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Journal Article

Development of Clean Diesel NOx After-treatment System with Sulfur Trap Catalyst

2010-04-12
2010-01-0303
Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.
Journal Article

Simultaneous Reduction of NOx and PM in Diesel Exhaust Based on Electrochemical Reaction

2010-04-12
2010-01-0306
The emission regulations for diesel engines are continually becoming stricter to reduce pollution and conserve energy. To meet these increasingly stringent regulations, a new exhaust after-treatment device is needed. Recently, the authors proposed the simultaneous electrochemical reduction (ECR) system for diesel particulate matter (PM) and NOx. In this method, a gas-permeable electrochemical cell with a porous solid oxide electrolyte is used for PM filtering on the anode. Alkaline earth metal is coated on the cathode for NOx storage. Application of voltage to both electrodes enables the simultaneous reduction of PM and NOx by the forced flow of oxygen ions from the cathode to the anode (oxygen pumping). In this study, the basic characteristics of the ECR system were investigated, and a disk-shaped electrochemical cell was evaluated.
Journal Article

Typical Velocity Fields and Vortical Structures around a Formula One Car, based on Experimental Investigations using Particle Image Velocimetry

2016-04-05
2016-01-1611
This paper presents typical flow structures around a 60%-scale wind-tunnel model of a Formula One (F1) car, using planar particle image velocimetry (PIV). The customized PIV system is permanently installed in a wind tunnel to help aerodynamicists in the development loop. The PIV results enhance the understanding of the mean velocity field in the two-dimensional plane in some important areas of the car, such as the front-wheel wake and the underfloor flow. These real phenomena obtained in the wind tunnel also help maintain the accuracy of simulations using computational fluid dynamics (CFD) by allowing regular checking of the correlation with the real-world counterpart. This paper first surveys recent literature on unique flow structures around the rotating exposed wheel, mostly that on the isolated wheel, and then gives the background to F1 aerodynamics in the late 2000s.
Journal Article

Friction Coefficient Variation Mechanism under Wet Condition in Disk Brake (Variation Mechanism Contributing Wet Wear Debris)

2016-09-18
2016-01-1943
This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.
Journal Article

Emissions Reduction Potential of Extremely High Boost and High EGR Rate for an HSDI Diesel Engine and the Reduction Mechanisms of Exhaust Emissions

2008-04-14
2008-01-1189
The effects of an increasing boost pressure, a high EGR rate and a high injection pressure on exhaust emissions from an HSDI (High Speed Direct Injection) diesel engine were examined. The mechanisms were then investigated with both in-cylinder observations and 3DCFD coupled with ϕT-map analysis. Under a high-load condition, increasing the charging efficiency combined with a high injection pressure and a high EGR rate is an effective way to reduce NOx and soot simultaneously, which realized an ultra low NOx of 16ppm at 1.7MPa of IMEP (Indicated Mean Effective Pressure). The flame temperature with low NOx and low soot emissions is decreased by 260K from that with conventional emissions. Also, the distribution of the fuel-air mixture plot on a ϕT-map is moved away from the NOx and soot formation peninsula, compared to the conventional emissions case.
Journal Article

Low Emissions and High-Efficiency Diesel Combustion Using Highly Dispersed Spray with Restricted In-Cylinder Swirl and Squish Flows

2011-04-12
2011-01-1393
A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.
Journal Article

Cooling Loss Reduction of Highly Dispersed Spray Combustion with Restricted In-Cylinder Swirl and Squish Flow in Diesel Engine

2012-04-16
2012-01-0689
In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.
Journal Article

FAME Blended Diesel Fuel Impacts on Engine/Vehicle Systems

2011-08-30
2011-01-1944
The impact of fatty acid methyl ester (FAME) blended diesel fuel on engine/vehicle systems was comprehensively investigated by vehicle, laboratory and engine tests. In this study, 20% FAME blended fuel (B20) was mainly used and soy bean oil methyl ester (SME) was primarily selected as the FAME. Vehicle testing with long-term fuel storage in vehicle fuel tanks was conducted, considering the most severe conditions in market use. Laboratory and engine tests were also conducted to better understand the vehicle test results. In the vehicle test, engine startability, idle roughness and fuel injection control were evaluated using nine vehicles with plastic or metal fuel tanks. All vehicles showed no problems up to 7 months. While five vehicles with plastic fuel tank did not show any problems throughout the test period up to 18 months, four vehicles with metal fuel tanks experienced malfunctions in engine start or fuel injection control following 8, 13, 13 and 18 months respectively.
Journal Article

