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The use of hybrid, fuel cell electric, and pure electric vehicles is on the increase as part of measures to help reduce exhaust gas emissions and to help resolve energy issues. These vehicles use regenerative-friction brake coordination technology, which requires a braking system that can accurately control the hydraulic brakes in response to small changes in regenerative braking. At the same time, the spread of collision avoidance support technology is progressing at a rapid pace along with a growing awareness of vehicle safety. This technology requires braking systems that can apply a large braking force in a short time. Although brake systems that have both accurate hydraulic control and large braking force have been developed in the past, simplification is required to promote further adoption.

From the viewpoint of the global warming restraint, reduction of exhaust emissions from diesel engine is urgent demand. However, it needs further development in combustion control besides after treatment system. Larger amount of EGR (Exhaust Gas Recirculation) is effective to reduce NOx emission. On the other hand, in-cylinder physical conditions greatly influence on self-ignition and combustion process, especially low O2 fraction charged gas owing to excessive EGR causes misfire. A drastic solution for this problem, fuel injection timing should be optimally manipulated based on predicted ignition delay period before actual injection. For this purpose, Toyota has developed a model based diesel combustion control concept to avoid the misfire and to keep low emission combustion includes in transient condition.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

The emissions reduction potential of neat GTL (Gas to Liquids: Fischer-Tropsch synthetic gas-oil derived from natural gas) fuels has been preliminarily evaluated by three different latest-generation diesel engines with different displacements. In addition, differences in combustion phenomena between the GTL fuels and baseline diesel fuel have been observed by means of a single cylinder engine with optical access. From these findings, one of the engines has been modified to improve both exhaust emissions and fuel consumption simultaneously, assuming the use of neat GTL fuels. The conversion efficiency of the NOx (oxides of nitrogen) reduction catalyst has also been improved.

To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.

Cold weather operation has been a major issue for fuel cell vehicles (FCV). In order to counteract this effect on FCV operation, an approach for rapid warm-up operation based on : concentration overvoltage increase and conversion efficiency decrease by limiting oxygen or hydrogen supply, was adopted in a running fuel cell hybrid vehicle. In order to adjust the output power response of the fuel cell to the target power of the vehicle, -the inherent capacitance characteristics of the fuel cell were measured- based on the oxidation-reduction reaction and an electric double-layer capacitor, and an equivalent electric circuit model of a fuel cell with the capacitance was constructed. This equivalent electric circuit model was used to develop a power control algorithm to manage absorption of the surplus power, or deviation, to the capacitance.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

Alcohol fuels that can be produced from cellulose continue to become more widely used in gasoline engines. This research investigated the application of alcohol to diesel engines with the aims of improving the combustion of diesel engines and of utilizing alternative fuels. Two methods were compared, a method in which alcohol is injected into the air intake system and a method in which alcohol is blended in advance into the diesel fuel. Alcohol is an oxygenated fuel and so the amount of soot that is emitted is small. Furthermore, blended fuels have characteristics that help promote mixture formation, which can be expected to reduce the amount of soot even more, such as a low cetane number, low viscosity, low surface tension, and a low boiling point. Ethanol has a strong moisture-absorption attribute and separates easily when mixed with diesel fuel. Therefore, 1-butanol was used since it possesses a strong hydrophobic attribute and does not separate easily.

For over a decade and a half, Toyota Motor Corporation has been developing fuel cell vehicles (FCVs) and is continuing various approaches to enable mass production. This study used new methods to quantitatively observe some of the mass transfer phenomena in the reaction field, such as oxygen transport, water drainage, and electronic conductivity. The obtained results are applicable to the design requirements of ideal reaction fields, and have the potential to assist to reduce the size of the fuel cell.

This paper considers an application of reference governor (RG) to automotive diesel aftertreatment temperature control. Recently, regulations on vehicle emissions have become more stringent, and engine hardware and software are expected to be more complicated. It is getting more difficult to guarantee constraints in control systems as well as good control performance. Among model-based control methods that can directly treat constraints, this paper focuses on the RG, which has recently attracted a lot of attention as one method of model prediction-based control. In the RG, references in tracking control are modified based on future prediction so that the predicted outputs in a closed-loop system satisfy the constraints. This paper proposes an online RG algorithm, taking account of the real-time implementation on engine embedded controllers.

