frequency of 16.7 Hz at a maximum compression pressure of 15 MPa.

In an attempt to achieve lean combustion in Diesel engines which has a potential for simultaneous reduction in no and soot, the authors developed a micro-hole nozzle which has orifices with a diameter as small as 0.06 mm. Combustion tests were carried out using a rapid compression-expansion machine which has a DI Diesel type combustion chamber equipped with the micro-hole nozzle. A comparison with the result of a conventional nozzle experiment revealed that the ignition delay was shortened by 30 %, and in spite of that, both peaks of initial premixed combustion and diffusion combustion increased significantly. The combustion in the case of the micro-hole nozzle experiment was accompanied with a decrease in soot emission, whereas an increase in NO emission.

The local heat fluxes from impinging combusting and evaporating diesel sprays to the wall of a square combustion chamber were measured in a rapid compression machine. It was revealed that the ratio of local heat flux between the combusting and evaporating spray, q̇c/q̇e, is of the same order of magnitude as (Tc-Tw)/(Te-Tw) and its values estimated by a two-zone model agree roughly with the measured ones. The time-mean local heat flux during the spray impingement was found to be approximately proportional to the 0.8th power of the injection velocity and the heat-transfer phenomenon depends largely on whether the ignition starts before or after the impingement.

A one-dimensional numerical calculation has been performed on a new reciprocating heat engine proposed on the basis of super-adiabatic combustion in porous media. The system consists of two pistons and a thin porous medium in a cylinder; one being a displacer piston and the other a power piston. These create reciprocating motions with a phase relation angle. By means of the reciprocating flow system, the residual combustion gas enthalpy is effectively regenerated to induce enthalpy increase in the mixture through the porous medium. Due to heat recirculation, the thermal efficiency reaches to 58% under the condition of the compression ratio of 2.3.

The influence of the head shape on intracranial responses under impact was investigated by using Finite Element Method. Head shape models of 52 young adult male Japanese were analyzed by Multi Dimensional Scaling (MDS), and a 2 dimensional distribution map of head shapes was obtained. Five finite element models of the Japanese head were constructed by a transformed finite element model of an average European adult male (H-Head model) using Free Form Deformation (FFD) technique. The constructed models represent the 5th and 95th percentile of the first 2 scales obtained by MDS. The same acceleration pulse was applied to the H-Head model and the five finite element models. The cause of the difference was considered to be differences in pressure distribution in the brain caused by the differences in the head shape. Variation in the head shape should be taken into account in simulating the effects of impact using a finite element model.