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This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.

Diamond-like carbon (DLC) coating has excellent properties like high hardness and low friction. So it has attracted considerable attention in recent years as a low-friction coating material. However, some DLC coatings display increased wear in oil containing Mo-DTC (Molybdenum-dithiocarbamates). Wear analyses of sliding surface after block-on-ring tests were conducted suggest that the decomposition product from Mo-DTC, MoO3, reacts with active sites in the DLC to promote the wear of DLC.

This paper describes the application of a life prediction method for stainless steel exhaust manifolds. Examination of the exhaust manifold cracks indicated that many of the failures could be attributed to out-of-phase thermal fatigue due to compressive strains that occur at high temperatures. Therefore, the plastic strain range was used as the crack initiation criteria. In addition, the comparison of the calculated thermal fatigue stress-strain hysteresis to the experimental hysteresis made it clear that it was essential to use the stress-strain data that was obtained through tensile and compression testing by keeping the test specimens at the maximum temperature of the thermal fatigue test mode. A finite element crack prediction method was developed using the aforementioned material data and good results were obtained.

A full vehicle multi-body dynamic (MBD) model with suspension control system is developed for fatigue life prediction under rough road condition. The model consists of tires, a trimmed body, heavy attached parts, powertrain, suspension, joints, and a driver model, and includes a suspension control system that varies characteristics of the suspension according to the rough road inputs. For tires, a commercial MBD tire model is employed with identifiable parameters. The models are simulated to run on the optically measured road surface of the proving ground. Apart from the trimmed body, several important heavy attached parts are modeled separately, that represent dynamic behavior that induces complex body input load. These parts, along with suspension and powertrain systems are connected to the body using nonlinear elements such as joints, springs, and dampers. Contact conditions are used to represent mount bushing, hood lock, stopper rubber, etc.

In preparation for compliance with California's SULEV standard and Euro STAGE 4 standard, which will take effect in 2002 and 2005, respectively, we have developed a laminated planar oxygen sensor. The developed sensor has the following characteristics: high thermal conductivity and superior dielectric characteristic, due to direct joining of the heater element alumina substrate and the sensor element zirconia electrolyte; low heat stress at temperature rise, due to optimized heater design; superior sensor protection from water droplets, and improved sensor response, due to optimized arrangement of intake holes in the sensor cover. With these characteristics, the developed oxygen sensor can be activated in 10 seconds after cold start. This report describes the technologies we used to develop the early-activation oxygen sensor.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

ϵ-caprolactam was polymerized in the interlayer space of montmorillonite, the clay mineral yielding a nylon-clay hybrid (NCH). X-ray and TEM measurements revealed that each template of the silicate, which was 1 nm thick, was dispersed in the nylon 6 matrix, and that the interlayer distance of clay increased continuously from 1.2 nm for the unintercalated material to 21.4 nm for the intercalated material. Thus, NCH is a polymer-based molecular composite or a nano-composite. NCH contains 1-15 vol% of monolayer clay. Injection-molded NCH showed excellent mechanical properties compared with nylon 6 in terms of tensile strength, tensile modulus and heat resistance. The tensile modulus of NCH was twice that of Nylon 6, and the heat distortion temperature increased from 65°C for nylon 6 to 145°C for the NCH containing only 1.6 vol% of a clay mineral. It was found that such excellent properties of an NCH system was due to the strong ionic interaction between nylon 6 and the silicate layer.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

In a previous paper (Part 1 of this series), nylon-66 specimens were immersed in two GTL diesel fuels (GTL-A and GTL-B) and then subjected to tensile testing. The tensile test results revealed that the elongation of the specimen immersed in GTL-A was dramatically reduced. The GTL diesel fuels and nylon specimens before and after immersion were analyzed to determine the cause of the decline in elongation. It was found that the poor elongation was caused by penetration and oxidation of low molecular-weight paraffins and that the ease of penetration and oxidation of paraffin depended on the structure of paraffin. In this paper, the low molecular-weight paraffins detected in GTL-A were mixed to produce model fuels. Then, pieces of nylon cut from the tensile test specimen, were immersed in the model fuels. In addition, partial oxidation products of the paraffin (alcohol, aldehyde or ketone and acid) were used in immersion tests of the nylon pieces.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

The effect of phosphorus concentration in gasoline engine oils on the valve train wear was experimentally investigated by using the JASO M328-91 3A valve train wear (3A-VTW) test method. The phosphorus concentration is determined proportionally to the amount of zinc dithiophosphate (ZDDP), which is formulated as both antiwear agent and antioxidant. Lower concentrations of ZDDP generally bring about larger wear in the valve train. However, it was found from the experiments that valve train wear remained low despite a decrease of phosphorus concentration when secondary ZDDPs with short alkyl chain together with appropriate ashless dispersants were selected. Since adsorptivity of secondary ZDDPs with short alkyl chain lengths onto rubbing metal surfaces is higher than that of primary types, the secondary types give excellent antiwear characteristics.

