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The effects of different biodiesel blends on engine-out emissions under various transient conditions were investigated in this study using fast response diagnostic equipment. The experimental work was conducted on a modern 3.0 L, V6 high pressure common rail diesel engine fuelled with mineral diesel (B0) and three different blends of rapeseed methyl esters (RME) (B30, B60, B100 by volume) without any modifications of engine parameters. DMS500, Fast FID and Fast CLD were used to measure particulate matter (PM), total hydrocarbon (THC) and nitrogen monoxide (NO) respectively. The tests were conducted during a 12 seconds period with two tests in which load and speed were changed simultaneously and one test with only load changing. The results show that as biodiesel blend ratio increased, total particle number (PN) and THC were decreased whereas NO was increased for all the three transient conditions.

Polyoxymethylene dimethyl ethers (PODEn) are promising alternative fuel candidates for diesel engines because they present advantages in soot reduction. This study uses a PODEn mixture (contains PODE3-6) from mass production to provide oxygen component in blend fuels. The spray combustion of PODEn-diesel bend fuels in a constant volume vessel was studied using high speed imaging, PLII-LEM and OH* chemiluminescence. Fuels of several blend ratios are compared with pure diesel. Flame luminance data show a near linear decrease tendency with the blend ratio increasing. The OH* images reveal that the ignition positions of all the cases have small differences, which indicates that using a low PODEn blend ratio of no more than 30% does not need significant adjustment in engine combustion control strategies. It is found that 30% PODEn blended with diesel (P30) can effectively reduce the total soot by approximately 68% in comparison with pure diesel.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.