Development of an On-Board PM Sensor for the OBD System Based on an Electrochemical Polarization

2011-08-30
2011-01-2059
An on-board particulate matter (PM) sensor, consisting of a gas-permeable electrochemical cell with a porous yttria-stabilized zirconia solid oxide electrolyte, was developed to assist the on-board diagnostics (OBD) system of a vehicle. Exhaust is pumped from the anode side to the cathode side and PM deposited on the anode is instantly oxidized by the catalytic effects of the metal component of the electrode at temperatures higher than 350°C. The PM oxidation reaction occurs at the three-phase boundary between the anode, electrolyte and gas phase, and causes a slight change in the bulk average oxygen concentration, which produces electrochemical polarization by the difference in oxygen partial pressures between the anode and cathode. The developed PM sensor has a detection limit of 2 mg/m₃, at which level will enable PM detection in the OBD system according to the EURO VI regulation.
Journal Article

Experimental Study of the Impact of Diesel/Biodiesel Blends Oxidation on the Fuel Injection System

2014-10-13
2014-01-2767
The stability of Diesel/Biodiesel blends can play an important role in deposits formation inside the fuel injection system (FIS). The impact of the stability of FAME/Diesel fuel blends on lacquer deposits formation and on the behavior and reliability of the FIS was investigated using blends of Rapeseed and Soybean methyl esters (RME, SME) and conventional Diesel fuel (volume fractions of RME and SME range from 0 to 20%v/v). Fuels were aged under accelerated conditions and tested on an injection test rig according to an operating cycle developed to provoke injector needle blocking. The soaking duration was found to affect injector fouling. A relationship between the injector fouling tendency and the fuel stability was established. Under current test condition, injectors fouling increased with fuel oxidation measured with Total-Acid-Number.
Technical Paper

Next Generation High Performance ATF for Slip-Controlled Automatic Transmission

1997-10-01
972927
A slip-controlled lock-up clutch system Is very efficient in improving the fuel economy of automatic transmission (AT) equipped vehicles. However, a special automatic transmission fluid (ATF) which combines an anti-shudder property with high torque capacity is required for this system. In this study, we established additive technology for ATF having a sufficient anti-shudder property and high torque capacity. Based on the technology, new ATF: ATF-T4 was developed. It was confirmed in actual AT tests that ATF-T4 has excellent anti-shudder durability and high torque capacity. Furthermore, ATF-T4 has good SAE No. 2 friction characteristics, oxidation stability, compatibility with materials (elastomers, nylons, etc.) and viscosity at low temperatures.
Technical Paper

Combustion Improvement for Reducing Exhaust Emissions in IDI Diesel Engine

1998-02-23
980503
Means for reducing the particulate matter (PM) from swirl chamber type diesel engines were searched out, and the reducing mechanisms were examined using an optically accessible engine. The following points were clarified in this study. 1. At light load, the suppression of the initial injection rate reduces PM, because SOF is reduced by the change in ignition point and smoke is reduced by the retarded flowout of the dense soot from the swirl chamber 2. Under medium and high load conditions, the main cause of the exhaust smoke is fierce spray-wall impingement which leads to fuel adhesion on the wall and the stagnation of a rich fuel-air mixture. 3. Enlarging swirl chamber volume ratio suppresses the formation of dense soot in the swirl chamber. In the main chamber, however, the soot oxidization becomes insufficient due to the mixing effect reduced by the essentially decreased chamber depth. 4.
Technical Paper

Effect of Hydrocarbon Molecular Structure on Diesel Exhaust Emissions Part 2: Effect of Branched and Ring Structures of Paraffins on Benzene and Soot Formation

