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Friction between the piston and cylinder accounts for large amount of the friction losses in an internal combustion (IC) engine. Therefore, any effort to minimize such a friction will also result in higher efficiency, lower fuel consumption and reduced emissions. Plasma electrolytic oxidation (PEO) coating is considered as a hard ceramic coating which can provide a dimpled surface for oil retention to bear the wear and reduce the friction from sliding piston rings. In this work, a high speed pin-on-disc tribometer was used to generate the boundary, mixed and hydrodynamic lubrication regimes. Five different lubricating oils and two different loads were applied to do the tribotests and the COFs of a PEO coating were studied. The results show that the PEO coating indeed had a lower COF in a lower viscosity lubricating oil, and a smaller load was beneficial to form the mixed and hydrodynamic lubricating regimes earlier.