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Fuel quality has a significant influence on the combustion engine operation. In recent years the increasing concerns about environmental protection, energy saving, energy security and the requirements of protecting fuel injection and aftertreatment systems have been major driving forces for the Chinese fuel specification evolution. The major property changes in the evolution of Chinese national gasoline and diesel standards are introduced and the reasons behind these changes are analyzed in this paper. The gasoline fuel development from State I to State VI-B involved a decrease of sulfur, manganese, olefins, aromatics and benzene content. The diesel fuel quality improvement from State I to State VI included achieving low sulfur fuels and a cetane number (CN) increase. Provincial fuel standards, stricter than corresponding national standards, were implemented in economically developed areas in the past.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

Cold weather operation has been a major issue for fuel cell hybrid vehicles (FCHV). To counteract the effects of low temperatures on FCHV operation, an approach for rapid warm-up operation based on concentration overvoltage increase and conversion efficiency decrease by limiting oxygen or hydrogen supply was adopted. In order to suppress increases in exhaust hydrogen concentration due to pumping hydrogen during rapid warm-up, dilution control using bypass air and reduction of concentration overvoltage by a minimum voltage guard were implemented. These approaches effectively control waste heat generation and suppress exhaust hydrogen concentrations during cold start and warm-up. These developments were incorporated into the 2008 Toyota FCHV-adv and it was confirmed that the rapid warm-up operation strategy allowed the FCHV-adv to be successfully and repeatedly started at -30°C.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

The effects of different biodiesel blends on engine-out emissions under various transient conditions were investigated in this study using fast response diagnostic equipment. The experimental work was conducted on a modern 3.0 L, V6 high pressure common rail diesel engine fuelled with mineral diesel (B0) and three different blends of rapeseed methyl esters (RME) (B30, B60, B100 by volume) without any modifications of engine parameters. DMS500, Fast FID and Fast CLD were used to measure particulate matter (PM), total hydrocarbon (THC) and nitrogen monoxide (NO) respectively. The tests were conducted during a 12 seconds period with two tests in which load and speed were changed simultaneously and one test with only load changing. The results show that as biodiesel blend ratio increased, total particle number (PN) and THC were decreased whereas NO was increased for all the three transient conditions.

Recently, global warming and energy security have received significant attention. Thus an improvement of the vehicle fuel economy is strongly required. For engines, one effective way is to improve the engine thermal efficiency. Raising compression ratio [1] or turbo charging technologies have potential to achieve high thermal efficiency. However knock does not allow the high thermal efficiency. Knock depends on the fuel composition and the pressure and temperature history of unburnt end-gas [2-3]. For fuels, RON is well known for describing the anti knock quality. High RON fuels have high anti knock quality and result in higher thermal efficiency. This paper investigates the impact of high RON fuels on the thermal efficiency by using high compression ratio engine, turbo charged engine, and lean boosted engine [4]. Finally, it is shown that the high thermal efficiency can be approached with high RON gasoline and ethanol.

Reduction of exhaust emissions was investigated in a modern diesel engine equipped with advanced diesel after treatment system using a Gas-to-Liquid (GTL) fuel, a cleaner burning alternative diesel fuel. This fuel has near zero sulfur and aromatics and high cetane number. Some specially prepared GTL fuel samples were used to study the effects of GTL fuel distillation characteristics on exhaust emissions before engine modification. Test results indicated that distillation range of GTL fuels has a significant impact on engine out PM. High cetane number also improved HC and CO emissions, while these fuel properties have little effect on NOx emissions. From these results, it was found that low distillation range and high cetane number GTL fuel can provide a favorable potential in NOx/PM emissions trade-off. In order to improve the tail-pipe emissions in the latest diesel engine system, the engine modifications were carried out for the most favorable GTL fuel sample.

Feasibility studies concerning ethanol utilization in direct injection gasoline engines were conducted in order to clarify the effects of ethanol on engine performance, exhaust emissions and injector deposit formation. The investigation results indicate that E100 (100% ethanol fuel) can improve full load engine performance around whole engine speed range in a high compression ratio engine (ε=13:1), compared to that of a base compression ratio engine (ε=11.5:1) operated on a premium gasoline. This was caused by the volumetric efficiency (ηv) improvement and engine knock suppression in the high compression ratio engine. On the other hand, HC emissions remarkably increased under lower engine speeds at a full load condition. This phenomenon suggests that poor combustion occurred due to insufficient mixing of air and E100 fuel under these conditions, in which the amount of ethanol injected was too large and fluidity in the cylinder was weak.

From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.

From the energy security and CO2 discharge reduction point of view, much attention has been paid to the usage of biofuel, ethanol, as an alternative source of energy in the transportation industry. Yet, the major drawback in applying highly concentrated ethanol in the spark ignited internal combustion engines is cold start instability. This is due to the characteristics of ethanol, large latent heat required to vaporize. This paper investigates necessary conditions for the engine cold start, using highly concentrated ethanol. Tests performed with varieties of ethanol fuel, a relationship between cold startability lower temperature limit and reid vapor pressure was observed. A method to boost the vaporization, intake valve timing control is introduced to obtain high compression peak temperature.

In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.