Over the past decades, the automotive industry has made significant efforts to improve engine fuel economy by reducing mechanical friction. Reducing friction under cold conditions is becoming more important in hybrid vehicle (HV) and plug-in hybrid vehicle (PHV) systems due to the lower oil temperatures of these systems, which results in higher friction loss. To help resolve this issue, a new internal gear fully variable discharge oil pump (F-VDOP) was developed. This new oil pump can control the oil pressure freely over a temperature range from -10°C to hot conditions. At 20°C, this pump lowers the minimum main gallery pressure to 100 kPa, thereby achieving a friction reduction effect of 1.4 Nm. The developed oil pump achieves a pressure response time constant of 0.17 seconds when changing the oil pressure from 120 kPa to 200 kPa at a temperature of 20°C and an engine speed of 1,600 rpm.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

The effects of blending ETBE to diesel fuel on the characteristics of low temperature diesel combustion and exhaust emissions were investigated in a naturally-aspirated DI diesel engine with large rates of cooled EGR. Low temperature smokeless diesel combustion in a wide EGR range was established with ETBE blended diesel fuel as mixture homogeneity is promoted with increased premixed duration due to decreases in ignitability as well as with improvement in fuel vaporization due to the lower boiling point of ETBE. Increasing the ETBE content in the fuel helps to suppress smoke emissions and maintain efficient smokeless operation when increasing EGR, however a too high ETBE content causes misfiring at larger rates of EGR. While the NOx emissions increase with increases in ETBE content at high intake oxygen concentrations, NOx almost completely disappears when reducing the intake oxygen content below 14 % with cooled EGR.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

Reduction of exhaust emissions was investigated in a modern diesel engine equipped with advanced diesel after treatment system using a Gas-to-Liquid (GTL) fuel, a cleaner burning alternative diesel fuel. This fuel has near zero sulfur and aromatics and high cetane number. Some specially prepared GTL fuel samples were used to study the effects of GTL fuel distillation characteristics on exhaust emissions before engine modification. Test results indicated that distillation range of GTL fuels has a significant impact on engine out PM. High cetane number also improved HC and CO emissions, while these fuel properties have little effect on NOx emissions. From these results, it was found that low distillation range and high cetane number GTL fuel can provide a favorable potential in NOx/PM emissions trade-off. In order to improve the tail-pipe emissions in the latest diesel engine system, the engine modifications were carried out for the most favorable GTL fuel sample.

Feasibility studies concerning ethanol utilization in direct injection gasoline engines were conducted in order to clarify the effects of ethanol on engine performance, exhaust emissions and injector deposit formation. The investigation results indicate that E100 (100% ethanol fuel) can improve full load engine performance around whole engine speed range in a high compression ratio engine (ε=13:1), compared to that of a base compression ratio engine (ε=11.5:1) operated on a premium gasoline. This was caused by the volumetric efficiency (ηv) improvement and engine knock suppression in the high compression ratio engine. On the other hand, HC emissions remarkably increased under lower engine speeds at a full load condition. This phenomenon suggests that poor combustion occurred due to insufficient mixing of air and E100 fuel under these conditions, in which the amount of ethanol injected was too large and fluidity in the cylinder was weak.

In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

The Diesel Particulate and NOx Reduction System (DPNR) is an effective technology as a diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. However, it requires desulfurization control since the DPNR catalyst is poisoned by sulfur components in the exhaust gas from the fuel and lubricant. Desulfurization control causes some degree of fuel penalty and thermal deterioration of the DPNR catalyst because it requires control of rich air fuel ratio and high temperature simultaneously. In this paper, we investigated a new system with a sulfur trap catalyst which can trap sulfur components included in the exhaust gas as sulfates (Sulfur trap DPNR). In this system, desulfurization control is not performed because the sulfur poisoning of the DPNR catalyst is drastically suppressed by the sulfur trap catalyst. In the present DPNR, periodic desulfurization control is required.

A new HC adsorber system was developed to achieve California SULEV emission standards for a V8 5.0-liter engine application (i.e. LS600hL). A HC adsorber system was first released on 2001 PZEV Prius (1.5-liter engine) in U.S.A. For the 5.0L application the substrate volume of both catalyst and adsorber had to be enlarged for a large volume displacement. Prius-type adsorber system could not be adopted for LS600hL because of the problems of installation. So, a new constructional adsorber was proposed. However the increase of gas flow into the adsorber substrate was a problem for desorption. The gas flow into the adsorber substrate was found to be controllable by the specification adjustment of the “throat” and “retainer” parts of adsorber system. Thus the rapid desorption was successfully reduced, and the HC adsorber system achieved a 50% reduction of HC emission.