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Journal Article

Cu-Zeolite SCR Catalyst Thermal Deactivation Studied with FTIR Spatial Resolution

2011-04-12
2011-01-1138
The performance of a commercial Cu-zeolite SCR catalyst after differing degrees of hydrothermal aging (aged for 72 hours at 500, 700 and 800°C with 10% moisture balanced with air) was studied by spatially resolving different key reactions using gas-phase FTIR measurements. Gases were sampled along a channel at different positions and analyzed using FTIR, which overcomes the interference of water and nitrogen on ammonia concentration detection encountered in standard mass spectrometer-based spatial resolution measurements. The NO:NO₂ concentration ratio was changed so that the standard (NO:NO₂ = 1:0), fast (NO:NO₂ = 1:1) and NO₂ (NO:NO₂ = 0:1) SCR reactions could be investigated as a function of the catalyst's hydrothermal aging extent. In addition, the effects of hydrothermal aging on the activity of NH₃ and NO oxidation were also investigated. Hydrothermal aging had little effect on NO oxidation activity.
Technical Paper

1997 Propane Vehicle Challenge Design Strategy -University of Waterloo

1998-02-23
980491
The conversion design strategy, and emissions and performance results for a dedicated propane, vapour injected, 1995 Dodge Dakota truck are reported. Data is obtained from the University of Waterloo entry in the 1997 Propane Vehicle Challenge. A key feature of the design strategy is its focus on testing and emissions while preserving low engine speed power for drivability. Major changes to the Dakota truck included the following: installation of a custom shaped fuel tank, inclusion of a fuel temperature control module, addition of a vaporizer and a fuel delivery metering unit, installation of a custom vapour distribution manifold, addition of an equivalence ratio electronic controller, inclusion of a wide range oxygen sensor, addition of an exhaust gas recirculation cooler and installation of thermal insulation on the exhaust system. A competition provided natural gas catalyst was used.
Technical Paper

The Effects of Thermal Degradation on the Performance of a NOX Storage/Reduction Catalyst

2009-04-20
2009-01-0631
The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.
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