A laboratory scale simulation test method was developed to evaluate deterioration of radial lip seals of fluoroelastomer (FKM) compounds for engine crankshafts. The investigation of the collected radial lip seals of FKM compounds from the field with service up to 450,000km indicated that the only symptom of deterioration is a decrease of lip interference. This deterioration was not duplicated under conventional test conditions using an oil seal test machine because sludge build up at the seal lip caused oil leakage. However, revised test conditions make it possible to duplicate the deterioration experienced in the field. An immersion test using a radial lip seal assembled with the mating shaft was newly developed. This test method was found to be useful to evaluate deterioration of radial lip seals using FKM compounds. Oil additives affect the deterioration of lip seal materials significantly. Therefore, immersion tests of four different oils were conducted to evaluate this effect.

This newly developed helical spring can be used at a stress level up to 1300 MPa. The material is composed of Fe-C-Si-Mn-Ni-Cr-Mo-V alloy. Its strength-toughness balance was greatly superior to that of other spring steels. To improve the fatigue strength at a higher stress level, decarburization at the surface upon austenitizing was severely controlled, applying induction heating. Then, a special shot peening process, introduced for the first time, was applied to obtain a surface residual stress at the surface of over 1000 MPa. The spring was first applied to a 1992 TOYOTA model car. Plans are to increase the use since the spring material achieves a weight reduction of at least 30 % and, possibly, 35 to 40 %.

Sintered silicon nitride, particularly in structural ceramics, has superior properties such as low weight, heat resistance, wear resistance, etc. It is already being applied to automobile engine parts such as the swirl chamber and the turbine rotor. In recent years, the strength of silicon nitride has shown to be above 1000MPa. This has been achieved through advances in manufacturing technology such as materials powder, forming, sintering and so on. But the silicon nitride is easily damaged during grinding because it has less fracture toughness than metal. Consequently, the inherent strength of the material is not demonstrated in the actual products presently produced. It is assumed that the main cause of strength reduction is microcrack. In ordinary grinding methods, the length of microcrack has been estimated at approximately twenty micrometers by fracture mechanics analysis.

The authors developed a high-reliability low-cost gold-plated connector for automobiles. The connector is covered with three plated layers, nickel, palladium-nickel alloy, and gold. The three-layer plating helps to reduce the required thickness of gold. This paper describes the reasons why palladium-nickel plating was adopted and compares the corrosion resistance, oxidation resistance and wear resistance of three-layer-plated materials with those of conventional gold-plated materials. In addition, the characterisitics of three-layer-plated connectors were compared with those of conventional gold-plated connectors. It was found that the reliability of three-layer-plated connectors was as high as that of conventional gold-plated connectors.

The muffler layout in the exhaust system has been optimized for the attenuation of exhaust noise which has not been studied much to this date. As a result, “Exhaust Manifold Muffler” has been developed. This unit is capable of efficiently muffling the primary and secondary componemts of the engine explosion stroke noise. Such task is achieved without deterioration of engine performance by allocating the volume at the junction of the exhaust manifold branch pipes. Acoustic characteristics of “Exhaust Manifold Muffler” have been analyzed by FEM and experimental methods, which have shown that not only does the volume placed at the junction of the exhaust manifold branch pipes work as a conventional muffler, but also prevents the exhaust manifold branch pipes from amplifying exhaust noise. This is the reason why “Exhaust Manifold Muffler” can muffle more efficiently than the conventional muffler.

The influence of engine oil viscosity on the wear of piston rings and cam faces has been investigated by fired engine tests using a radioisotope (RI) tracer technique. High-temperature and high-shear-rate (HTHS; 150°C, 1O6 s-1) viscosities of the experimental oils prepared are 2.2, 2.4, 2.6 and 3.1 mPa•s. At an oil temperature of 90°C the wear of piston rings and cam faces did not increase, even if the HTHS viscosity was lowered down to 2.2 mPa•s. However, both piston rings and cam faces exhibited an increase in wear below 2.4 mPa•s at 130°C. It was also recognized that valve train wear did not significantly increase with reducing viscosity in the motored engine tests at a temperature of 50°C. From these test results, it was suggested that the oil with the HTHS viscosity of 2.6 mPa•s sufficiently demonstrates the antiwear performance equivalent to that with around 3.0 mPa•s for application to piston rings and cam faces.

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.

A high strength and high toughness new bainitic steel has been developed which shows comparable mechanical properties, fatigue property, and machinability to those of quenched and tempered SAE 5140. The heat treatment of the bainitic steel is aging after hot forging in order to improve ratio of 0.2% proof stress and tensile strength (i.e. yield ratio) and to avoid warpage associated with quenching. The new bainitic steel has been applied to the slender and lightweight lower arms for automotive suspension. As a result, the total production costs in the lower arms have been reduced by nearly 15 percent.

The change of the fuel flow rate in an injector with mileage accumulation causes poor drivability and exhaust emission deterioration in Otto-type methanol fueled vehicles with a multi-point fuel injection system. This is one of the serious problems which needs to be solved for the practical use of methanol fueled vehicles. The investigation results reveal that the wear of contact surfaces between a valve needle and a valve body increases the resistance force for valve needle movement and causes the change of dynamic fuel flow rate in the injector. The effects of several countermeasures to solve this problem are evaluated.