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The effect of phosphorus concentration in gasoline engine oils on the valve train wear was experimentally investigated by using the JASO M328-91 3A valve train wear (3A-VTW) test method. The phosphorus concentration is determined proportionally to the amount of zinc dithiophosphate (ZDDP), which is formulated as both antiwear agent and antioxidant. Lower concentrations of ZDDP generally bring about larger wear in the valve train. However, it was found from the experiments that valve train wear remained low despite a decrease of phosphorus concentration when secondary ZDDPs with short alkyl chain together with appropriate ashless dispersants were selected. Since adsorptivity of secondary ZDDPs with short alkyl chain lengths onto rubbing metal surfaces is higher than that of primary types, the secondary types give excellent antiwear characteristics.

The influence of engine oil viscosity on the wear of piston rings and cam faces has been investigated by fired engine tests using a radioisotope (RI) tracer technique. High-temperature and high-shear-rate (HTHS; 150°C, 1O6 s-1) viscosities of the experimental oils prepared are 2.2, 2.4, 2.6 and 3.1 mPa•s. At an oil temperature of 90°C the wear of piston rings and cam faces did not increase, even if the HTHS viscosity was lowered down to 2.2 mPa•s. However, both piston rings and cam faces exhibited an increase in wear below 2.4 mPa•s at 130°C. It was also recognized that valve train wear did not significantly increase with reducing viscosity in the motored engine tests at a temperature of 50°C. From these test results, it was suggested that the oil with the HTHS viscosity of 2.6 mPa•s sufficiently demonstrates the antiwear performance equivalent to that with around 3.0 mPa•s for application to piston rings and cam faces.

A bench engine test for evaluating the fuel efficiency of automotive crankcase oils using modern engines was developed. The fuel consumption was primarily proportional to the viscosity of the oils down to 5 mm2/s at operating temperatures, indicating that the use of low-viscosity oil was effective in improving fuel efficiency. This may be because the oil film would be formed easily, since sliding parts, such as valve train systems, in modern engines are finely finished. Organo molybdenum dithiocarbamates were effective in improving fuel efficiency at high temperature. A 2.7% improvement in fuel efficiency relative to conventional SAE 10W-30 oils was achieved by the combination of low-viscosity SAE 5W-20 oils and organo molybdenum dithiocarbamates under constant operating conditions with engine speed 1,500 rpm and torque 37.2 N•m.

This paper describes lubricant technology to enhance the durability of the low friction performance of gasoline engine oils which were formulated with molybdenum dithiodicarbamates (MoDTCs) as friction modifiers. This paper also describes an evaluation method which consists of three tests: (1) Our in-house rig test to simulate oil deterioration in an engine stand; (2) Quantitative analysis of MoDTC and ZnDTP in oils and; (3) A friction test (SRV). It was found that the low friction performance of fuel economy engine oils deteriorated primarily due to the consumption of MoDTC and ZnDTP. Calcium salicylates had better durability of low friction performance than calcium sulfonates. Furthermore, sulfurized compounds enhanced the durability. Based on these findings, an experimental oil was formulated.

The anti-shudder effect of ATF additives and their mechanisms have been investigated. Anti-shudder durability was evaluated using an automatic transmission (AT) on an engine stand under continuously slip-controlled condition. The addition of over-based Ca-sulfonate and friction modifier (FM) remarkably improved the anti-shudder durability of ATF. The surface roughness of the contact area (contact area roughness) of the clutch plates was measured by an electron probe surface roughness analyzer. To evaluate the boundary frictional properties of the adsorbed film formed, the friction coefficient of the clutch plates in the absence of oil was examined after the anti-shudder durability test. It was found that shudder occurrence was strongly correlated with the contact area roughness and the boundary frictional property of the steel plate surface. Large contact area roughness and low boundary friction were preferred to prevent shudder.