1998-10-19
982495
The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.
Technical Paper

Development of alloy cast iron for press die

2000-06-12
2000-05-0194
This paper describes the development of alloy cast iron that can be used for the cutting edges of the trimming die of a press die. Usually, a block of tool steel or steel casting is inserted at the cutting edge of the trimming die of a press die. However, we unified the structure part and the cutting-edge part of a press die with alloy cast iron. As it can''t bear as the cutting edge in this state, the cutting edge is processed by flame-hardening. After the flame- hardening, we developed the alloy cast iron so that enough hardness may be obtained by natural air cooling. Thereby, the machining of the installation seat of the cutting edge decreased and the expense of dies has been reduced.
Technical Paper

An Intelligent Catalyst

2001-03-05
2001-01-1301
The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.
Technical Paper

Development of Three-way Catalyst Using Composite Alumina-Ceria-Zirconia

2003-03-03
2003-01-0811
To realize the high performance of the three-way catalyst, this development focused on the heat resistance of the CeO2-ZrO2 solid solution (CZ) that possesses the oxygen storage capacity (OSC). A new concept of the OSC compound with high durability is proposed. We devised a new method of inhibiting the coagulation of the primary CZ particles by placing diffusion barrier layers made of alumina among the primary CZ particles. This material is called “ACZ”. The specific surface area of ACZ was larger than that of the conventional CZ after durability test. The sintering of Pt on the ACZ-added catalyst is inhibited and the crystal size of CZ in the ACZ-added catalyst is smaller than that in the CZ-added catalyst. The OSC and the light off temperature of the ACZ-added catalyst are improved.
Technical Paper

Analysis of the Deterioration of Nylon-66 Immersed in GTL Diesel Fuel Part 1. Analysis and Test of Nylon and GTL Diesel Fuel Before and After Immersion

2006-10-16
2006-01-3326
The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.
Technical Paper

Analysis of the Deterioration of Nylon-66 Immersed in GTL Diesel Fuel Part 2. Analysis of Model Fuel and Nylon Before and After Immersion

2006-10-16
2006-01-3327
In a previous paper (Part 1 of this series), nylon-66 specimens were immersed in two GTL diesel fuels (GTL-A and GTL-B) and then subjected to tensile testing. The tensile test results revealed that the elongation of the specimen immersed in GTL-A was dramatically reduced. The GTL diesel fuels and nylon specimens before and after immersion were analyzed to determine the cause of the decline in elongation. It was found that the poor elongation was caused by penetration and oxidation of low molecular-weight paraffins and that the ease of penetration and oxidation of paraffin depended on the structure of paraffin. In this paper, the low molecular-weight paraffins detected in GTL-A were mixed to produce model fuels. Then, pieces of nylon cut from the tensile test specimen, were immersed in the model fuels. In addition, partial oxidation products of the paraffin (alcohol, aldehyde or ketone and acid) were used in immersion tests of the nylon pieces.
Technical Paper

Development of Ductile Cast Iron Flywheel Integrated with Hot Form-Rolled Gear

1998-02-01
980568
New ductile cast iron flywheel integrated with gear and its manufacturing process were developed to reduce the manufacturing steps and cost compared with conventional flywheel around which a steel ring gear is fit. In this process, the ring gear teeth around a cast iron flywheel are formed directly in net shape and free from any defect by the hot form-rolling method, followed by the thermomechanical treatment in a short time. The gear is superior to that made by the conventional hobbing and heat treatment in accuracy, strength and anti-wear property.
Technical Paper

Multifunctional Surface Treatment for Car Air Conditioners

1998-02-23
980284
In order to improve corrosion resistance and thermal efficiency of the air conditioner evaporator, a coating which provides hydrophilicity was formed over the chromate coating. In addition, there has been greater demand for air with fewer smells. This report describes the cause of “dusty odor” and a method to reduce it. The dusty odor is caused by a little corrosion of the substrate aluminum. Hydrophilic coating film dissolves little by little in condensed water, and substrate aluminum is exposed. A method to prevent the odor was developed by forming a coating giving hydrophilicity and durability to the evaporator surface.
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