To realize the precise control of injection and ignition of compressed natural gas engine, the 32-Digit PowerPC561 was selected as the single-chip microcomputer for the compressed natural gas engine. The signal processing module, controller module and power driver module of the engine control system were introduced successively. In the injection valve drive circuit, a new design method realized the ‘Peak&Hold’ drive current wave shape, which reduced the software work of injection development. In the ignition module circuit, the feedback of the time of ignition persistence and preliminary coil close period were successfully realized. The Engine Control Unit (ECU) has flexible control functions, which fulfill the requirements of engine control system.

Various issues must be resolved before sustainable mobility can be achieved, the most important of which are reacting to energy supply and demand, and lowering CO2 emissions. At present, the fact that the vast majority of vehicles run on conventional oil is regarded as a problem for which Toyota Motor Corporation (TMC) is developing various technological solutions. Fuel cell (FC) technology is one of the most promising of these solutions. A fuel cell is an extremely clean device that uses hydrogen and oxygen to generate power without emitting substances like CO2, NOx, or PM during operation. Its energy efficiency is high and it is widely expected to form the basis of the next generation of powertrains. Since 1992, TMC has been working to develop the main components of fuel cell vehicles, including the fuel cell itself, and the high pressure hydrogen tank and hybrid systems.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

Considering the popularity of biodiesel fuels for diesel vehicles, the impacts of rapeseed oil methyl ester (RME), which is the most utilized biodiesel fuel in Europe, on tailpipe emissions from a diesel passenger car was investigated. In this study, 30% RME blended diesel fuel (RME30) was used and the comparison of tailpipe emissions between RME30 and a reference diesel fuel was conducted using a test vehicle with the latest engine and aftertreatment system. The results of the investigation reveal that RME30 generates about the same amount of NOx in tailpipe emissions as diesel fuel, and less HC, CO, and PM. These phenomena occurred in spite of attaching catalysts to the test vehicle, and therefore suggesting that the NOx conversion efficiency of the catalysts for RME30 is equal to that for diesel fuel. The injection rate for RME30 was the same as that for diesel fuel.

Previous studies have investigated the impacts of biofuel usage on the performance, drivability and durability of modern diesel engines and exhaust after-treatment systems including test work with different types, concentrations and mixtures of bio fuel components. During this earlier work vehicle fuel filter blocking issues were encountered during a field trial using various types of EN 14214 compliant Fatty Acid Methyl Ester (FAME) blended into EN 590 diesel. This paper summarises a subsequent literature review that was carried out looking into potential causes of this filter blocking and further work that was then carried out to expand on the findings. From this, a laboratory study was carried out to assess the increase in fuel filter blocking tendency (FBT) when various FAMEs from mixed sources were blended into EN 590 diesel at different concentrations, including levels above those currently allowed in the European market.

Atomization of fuel sprays is a key factor in controlling the combustion quality in the direct-injection engines. In this present work, the effect of saturation ratio (Rs) on the near nozzle spray patterns of ethanol was investigated using an ultra-high speed imaging technique. The Rs range covered both flash-boiling and non-flash boiling regions. Ethanol was injected from a single-hole injector into an optically accessible constant volume chamber at a fixed injection pressure of 40 MPa with different fuel temperatures and back pressures. High-speed imaging was performed using an ultrahigh speed camera (1 million fps) coupled with a long-distance microscope. Under non-flash boiling conditions, the effect of Rs on fuel development was small but observable. Clear fuel collision can be observed at Rs=1.5 and 1.0. Under the flash boiling conditions, near-nozzle spray patterns were significant different from the non-flash boiling ones.

Natural gas is one of the promising alternative fuels due to the low cost, worldwide availability, high knock resistance and low carbon content. Ignition quality is a key factor influencing the combustion performance in natural gas engines. In this study, the effect of pre-chamber geometry on the ignition process and flame propagation was studied under varied initial mixture temperatures and equivalence ratios. The pre-chambers with orifices in different shapes (circular and slit) were investigated. Schlieren method was adopted to acquire the flame propagation. The results show that under the same cross-section area, the slit pre-chamber can accelerate the flame propagation in the early stages. In the most of the cases, the penetration length of the flame jet and flame area development are higher in the early stages of combustion.

Polyoxymethylene dimethyl ethers (PODEn) are promising alternative fuel candidates for diesel engines because they present advantages in soot reduction. This study uses a PODEn mixture (contains PODE3-6) from mass production to provide oxygen component in blend fuels. The spray combustion of PODEn-diesel bend fuels in a constant volume vessel was studied using high speed imaging, PLII-LEM and OH* chemiluminescence. Fuels of several blend ratios are compared with pure diesel. Flame luminance data show a near linear decrease tendency with the blend ratio increasing. The OH* images reveal that the ignition positions of all the cases have small differences, which indicates that using a low PODEn blend ratio of no more than 30% does not need significant adjustment in engine combustion control strategies. It is found that 30% PODEn blended with diesel (P30) can effectively reduce the total soot by approximately 68% in comparison with pure diesel.

Despite the fact that methanol is toxic to human health and causes serious damage to automobile engines and fuel system components, methanol-containing gasoline is becoming popular in some areas. Methanol demonstrates similar chemical properties to ethanol (which is already established as an additive to gasoline), so that it is difficult to identify methanol-containing gasoline without performing proper chemical analysis. In this study, we report a low-cost, portable, and easy-to-operate sensor that selectively changes color in response to methanol contained in gasoline. The colorimetric sensor will be useful for automobile users to avoid methanol-containing gasoline upon refueling.