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Both ammonia and hydrogen, as zero-carbon fuels for internal combustion engines, are received growing attention. However, ammonia faces a challenge of low flame propagation velocity. Through injecting hydrogen into active pre-chamber, its jet flame ignition can accelerate the flame propagation velocity of ammonia. The influence of different pre-chamber structures on engine combustion characteristics is significant. In this paper, numerical studies were conducted to assess the impact of various pre-chamber structures and hydrogen injection strategy on the combustion characteristics of ammonia/hydrogen engines while maintaining the equivalent ratio of 1.0. The results indicate that the jet angle significantly affects the position of jet flame and the followed main combustion. The in-cylinder combustion pressure peaks at jet angle of 150°. Meanwhile, the combustion duration of 150° is shortened by 74.3% compared with that of 60°.